Oxygen isotope variations in phosphate of biogenic apatites,II. Phosphorite rocks

Phosphorites from sedimentary sequences ranging in age from Archaean to Recent were analysed for δ¹⁸O in both the PO₄ (δ¹⁸O_p) and CO₃ (δ¹⁸O_c) in the apatite lattice. The oxygen isotope record is considerably better preserved in phosphates than in either carbonates or cherts. The use of the Longinelli and Nuti [8] temperature equation yields temperatures for Recent phosphorites that are in good agreement with those measured in the field. The δ¹⁸O_p values of ancient phosphorites decrease with increasing age. These changes with time are not likely to be due to post-depositional exchange. Changes in δ¹⁸O values of seawater and variations of temperature with time can account for the δ¹⁸O_p time trend, but the latter explanation is preferred. In Ancient phosphorites δ¹⁸O_c in structurally bound carbonate in apatite is not a reliable geochemical indicator.     

Magma contamination by direct wall rock interaction: constraints from xenoliths from the walls of a carbonate-hosted magma chamber (Vesuvius 1944 eruption)

During the 1944 eruption of Vesuvius different types of xenoliths were ejected. They represent fragments of the walls of a low volume (<0.5 km³) shallow (3–4 km depth) magma chamber. The study of these xenoliths enables us to estimate the amount of contamination occurring at the boundary of a high-T alkaline magma chamber hosted in carbonate rocks. The process of contamination of the magma by carbonates can be modelled, using isotopic and chemical data, as a mixing between magma and marbles. Mass exchanges occur at the boundary between the crystallizing magma and marble wall rocks, where endoskarn forms. The contamination of the solidification front of the chamber is very limited. The solidification front and the skarn shell effectively isolate the interior of the magma chamber from new inputs of contaminants from the carbonate wall rocks. Therefore, the main volume of magma, hosted in the magma chamber, did not undergo any significant mass exchange with the wall rocks.     

3D adaptive tomography using Delaunay triangles and Voronoi polygons

The solutions of traveltime inversion problems are often not unique because of the poor match between the raypath distribution and the tomographic grid. However, by adapting the local resolution iteratively, by means of a singular value analysis of the tomographic matrix, we can reduce or eliminate the null space influence on our earth image: in this way, we get a much more reliable estimate of the velocity field of seismic waves. We describe an algorithm for an automatic regridding, able to fit the local resolution to the available raypaths, which is based on Delaunay triangulation and Voronoi tessellation. It increases the local pixel density where the null space energy is low or the velocity gradient is large, and reduces it elsewhere. Consequently, the tomographic image can reveal the boundaries of complex objects, but is not affected by the ambiguities that occur when the grid resolution is not adequately supported by the available raypaths.     

Seismic images and rock properties of the very shallow structure of Campi Flegrei caldera (southern Italy)

In September 2001, an extensive active-seismic investigation (Serapis experiment) was carried out in the Gulfs of Naples and Pozzuoli, with the aim of investigating and reconstructing the shallow crustal structure of the Campi Flegrei caldera, and possibly identifying its feeding system at depth. The present study provides a joint analysis of the very shallow seismic reflection data and tomographic images based on the Serapis dataset. This is achieved by reflection seismic sections obtained by the 3D data gathering and through refined P-velocity images of the shallowest layer of Pozzuoli Gulf (z < 1,000 m). From the refined Vp model, the overall picture of the velocity distribution confirms the presence of a complex arc-shaped anomaly that borders the bay offshore. The deeper part of the anomaly (beneath 700 m, with Vp > 3,500 m/s) correlates with units made up of agglomerate tuffs and interbedded lava, which form the southern edge of the caldera, which was probably formed following the two large ignimbritic eruptions that marked the evolutionary history of the area under study. The upper part of the anomaly that tends to split into two parallel arcs is correlated with dikes, volcanic mounds and hydrothermal alteration zones noted in previous shallow reflection seismic analyses. The depth of the transition between the upper and lower parts of the anomaly is characterized by an abrupt Vp increase on the one-dimensional (1D) profiles extracted from the 3D tomographic model and by the presence of a strong reflector located at about 0.6/0.7 s Two Way Time (TWT) on Common Mid Point gathers. The move-out velocity analysis and stack of the P–P and P–S reflections at the layer bottom allowed to estimate relatively high Vp/Vs values (3.7 ± 0.9). This hypothesis has been tested by a theoretical rock physical modeling of the Vp/Vs ratio as a function of porosity suggesting that the shallow layer is likely formed by incoherent, water saturated, volcanic and marine sediments that filled Pozzuoli Bay during the post-caldera activity.     

