Simulation of a Stably Stratified Atmospheric Boundary Layer Using One-Dimensional Turbulence

One-dimensional turbulence (ODT) is a single-column simulation in which vertical motions are represented by an unsteady advective process, rather than their customary representation by a diffusive process. No space or time averaging of mesh-resolved motions is invoked. Molecular-transport scales can be resolved in ODT simulations of laboratory-scale flows, but this resolution of these scales is prohibitively expensive in ODT simulations of the atmospheric boundary layer (ABL), except possibly in small subregions of a non-uniform mesh.Here, two methods for ODT simulation of the ABL on uniform meshes are described and applied to the GABLS (GEWEX Atmospheric Boundary Layer Study; GEWEX is the Global Energy and Water Cycle Experiment) stable boundary-layer intercomparison case. One method involves resolution of the roughness scale using a fixed eddy viscosity to represent subgrid motions. The other method, which is implemented at lower spatial resolution, involves a variable eddy viscosity determined by the local mesh-resolved flow, as in multi-dimensional large-eddy simulation (LES). When run at typical LES resolution, it reproduces some of the key high-resolution results, but its fidelity is lower in some important respects. It is concluded that a more elaborate empirically based representation of the subgrid physics, closely analogous to closures currently employed in LES of the ABL, might improve its performance substantially, yielding a cost-effective ABL simulation tool. Prospects for further application of ODT to the ABL, including possible use of ODT as a near-surface subgrid closure framework for general circulation modeling, are assessed.     

Evaluating a modified point-based method to downscale cell-based climate variable data to high-resolution grids

To address the demand for high spatial resolution gridded climate data, we have advanced the Daymet point-based interpolation algorithm for downscaling global, coarsely gridded data with additional output variables. The updated algorithm, High-Resolution Climate Downscaler (HRCD), performs very good downscaling of daily, global, historical reanalysis data from 1° input resolution to 2.5 arcmin output resolution for day length, downward longwave radiation, pressure, maximum and minimum temperature, and vapor pressure deficit. It gives good results for monthly and yearly cumulative precipitation and fair results for wind speed distributions and modeled downward shortwave radiation. Over complex terrain, 2.5 arcmin resolution is likely too low and aggregating it up to 15 arcmin preserves accuracy. HRCD performs comparably to existing daily and monthly US datasets but with a global extent for nine daily climate variables spanning 1948–2006. Furthermore, HRCD can readily be applied to other gridded climate datasets.     

Regional‐scale sedimentation process models from airborne gamma ray remote sensing and digital elevation data

Airborne gamma ray survey data were used to provide information on potassium, thorium and uranium concentrations in surface soil and rock in arid central Australia. Spatial patterns in these radioelements allow tracing of paths of sediment at catchment scale. Survey elevation data are combined with contour data to produce digital elevation models for terrain analysis, tracing of sediment flow paths and modelling of extreme floods. Gamma ray data show consistent variation with slope, a limited range of drainage areas, and erosion/deposition models derived from the conservation of mass equation. Supply‐limited sediment transport models give a reasonable reproduction of observed radioelement distribution but some elements of the distribution pattern reflect the area inundated by 500–1000 year floods rather than the effects of simple downslope movement. Partial area sediment supply models are derived by downstream accumulation of erosion and deposition rates calculated using the conservation of mass equation with transport laws based on slope alone and stream power. Comparison with observed radioelement patterns suggests that both transport laws apply in different parts of the landscape. Regional‐scale sediment transport models will require a range of models depending on location in the landscape and event frequency. This approach may allow estimation of sediment delivery ratios. Copyright © 2001 John Wiley & Sons, Ltd.     

