Passive Seismology and Deep Structure in Central Italy

—In the last decade temporary teleseismic transects have become a powerful tool for investigating the crustal and upper mantle structure. In order to gain a clearer picture of the lithosphere-asthenosphere structure in peninsular Italy, between 1994 and 1996, we have deployed three teleseismic transects in northern, central, and southern Apennines, in the framework of the project GeoModAp (European Community contract EV5V-CT94–0464). Some hundreds of teleseisms were recorded at each deployment which lasted between 3 and 4 months. Although many analyses are still in progress, the availability of this high quality data allowed us to refine tomographic images of the lithosphere-asthenosphere structure with an improved resolution in the northern and central Apennines, and to study the deformation of the upper mantle looking at seismic anisotropy through shear-wave splitting analysis. Also, a study of the depth and geometry of the Moho through the receiver function technique is in progress. Tomographic results from the northernmost 1994 and the central 1995 teleseismic experiments confirm that a high-velocity anomaly (HVA) does exist in the upper 200–250 km and is confined to the northern Apenninic arc. This HVA, already interpreted as a fragment of subducted lithosphere is better defined by the new temporary data, compared to previous works, based only on data from permanent stations. No clear high-velocity anomalies are detected in the upper 250 km below the central Apennines, suggesting either a slab window due to a detachment below southern peninsular Italy, or a thinner, perhaps continental slab of Adriatic lithosphere not detectable by standard tomography. We found clear evidence of seismic anisotropy in the uppermost mantle, related to the main tectonic processes which affected the studied regions, either NE–SW compressional deformation of the lithosphere beneath the mountain belt, or arc-parallel asthenospheric flow (both giving NW–SE fast polarization direction), and successive extensional deformation (～E–W trending) in the back-arc basin of northern Tyrrhenian and Tuscany. Preliminary results of receiver function studies in the northern Apennines show that the Moho depth is well defined in the Tyrrhenian and Adriatic regions while its geometry underneath the mountain belt is not yet well constrained, due to the observed high complexity.     

Mechanistic and Kinetic Study of the Gas-Phase Reaction of Atomic Chlorine with Cyclohexanone using an Absolute and a Relative Technique; Influence of Temperature

The reaction of Cl with cyclohexanone (1) was investigated, for the first time, as a function of temperature (273–333 K) and at a low total pressure (1 Torr) with helium as a carrier gas using a discharge flow-mass spectrometry technique (DF-MS). The resulting Arrhenius expression is proposed, k ₁= (7.7 ± 4.1) × 10^–10 exp[–(540 ± 169)/T]. We also report a mechanistic study with the quantitative determination of the products of the reaction of Cl with cyclohexanone. The absolute rate constant derived from this study at 1 Torr of total pressure and room temperature is (1.3 ± 0.2) × 10^–10 cm³ molecule^–1 s^–1. A yield of 0.94 ± 0.10 was found for the H-abstraction channel giving HCl. In relative studies, using a newly constructed relative rate system, the decay of cyclohexanone was followed by gas chromatography coupled with flame-ionisation detection. These relative measurements were performed at atmospheric pressure with synthetic air and room temperature. Rate constant measured using the relative method for reaction (1) is: (1.7 ± 0.3) × 10^–10 cm³ molecule^–1 s^–1. Finally, results and atmospheric implications are discussed and compared with the reactivity with OH radicals.     

A Logistic Regression Model Applied to Evaluate the Influence of Operating Time of AgI Ground Acetonic Generators on the Size and Hardness of Hail

In this paper we study the effect of operating time of AgI ground acetonic generatorsbefore hailing on the hail characteristics (size and hardness), and hailfall crop damages.The study was carried out in a large area of northern Spain over an area of 12,000 km².Data are available from 1,984 hailstorms that occurred from May to September in theperiod 1982–1987. By using several Stepwise Logistic Regression Models, a statisticalsignificant (p < 0.05) decrease shows up in hailfall crop damage due to hail prevention.This effect is due to the influence of ground seeding on the hardness and mainly on thesize of hailstones.     

Morphological and geological aspects related to large slope failures on oceanic islands: The huge La Orotava landslides on Tenerife, Canary Islands

Huge volcanic landslides are one of the most hazardous geomorphological processes that can occur during the evolution of volcanic ocean islands. The causes of these phenomena, however, are very complex and combine non-volcanic and volcanic factors. In the Canary Islands, more than 20 events have been detected during the last decades. A detailed analysis was carried out for La Orotava amphitheatre on Tenerife in order to understand the relationship between geomorphological and geological aspects and huge volcanic landslides. The results indicated four major features that play a significant role in such mass movements: deep erosive canyons, high coastal cliffs, widespread residual soils and structural axes. High coastal cliffs and deep erosive canyons locally reduce the stability conditions and control both the seaward and the lateral boundary of the landslide. Weak residual soils formed above phonolitic pyroclastic deposits occur repeatedly in the stratigraphic column of La Orotava and are characterised by their large extent. Thus, one of these soils may have evolved into the slip surface of the failure. Part of the head scarp of the amphitheatre is defined by a volcanic rift zone, as indicated by the measurement of dike orientation and a density map of eruptive vents. The four features are not able to trigger a failure, but to destabilise the volcano flank and determine the boundary of the slide. Therefore, information on depth and orientation of canyons; location and height of coastal cliffs; stratigraphic repetition, extension and thickness of residual soils and orientation and density of dikes and eruptive vents along structural axes should be incorporated into a hazard assessment on large landslides on volcanic islands.     

Chemistry and trophic evolution of Lake Lugano in relation to nutrient budget

Chemical studies performed in the last 50 years on the northern and southern basins of Lago di Lugano are reviewed and discussed in relation to the phosphorus and nitrogen loads from the drainage area.Both basins became eutrophic in the fifties as a consequence of the dense population and industrial activity in the drainage area; the effect of these was aggravated by the meromictic condition of the layer below 100 m in the northern basin.The reduction of phosphorus loads in progress since 1976 has resulted in a significant improvement in the chemical and biological condition of the southern basin and the upper 100 m of water in the northern basin. On the other hand, the balance between dissolved oxygen and reducing substances in the northern basin is shifting toward a decrease of the net oxygen concentration, partly as a consequence of the unusually dry conditions of the last three years.A reduction in phosphorus load down to 18 and 22 t a^–1 in the northern and southern basins respectively is still necessary in order to reduce the lake phosphorus concentration to 30–35 µg O l^–1.     

Stochastic modeling of seismic surface rotations

In this paper, a stochastic analysis of surface rotations during earthquakes is presented. The surface motion is modeled by a spacetime random field. A method to obtain rotation based on direct differentiation of the random field is proposed with a reference to a second method based on wave decomposition. The first method leads to a spectral density of surface rotations in terms of point translation spectral density, coherence function and apparent waves velocity, while the second method formulates the rotational spectrum in terms of point translation spectral density and wave parameters. The advantages and disadvantages of both methods are discussed in detail.On leave from: Faculty of Civil Engineering, Technical University, ul. Katowicka 48, 45–951 Opole Poland.     

Correlation of atmospheric occurences over the United States with some physical and chemical parameters. Part I: Frequences of thunderstorms

Summary A multiple regression analysis has been carried out to obtain some approximate insight into conditions which might favour the occurence of thunderstorms, in terms of certain parameters measured on the ground. It is thought that annual thunderstorm frequencies may largely depend on local temperature parameters and deviations of precipitable water vapour from equilibrium values.Contribution of the «Centro Nucleazione Aerosoli» of the National Research Council of Italy, Via Vettore 4 (Monte Sacro),Roma.