Prediction of response spectra via real-time earthquake measurements

The development and implementation of an earthquake early warning system (EEWS), both in regional or on-site configurations can help to mitigate the losses due to the occurrence of moderate-to-large earthquakes in densely populated and/or industrialized areas. The capability of an EEWS to provide real-time estimates of source parameters (location and magnitude) can be used to take some countermeasures during the earthquake occurrence and before the arriving of the most destructive waves at the site of interest. However, some critical issues are peculiar of EEWS and need further investigation: (1) the uncertainties on earthquake magnitude and location estimates based on the measurements of some observed quantities in the very early portion of the recorded signals; (2) the selection of the most appropriate parameter to be used to predict the ground motion amplitude both in near- and far-source ranges; (3) the use of the estimates provided by the EEWS for structural engineering and risk mitigation applications.In the present study, the issues above are discussed using the Campania–Lucania region (Southern Apennines) in Italy, as test-site area. In this region a prototype system for earthquake early warning, and more generally for seismic alert management, is under development. The system is based on a dense, wide dynamic accelerometric network deployed in the area where the moderate-to-large earthquake causative fault systems are located.The uncertainty analysis is performed through a real-time probabilistic seismic hazard analysis by using two different approaches. The first is the Bayesian approach that implicitly integrate both the time evolving estimate of earthquake parameters, the probability density functions and the variability of ground motion propagation providing the most complete information. The second is a classical point estimate approach which does not account for the probability density function of the magnitude and only uses the average of the estimates performed at each seismic station.Both the approaches are applied to two main towns located in the area of interest, Napoli and Avellino, for which a missed and false alarm analysis is presented by means of a scenario earthquake: an M 7.0 seismic event located at the centre of the seismic network.Concerning the ground motion prediction, attention is focused on the response spectra as the most appropriate function to characterize the ground motion for earthquake engineering applications of EEWS.     

A one-dimensional viscoelastic and viscoplastic constitutive approach to modeling the delayed behavior of clay and organic soils

Accurate modeling of the time-dependent behavior of geomaterials is of great importance in a number of engineering structures interacting with soft, highly compressible clay layers or with organic clays and peats. In this work, a uniaxial constitutive model, based on Perzyna’s overstress theory and directly extendible to multiaxial stress conditions, is formulated and validated. The proposed constitutive approach essentially has three innovative aspects. The first concerns the implementation of two viscoplastic mechanisms within Perzyna’s theory in order to distinguish between short-term (quasi-instantaneous) and long-term plastic responses. Similarly, elastic response is simulated by combining an instantaneous and a long-term viscous deformation mechanism. The second innovative aspect concerns the use of a bespoke logarithmic law for viscous effects, which has never been used before to simulate delayed soil behavior (as far as the authors are aware). The third concerns the model’s extensive validation by simulating a number of different laboratory test results, including conventional and unconventional oedometer tests with small and large load increments/decrements and wide and narrow loading/unloading cycles, constant rates of stress and strain tests, and oedometer tests performed in a Rowe consolidation cell with measurement of pore pressure dissipation.     

Effects of short flexible seagrass Zostera noltei on flow,erosion and deposition processes determined using flume experiments

Innovative flume experiments were conducted in a recirculating straight flume. Zostera noltei meadows were sampled in their natural bed sediments in the field at contrasting stages of their seasonal growth. The aims of this study were: (i) to quantify the combined effects of leaf flexibility and development characteristics of Zostera noltei canopies on their interaction with hydrodynamics; and (ii) to quantify the role of Zostera noltei meadows in suspended sediment trapping and bed sediment resuspension related with changes in hydrodynamic forcing caused by the seasonal development of seagrasses. Velocity within the canopy was significantly damped. The attenuation in velocity ranged from 34 to 87% compared with bare sediments and was associated with a density threshold resulting from the flow‐induced canopy reconfiguration. The reduction in flow was higher in dense canopies at higher velocities than in less dense canopies, in which the reduction in flow was greater at low velocities. These contrasted results can be explained by competition between a rough‐wall boundary layer caused by the bed and a shear layer caused by the canopy. The velocity attenuation was associated with a two to three‐fold increase in bottom shear stress compared with unvegetated sediment. Despite the increase in near‐bed turbulence, protection of the sediment against erosion increased under a fully developed meadow, while sediment properties were found to be the main factor controlling erosion in a less developed meadow. Deposition fluxes were higher on the vegetated bed than on bare sediments, and these fluxes increased with leaf density. Fewer freshly deposited sediments were resuspended in vegetated beds, resulting in an increase in net sediment deposition with meadow growth. However, in the case of a very high leaf area index, sediment was mostly deposited on leaves, which facilitated subsequent resuspension and resulted in less efficient sediment trapping than in the less developed meadow.