Sedimentological and provenance response to Cambrian closure of the Clymene ocean: The upper Alto Paraguai Group,Paraguay belt,Brazil

Final Gondwana amalgamation was marked by the closure of the Neoproterozoic Clymene ocean between the Amazonia craton and central Gondwana. The events which occurred in the last stage of this closure were recorded in the upper Alto Paraguai Group in the foreland of the Paraguay orogen. Outcrop-based facies analysis of the siliciclastic rocks of upper Alto Paraguai Group, composed of the Sepotuba and Diamantino Formations, was carried out in the Diamantino region, within the eastern part of the Barra dos Bugres basin, Mato Grosso state, central-western Brazil. The Sepotuba Formation is composed of sandy shales with planar to wave lamination interbedded with fine-grained sandstone with climbing ripple cross-lamination, planar lamination, swaley cross-stratification and tangential to sigmoidal cross-bedding with mud drapes, related to marine offshore deposits. The lower Diamantino Formation is composed of a monotonous, laterally continuous for hundreds of metres, interbedded siltstone and fine-grained sandstone succession with regular parallel lamination, climbing ripple cross-lamination and ripple-bedding interpreted as distal turbidites. The upper part of this formation consists of fine to medium-grained sandstones with sigmoidal cross-bedding, planar lamination, climbing ripple cross-lamination, symmetrical to asymmetrical and linguoid ripple marks arranged in lobate sand bodies. These facies are interbedded with thick siltstone in coarsening upward large-scale cycles related to a delta system. The Sepotuba Formation characterises the last transgressive deposits of the Paraguay basin representing the final stage of a marine incursion of the Clymene ocean. The progression of orogenesis in the hinterland resulted in the confinement of the Sepotuba sea as a foredeep sub-basin against the edge of the Amazon craton. Turbidites were generated during the deepening of the basin. The successive filling of the basin was associated with progradation of deltaic lobes from the southeast, in a wide lake or a restricted sea that formed after 541 ± 7 Ma. Southeastern to east dominant Neoproterozoic source regions were confirmed by zircon grains that yielded ages around 600 to 540 Ma, that are interpreted to be from granites in the Paraguay orogen. This overall regressive succession recorded in the Alto Paraguai Group represents the filling up of a foredeep basin after the final amalgamation of western Gondwana in the earliest Phanerozoic.     

Dissolved nitrous oxide (N2O) dynamics in agricultural field drains and headwater streams in an intensive arable catchment

Indirect nitrous oxide (N₂O) emissions produced by nitrogen (N) leaching into surface water and groundwater bodies are poorly understood in comparison to direct N₂O emissions from soils. In this study, dissolved N₂O concentrations were measured weekly in both lowland headwater streams and subsurface agricultural field drain discharges over a 2‐year period (2013–2015) in an intensive arable catchment, Norfolk, UK. All field drain and stream water samples were found to have dissolved N₂O concentrations higher than the water–air equilibrium concentration, illustrating that all sites were acting as a net source of N₂O emissions to the atmosphere. Soil texture was found to significantly influence field drain N₂O dynamics, with mean concentrations from drains in clay loam soils (5.3 μg N L^?1) being greater than drains in sandy loam soils (4.0 μg N L^?1). Soil texture also impacted upon the relationships between field drain N₂O concentrations and other water quality parameters (pH, flow rate, and nitrate (NO₃) and nitrite (NO₂) concentrations), highlighting possible differences in N₂O production mechanisms in different soil types. Catchment antecedent moisture conditions influenced the storm event mobilisation of N₂O in both field drains and streams, with the greatest concentration increases recorded during precipitation events preceded by prolonged wet conditions. N₂O concentrations also varied seasonally, with the lowest mean concentrations typically occurring during the summer months (JJA). Nitrogen fertiliser application rates and different soil inversion regimes were found to have no effect on dissolved N₂O concentrations, whereas higher N₂O concentrations recorded in field drains under a winter cover crop compared to fallow fields revealed cover crops are an ineffective greenhouse gas emission mitigation strategy. Overall, this study highlights the complex interactions governing the dynamics of dissolved N₂O concentrations in field drains and headwater streams in a lowland intensive agricultural catchment.     

