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91.
The thermal dehydration process of fibroferrite, FeOH(SO4)·5H2O, a secondary iron-bearing hydrous sulfate, was investigated by in situ high-temperature synchrotron X-ray powder diffraction (HT-XRPD), in situ high-temperature Fourier transform infrared spectroscopy (HT-FTIR) and thermal analysis (TGA-DTA) combined with evolved gas mass spectrometry. The data analysis allowed the determination of the stability fields and the reaction paths for this mineral as well as characterization of its high-temperature products. Five main endothermic peaks are observed in the DTA curve collected from room T up to 800 °C. Mass spectrometry of gases evolved during thermogravimetric analysis confirms that the first four mass loss steps are due to water emission, while the fifth is due to a dehydroxylation process; the final step is due to the decomposition of the remaining sulfate ion. The temperature behavior of the different phases occurring during the heating process was analyzed, and the induced structural changes are discussed. In particular, the crystal structure of a new phase, FeOH(SO4)·4H2O, appearing at about 80 °C due to release of one interstitial H2O molecule, was solved by ab initio real-space and reciprocal-space methods. This study contributes to further understanding of the dehydration mechanism and thermal stability of secondary sulfate minerals.  相似文献   
92.
Back-analysis is broadly used for approaching geotechnical problems when monitoring data are available and information about the soils properties is of poor quality.For landslide stability assessment back-analysis calibration is usually carried out by time consuming trial-and-error procedure.This paper presents a new automatic Decision Support System that supports the selection of the soil parameters for three-dimensional models of landslides based on monitoring data.The method considering a pool of possible solutions,generated through permutation of soil parameters,selects the best ten configurations that are more congruent with the measured displacements.This reduces the operator biases while on the other hand allows the operator to control each step of the computation.The final selection of the preferred solution among the ten best-fitting solutions is carried out by an operator.The operator control is necessary as he may include in the final decision process all the qualitative elements that cannot be included in a qualitative analysis but nevertheless characterize a landslide dynamic as a whole epistemological subject,for example on the base of geomorphological evidence.A landslide located in Northeast Italy has been selected as example for showing the system potentiality.The proposed method is straightforward,scalable and robust and could be useful for researchers and practitioners.  相似文献   
93.
Earthflow‐type landslides are persistent natural hazards having deep socio‐economic and environmental consequences. They have significantly contributed to the geomorphic evolution of mountainous slopes in Europe since the Late Glacial. An understanding of their complex kinematics is crucial to better constrain the processes governing their occurrence and mobility. In this work we explored the possibility to quantify displacement vectors on a spatially distributed basis and to quantify volumetric transfer at the slope scale with regard to a large flow‐type landslide located in the northern Apennines of Italy. For this purpose we applied digital image correlation (DIC) and digital elevation model differencing (DEMoD) techniques to multi‐temporal airborne LiDAR surveys of 2006, 2007 and 2009. The DIC was applied to greyscale slope gradient maps retrieved after precise co‐registration of LiDAR surveys. Thereby, movement patterns over various sectors of the landslide were reconstructed and quantified, most notably up to 20 m in the head zone, up to 51 m in the lower main track, and up to about 27 m at the landslide toe. The DEMoD analysis revealed significant mass transfer from the source to the tracks and toe zone, with the upper flow tracks acting as temporal storage of large amounts of material. The mass balance indicated that significant amounts of advancing landslide debris were eroded by a local stream. An integrated analysis of DEMoD and DIC results allowed for a discussion of governing processes, such as the transition from slide to flow, the influence of underlying topography on earthflow mobility, and the role of undrained loading as a mechanism of toe zone reactivation. In conclusion, the successful application of DIC and DEMoD to the case study underlines the added value of high‐resolution DEMs in the analysis of earthflow kinematics toward a better understanding of their role in the geomorphic evolution of slopes. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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Abstract— Using an H‐plot analysis, we identify 234 currently known near‐Earth objects that are accessible for rendezvous with a “best case” delta‐V of less than 7 km/s. We provide a preliminary compositional interpretation and assessment of these potential targets by summarizing the taxonomic properties for 44 objects. Results for one‐half (22) of this sample are based on new spectroscopic measurements presented here. Our approach provides an easy‐to‐update method for giving guidelines to both observers and mission analysts for focusing on objects for which actual mission opportunities are most likely to be found. Observing prospects are presented for categorizing the taxonomic properties of the most accessible targets that are not yet measured.  相似文献   
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The town of Zafferana Etnea, located on the southeastern slope of Mt. Etna volcano (Italy), has been repeatedly threatened by lava flows in recent centuries. The last serious threat occurred during the 1991–1993 eruption, when the lava front came to a halt only 1.7 km from the centre of town. Morphostructural data derived from light detection and ranging (LiDAR) surveys carried out on Etna in 2005 have enabled us to evaluate the risk of lava invasion in a section (16 km2) of the Zafferana Etnea territory. Qualitative and quantitative results are obtained combining the information derived from LiDAR analysis with geological, morphological and structural data using geographic information systems technology (GIS). The study quantifies in unprecedented detail the areal extent and volume of forested and urban areas and its degree of exposure to different levels of hazard from future lava invasion. Nearly 52% of the urban texture fall into areas of moderate to high risk from lava invasion. Future land use planning should take these findings into account and promote new development preferentially in areas of lower risk.  相似文献   
98.
In the frame of the development of a photogrammetric system to be used in thermal/vacuum chambers at the European Space Research and Technology Centre (ESTEC) of European Space Agency (ESA) and other sites across Europe, the design of a network using micro-cameras was specified by ESA-ESTEC. A thermal/vacuum qualified photogrammetric system, which is able to work and acquire images in vacuum and at cryo-temperatures, was constructed by ESA-ESTEC Test Centre Division. The current system uses four space qualified one-mega pixel cameras and is able to measure large space structures in vacuum and at temperatures down to ?170 °C with a global accuracy better than 1 part per 100,000 in object space. Several tests aiming at the qualification of the sensors and system in terms of operation and accuracy have been carried out. Special measures have been developed and special attention has been taken into account specifically for the first application of the photogrammetric system. It is to verify the ESA’s Herschel Telescope Flight Model alignment positioning.  相似文献   
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Abstract

A central issue in tackling climate change is to understand to what extent different short-term mitigation strategies are consistent with long-term stabilization targets. The present article aims at cross-comparing emission paths derived by plausible short-term policies against those implied by long-term climate targets, comparing, for example, differences in peak periods. Short-term policies considered are, for instance, Kyoto-type targets with or without participation by the USA and/or by developing countries. Long-term targets focus instead on stabilization of CO2 concentrations, radiative forcing and the increase in atmospheric temperature relative to pre-industrial levels. In order to account for the uncertainty surrounding the climate cycle, for each long-term goal multiple paths of emission—the most probable, the optimistic and the pessimistic projections—are considered in the comparison exercise. Comparative analysis is performed using the FEEM-RICE model, a regional economy—climate model. The results suggest that some early policy action should take place for short-term emissions to be compatible with long-term targets. In particular, the Kyoto-type regimes appear to be on a compatible emission path, at least up to the second commitment period. However, this is no longer the case when assuming a pessimistic realization of the uncertain climate parameters.  相似文献   
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