Upper lithospheric seismic velocity structure across the Pripyat Trough and the Ukrainian Shield along the EUROBRIDGE'97 profile

We present new results on the structure resulting from Palaeoproterozoic terrane accretion and later formation of one of the aulacogens in the East European Platform. Seismic data has been acquired along the 530-km-long, N–S-striking EUROBRIDGE'97 traverse across Sarmatia, a major crustal segment of the East European Craton. The profile extends across the Ukrainian Shield from the Devonian Pripyat Trough, across the Palaeoproterozoic Volyn Block and the Korosten Pluton, into the Archaean Podolian Block. Seismic waves from chemical explosions at 18 shot points at approximately 30-km intervals were recorded in two deployments by 120 mobile three-component seismographs at 3–4 km nominal station spacing. The data has been interpreted by use of two-dimensional tomographic travel time inversion and ray trace modelling. The high data quality allows modelling of the P- and S-wave velocity structure along the profile. There are pronounced differences in seismic velocity structure of the crust and uppermost mantle between the three main tectonic provinces traversed by the profile: (i) the Pripyat Trough is a ca. 4-km-deep sedimentary basin, fully located in the Osnitsk–Mikashevichi Igneous Belt in the northern part of the profile. The velocity structure is typical for a Precambrian craton, but is underlain by a ca. 5-km-thick lowest crustal layer of high velocity. The development of the Pripyat Trough appears to have only affected the upper crust without noticeable thinning of the whole crust; this may be explained by a rheologically strong lithosphere at the time of formation of the trough. (ii) Very high seismic velocity and Vp/Vs ratio characterise the Volyn Block and Korosten Pluton to a depth of 15 km and probably also the lowest crust. The values are consistent with an intrusive body of mafic composition in the upper crust that formed from bimodal melts derived from the mantle and the lower crust. (iii) The Podolian Block is close to a typical cratonic velocity structure, although it is characterised by relatively low seismic velocity and Vp/Vs ratio. A pronounced SW-dipping mantle reflector from Moho to at least 70 km depth may represent the Proterozoic suture between Sarmatia and Volgo–Uralia, the structure from terrane accretion, or a later shear zone in the upper mantle. The sub-Moho P-wave seismic velocity is high everywhere along the profile, with the exception of the area above the dipping reflector. This velocity change further supports a plate tectonic origin of the dipping mantle reflector. The profile demonstrates that structure from Palaeoproterozoic plate tectonic processes are still identifiable in the lithosphere, even where younger metamorphic equilibration of the crust has taken place.     

Organic carbon and sulphur compounds in wetland soils: insights on structure and transformation processes using K-edge XANES and NMR spectroscopy

X-ray absorption near-edge structure (XANES) and nuclear magnetic resonance (NMR) spectroscopy were used in combination to characterize organic carbon structures in a series of wetland soils in Saskatchewan, and XANES spectroscopy was also used to examine sulphur speciation in the soils. The organic C contents of most of the wetland soils are consistently higher by a factor of two to five times compared to adjacent well-drained soils. NMR analyses indicate that the organic matter in the wetland soils consists of predominantly aliphatic structures such as carbohydrates and long chain poly(methylene) units which are refractory structures found in plant waxes. The poly(methylene) structures have a significant capacity to sorb nonpolar organic molecules. The phenolic OH and carboxyl group content of the wetland soils studied is an additional significant factor in their sequestering ability for heavy metals or pesticides. Carbon XANES spectroscopy shows that the surface (∼10 nm) layer of particulate organic matter has a structure dominated by aromatic, carbohydrate and carboxylic acid-like material apparently derived from partially degraded lignin and cellulose polymers which are adsorbed onto clay minerals. The aliphatic structures remaining in this surface layer are probably recalcitrant (poly)methylene units. At a depth of ∼100 nm, the aliphatic content significantly increases suggesting the presence of more labile structures. The presence of these more labile aliphatic compounds may be due to slow decomposition rates in the wet, often cool environments present and to the protective action of the more refractory components in the surface ∼10 nm of the organic matter. Drying of the wetlands, either by draining or as a result of climate change, is likely to result in the rapid decomposition of these labile organic structures releasing carbon dioxide. Our data indicate that the preservation of the organic carbon compounds in these soils is a result of their presence as surface adsorbed layers on the soil mineral particles. The soils contain three different classes of sulphur compounds: reduced organic sulphur such as sulphides, low valent oxidized sulphur such as sulphoxides, and high valent oxidized sulphur such as sulphonate and sulphate. Of these, reduced sulphur species constitute between one-third and two-thirds of the total. Sulphonate structures comprise between a fifth and a third of the total. Sulphates exhibit a wide variation in content, and sulphoxides are either not detected or are present to a lesser extent (<5%). Drying of the wetlands would cause oxidation of sulphides to sulphates.     