Electronic environments in carrollite, CuCo2S4, determined by soft X-ray photoelectron and absorption spectroscopy

Fracture surfaces of a natural carrollite specimen have been characterised by synchrotron and conventional X-ray photoelectron spectroscopy and near-edge X-ray absorption spectroscopy. For the synchrotron X-ray measurements, the mineral surfaces were prepared under clean ultra high vacuum and were unoxidised. The characterisation was undertaken primarily to establish unequivocally the oxidation state of the Cu in the mineral, but also to obtain information on the electronic environments of the Co and S, and on the surface species. Experimental and simulated Cu L_2,3-edge absorption spectra confirmed an oxidation state of Cu^I, while Co 2p photoelectron and Co L_2,3 absorption spectra were largely consistent with the Co^III established previously by nuclear magnetic resonance spectroscopy. S 2p photoelectron spectra provided no evidence for S to be present in the bulk in more than one state, and were consistent with an oxidation state slightly less negative than S^-II. Therefore it was concluded that carrollite can be best represented by Cu^ICo^III₂(S₄)^-VII. The Cu^I oxidation state is in agreement with that expected for Cu tetrahedrally coordinated by S, but is in disagreement with the Cu^II deduced previously from some magnetic, magnetic resonance and Cu L-edge X-ray absorption spectroscopic measurements. A significant concentration of S species with core electron binding energies both lower and higher than the bulk value were formed at fracture surfaces, and these entities were assigned to monomeric and oligomeric surface S species. The density of Cu d states calculated for carrollite differed from that previously reported but was consistent with the observed Cu L₃ X-ray absorption spectrum. The initial oxidation of carrollite in air under ambient conditions was confirmed to be congruent, unlike the incongruent reaction undergone by a number of non-thiospinel sulfide minerals.     

Effects of sampling effort on the estimation of spatial gradients in a tropical reservoir impacted by an oil refinery

We investigated the effects of increase in sampling effort (30-1043 sampling points) on the accuracy of assessment of the spatial patterns of surface-water quality in a eutrophic tropical reservoir. The investigation was carried out during the dry season, when previous investigations showed that the spatial heterogeneity is more stable. A multi-parameter Yellow Springs Instruments probe coupled to a TechGeo D-GPS was used. This system is equipped to measure and store in a continuous recording mode, several physical and chemical parameters linked to geographical coordinates obtained with a precision of less than 1 m. We used different geostatistical approaches to determine the optimal number of sampling points required to reflect the real spatial patterns of water quality in the system. This approach was tested in a small tropical reservoir (Ibirité) that receives effluents from an oil refinery (the state-owned REGAP oil refinery, PETROBRAS) located near the city of Belo Horizonte. The study showed not only that the spatial patterns of water quality are significantly affected by sampling effort but also it was demonstrated that the establishment of an adequate sampling program is a critical point for the precise identification of source points of pollution. The results of this investigation enabled us to demonstrate the potential uses and limits of this method for rapid assessment of the water quality of lakes and reservoirs that receive external inputs of water contaminants or nutrients.     

Nd isotopic evidence for the position of southernmost Indian terranes within East Gondwana

Sm-Nd model ages of orthopyroxene-bearing massif charnockites from the Cardamom Hills Massif and adjoining supracrustal rocks from the Kerala Khondalite Belt in southernmost India are used to infer some of the relationships within these rocks and between them and neighboring areas. Most of these rocks have model ages of 2.1–2.8 Ga with most charnockites in the range 2.2–2.6 Ga. Thus, 3.0–3.4 Ga Archean rocks to their north did not contribute material to either suite and the two suites may have been juxtaposed after formation of the supracrustal rocks. The similarity of Sm-Nd isotope systems in the two units studied here supports an argument that the massif charnockites were the primary sole source of the detritus incorporated into the supracrustal rocks. A cordierite gneiss, representative of a relatively minor lithology in the supracrustal belt, has a model age of 1.3 Ga. The protolith of this gneiss not only formed from much younger material than the rest of the belt but also formed significantly after the other metasedimentary rocks. The source material of the gneiss protolith may have been located in the Wanni and Vijayan Complexes of Sri Lanka. The overlap of the model ages of rocks in this area and those in the Highland Complex of Sri Lanka supports the notion that these two sets of rocks were joined to each other in Gondwana. They belong to a belt that ran from Antarctica through Sri Lanka and India into Madagascar. This belt was involved in Pan-African tectono-metamorphism, as reflected in the 550 Ma age of the last, granulite-forming, event throughout the belt.     

Taxonomic Studies on a New Marine Ciliate, Apocoleps magnus gen. nov., spec. nov. （Ciliophora, Colepidae）, Isolated from Qingdao, China

The morphology and infraciliature of a new marine colepid ciliate, Apocoleps magnus gen. nov., spec. nov., are described based on living observations and silver impregnations. The new genus Apocoleps is characterized by having 8 (vs. 6 in most other related genera) armour tiers, spines at both ends of the cell, 3 adoral organelles and plates with 4 reniform uni-windows. Apocoleps magnus spec. nov. is defined by the following features: body elongated and slightly curved, about 100–120μm× 35–45 μm in vivo; an...     

Mechanisms of orthopyroxene dissolution in silica-undersaturated melts at 1 atmosphere and implications for the origin of silica-rich glass in mantle xenoliths

Experiments dissolving orthopyroxene (En₉₃) in a variety of Si-undersaturated alkaline melts at 1 atmosphere and variable f _O2 demonstrate that orthopyroxene dissolves to form olivine, Si-rich melt and clinopyroxene. These phases form a texturally and chemically distinct boundary layer around the partly dissolved orthopyroxene crystals. The occurrence of clinopyroxene in the boundary layer is due to inward diffusion of Ca from the solvent melt to the boundary layer causing clinopyroxene saturation. Compositional profiles through the solvent and the boundary layer for a number of experiments demonstrate rapid diffusion of cations across the boundary layer – solvent interface. SiO₂ diffuses outward from the boundary layer whereas CaO and Al₂O₃ diffuse toward the Si-enriched boundary layer melt. The rate of Al diffusion is slower under reducing conditions compared to the rates in experiments performed in air. Concentrations of FeO and MgO in the boundary layer and solvent are approximately equal indicating rapid diffusion and attainment of equilibrium despite ongoing crystallisation of clinopyroxene within the boundary layer. The behaviour of Na₂O and K₂O is strongly affected by f _O2. Under reducing conditions Na₂O and K₂O concentrations are approximately equal in the boundary layer and solvent indicating normal diffusion down the concentration gradient and attainment of equilibrium. Under oxidising conditions, K₂O and to a lesser extent Na₂O, have compositional profiles indicative of uphill diffusion likely due to their preference for more polymerised Si- and Al-rich melts. Under reduced conditions Al-enrichment in the boundary layer melt is not as extreme and uphill diffusion did not occur. The composition of the solvent melt after the experiments indicates that it was contaminated by the boundary layer by convective mixing due to the onset of hydrodynamic instabilities brought on by density and viscosity contrasts between the two melts. Despite using a wide variety of solvent melt compositions we find that the boundary layer melts converge toward a common composition at high SiO₂ contents. The composition of glass generated by orthopyroxene dissolution at 1 atmosphere is similar in many respects to Si-rich glass found in many orthopyroxene-rich mantle xenoliths that have been attributed to high pressure in situ processes including mantle metasomatism. The results of this study suggest that at least some Si-rich melts are likely to have formed by dissolution of xenolith orthopyroxene at low pressure possibly by their Si-undersaturated host magmas. Received: 30 August 1996 / Accepted: 15 April 1998