Crustal and upper mantle velocity model along the DOBRE-4 profile from North Dobruja to the central region of the Ukrainian Shield: 1. seismic data

For studying the structure of the lithosphere in southern Ukraine, wide-angle seismic studies that recorded the reflected and refracted waves were carried out under the DOBRE-4 project. The field works were conducted in October 2009. Thirteen chemical shot points spaced 35–50 km apart from each other were implemented with a charge weight varying from 600 to 1000 kg. Overall 230 recording stations with an interval of 2.5 km between them were used. The high quality of the obtained data allowed us to model the velocity section along the profile for P- and S-waves. Seismic modeling was carried out by two methods. Initially, trial-and-error ray tracing using the arrival times of the main reflected and refracted P- and S-phases was conducted. Next, the amplitudes of the recorded phases were analyzed by the finite-difference full waveform method. The resulting velocity model demonstrates a fairly homogeneous structure from the middle to lower crust both in the vertical and horizontal directions. A drastically different situation is observed in the upper crust, where the V _p velocities decrease upwards along the section from 6.35 km/s at a depth of 15–20 km to 5.9–5.8 km/s on the surface of the crystalline basement; in the Neoproterozoic and Paleozoic deposits, it diminishes from 5.15 to 3.80 km/s, and in the Mesozoic layers, it decreases from 2.70 to 2.30 km/s. The subcrustal V _p gradually increases downwards from 6.50 to 6.7–6.8 km/s at the crustal base, which complicates the problem of separating the middle and lower crust. The V _p velocities above 6.80 km/s have not been revealed even in the lowermost part of the crust, in contrast to the similar profiles in the East European Platform. The Moho is clearly delineated by the velocity contrast of 1.3–1.7 km/s. The alternating pattern of the changes in the Moho depths corresponding to Moho undulations with a wavelength of about 150 km and the amplitude reaching 8 to 17 km is a peculiarity of the velocity model.     

Correction to: Zeolite containing rocks of kudurs and reasons of geophagy within the territory of Sikhote-Alin Nature Zapovednik,Far East of Russia

This paper establishes a mechanical model of the stress distribution in front of the driving face during coal roadway excavation. Theoretical research shows that the stress state in the plastic zone of the driving face is consistent with the limit equilibrium equation, and the elastic zone is in accordance with the equilibrium equation based on elasticity mechanics. Based on this improved mechanical state solution model, different coal material constitutive hypotheses are used for the analysis. The width of the plastic zone calculated under the brittle-perfectly elastic model can reach 2–5 times the height of the roadway, and the stress concentration coefficient can reach two or more times. 3DEC numerical simulation software was used to simulate the stress distribution of the heading face. The results of the simulation are similar to those of the theoretical analysis. Compared with the elastic-perfectly plastic model, the calculated results of the brittle-perfectly elastic model are more consistent with the numerical simulation results. The heading face coal during roadway excavation shows obvious damage, and the strength characteristics of the coal decrease.     

Structure and chemistry of (111) twin boundaries in MgAl<Subscript>2</Subscript>O<Subscript>4</Subscript> spinel crystals from Mogok

The atomic scale structure and chemistry of (111) twins in MgAl₂O₄ spinel crystals from the Pinpyit locality near Mogok (Myanmar, formerly Burma) were analysed using complementary methods of transmission electron microscopy (TEM). To obtain a three-dimensional information on the atomic structure, the twin boundaries were investigated in crystallographic projections and Using conventional electron diffraction and high-resolution TEM (HRTEM) analysis we have shown that (111) twins in spinel can be crystallographically described by 180° rotation of the oxygen sublattice normal to the twin composition plane. This operation generates a local hcp stacking in otherwise ccp lattice and maintains a regular sequence of kagome and mixed layers. In addition to rotation, no other translations are present in (111) twins in these spinel crystals. Chemical analysis of the twin boundary was performed by energy-dispersive X-ray spectroscopy (EDS) using a variable beam diameter (VBD) technique, which is perfectly suited for analysing chemical composition of twin boundaries on a sub-nm scale. The VBD/EDS measurements indicated that (111) twin boundary in spinel is Mg-deficient. Quantitative analyses of HRTEM (phase contrast) and HAADF-STEM (Z-contrast) images of (111) twin boundary have confirmed that Mg²⁺ ions are replaced with Be²⁺ ions in boundary tetrahedral sites. The Be-rich twin boundary structure is closely related to BeAl₂O₄ (chrysoberyl) and BeMg₃Al₈O₁₆ (taaffeite) group of intermediate polysomatic minerals. Based on these results, we conclude that the formation of (111) twins in spinel is a preparatory stage of polytype/polysome formation (taaffeite) and is a result of thermodynamically favourable formation of hcp stacking due to Be incorporation on the {111} planes of the spinel structure in the nucleation stage of crystal growth. The twin structure grows as long as the surrounding geochemical conditions allow its formation. The incorporation of Be induces a 2D-anisotropy and exaggerated growth of the crystal along the (111) twin boundary.     

Biomass Size Spectra of Near-Shore Shallow-Water Benthic Communities in the Gulf of Gdańsk Southern Baltic Sea

The concept of size spectra, developed by S heldon & P arsons 1967 and S heldon et al. 1972, seeks to describe community structure by evoking the distribution of biomass over a sequence of equal intervals of the logarithm of body size. In this study, biomass size spectra were prepared for benthic macro- and meiobenthos communities at 5 stations, differing in their sediment characteristics, located in the shallow, coastal area of the Gulf of Gdańsk Southern Baltic Sea. The purpose of this study was to determine whether the community spectra would allow distinct separation of ecological categories of the benthos and whether habitat differences between stations would significantly affect benthic size spectra.
Benthic biomass at the stations sampled depended mainly on nematodes and oligochaetes among the meiobenthos and on hydrobiid snails and M. edulis among the macrobenthos. Regardless of habitat, size spectra peaked initially at the meiofaunal range weight class 25 1. 19–501.19 ng C, identical to that reported in other studies. The separation between meio- and macrobenthic peaks, however, was not as pronounced as that found in other studies. Normalized size spectra demonstrated that most of the variations in the spectra between stations was introduced by macrobenthos, which differed between the coarse- and fine-grained sediments. Nonetheless, those differences were not strong enough to significantly affect the spectra. In consequence, the benthic biomass spectra of all the stations were found to conform to a common pattern and could be represented by a single, average spectrum.     

Crustal model of the Bransfield Rift, West Antarctica, from detailed OBS refraction experiments

The first detailed deep seismic refraction study in the Bransfield Strait, West Antarctica, using sensitive OBSs (ocean bottom seismographs) was carried out successfully during the Antarctic summer of 1990/1991. The experiment focused on the deep crustal structure beneath the axis of the Bransfield Rift. Seismic profile DSS-20 was located exactly in the Bransfield Trough, which is suspected to be a young rift system. Along the profile, five OBSs were deployed at spacings of 50-70 km. 51 shots were fired along the 310 km profile. This paper gives the first presentation of the results. A detailed model of the crustal structure was obtained by modelling the observed traveltimes and amplitudes using a 2-D ray-tracing technique. The uppermost (sedimentary?) cover, with velocities of 2.0-5.5 km s⁻¹, reaches a depth of up to 8 km. Below this, a complex with velocities of 6.4-6.8 km s⁻¹ is observed. The presence of a high-velocity body, with V _p= 7.3-7.7 km s⁻¹, was detected in the 14-32 km depth range in the central part of the profile. These inhomogeneities can be interpreted as a stage of back-arc spreading and stretching of the continental crust, coinciding with the Deception-Bridgeman volcanic line. Velocities of 8.1 km s⁻¹, characteristic of the Moho, are observed along the profile at a depth of 30-32 km.     

Geospatial cryptography: enabling researchers to access private,spatially referenced,human subjects data for cancer control and prevention

Journal of Geographical Systems - As the volume, accuracy and precision of digital geographic information have increased, concerns regarding individual privacy and confidentiality have come to the...     

Elastic properties of seafloor sediments from the modelling of amplitudes of multiple water waves recorded on the seafloor off Bear Island,North Atlantic

Wide‐angle seismic data acquired by use of air‐guns and ocean bottom seismometers (OBS) contain strong direct water arrivals and multiples, generally considered as noise and thus not included in the modelling. However, a recent study showed that standard ray‐tracing modelling of the water multiples recorded off the Bear Island, North Atlantic, provided a reliable estimate of the velocity distribution in the water layer. Here, we demonstrate that including the amplitudes in the modelling provide valuable information about the V_P contrast at the seafloor, as well as the V_P/V_S ratio and attenuation (Q_P) of the uppermost sediments. The V_P contrast at the seafloor is estimated at about 250 m/s, within a precision of approximately ±30 m/s. The V_P/V_S ratio in the uppermost sedimentary layer is modelled in the range 2.25–2.50 and the Q_P factor is estimated at 1000 for the water, 30–50 for the uppermost layer and 40–50 for the second sedimentary layer. The values obtained for the sediments suggest a lithology dominated by silty clays, with porosity below average.     

Photochemical escape of oxygen from Mars: A comparison of the exobase approximation to a Monte Carlo method

The non-thermal escape of neutral O atoms from Mars at the current epoch is largely due to dissociative recombination of :