Chromium Removal through Biosorption and Bioaccumulation by Bacteria from Tannery Effluents Contaminated Soil

Four bacterial isolates (two resistant and two sensitive to chromium) were isolated from soil contaminated with tannery effluents at Jajmau (Kanpur), India, and were identified by 16S rDNA gene sequencing as Stenotrophomonas maltophilia, Exiguobacterium sp., Pantoea sp., and Aeromonas sp. Biosorption of chromium by dried and living biomasses was determined in the resistant and sensitive isolates. The effect of pH, initial metal concentration, and contact time on biosorption was studied. At pH 2.5 the living biomass of chromium resistant isolate Exiguobacterium sp. ZM‐2 biosorbed maximum amount of Cr⁶⁺ (29.8 mg/g) whereas the dried biomass of this isolate biosorbed 20.1 mg/g at an initial concentration of 100 mg/L. In case of chromate sensitive isolates, much difference was not observed in biosorption capacities between their dried and living biomasses. The maximum biosorption of Cr³⁺ was observed at pH 4.5. However, biosorption was identical in resistant and sensitive isolates. The data on chromium biosorption were analyzed using Langmuir and Freundlich isotherm model. The biosorption data of Cr⁶⁺ and Cr³⁺ from aqueous solution were better fitted in Langmuir isotherm model compared to Freundlich isotherm model. Metal recovery through desorption was observed better with dried biomasses compared to the living biomasses for both types of chromium ions. Bioaccumulation of chromate was found higher in chromate resistant isolates compared to the chromate sensitive isolates. Transmission electron microscopy confirmed the accumulation of chromium in cytoplasm in the resistant isolates.     

Groundwater flow modelling of Hindon-Yamuna interfluve region, Western Uttar Pradesh

The study area Hindon -Yamuna interfluve region is underlain by a thick pile of unconsolidated Quaternary alluvial deposits and host multiple aquifer system. Excessive pumping in the last few decades, mainly for irrigation, has resulted in a significant depletion of the aquifer. Therefore, proper groundwater management of Hindon-Yamuna interfluve region is necessary. For effective groundwater management of a basin it is essential that careful zone budget study should be carried out. Keeping this in view, groundwater flow modelling was attempted to simulate the behavior of flow system and evaluate zone budget. Visual MODFLOW, pro 4.1 is used in this study to simulate groundwater flow. The model simulates groundwater flow over an area of about 1345 km² with a uniform grid size of 1000 m by 1000 m and contains three layers, 58 rows and 37 columns. The horizontal flows, seepage losses from unlined canals, recharge from rainfall and irrigation return flows were applied using different boundary packages available in Visual MODFLOW, pro 4.1. The river — aquifer interaction was simulated using the river boundary package. Simulated pumping rates of 500 m³/day, 1000 m³/day and 1500 m³/day were used in the pumping well package.The zone budget for the steady state condition of study area indicated that the total annual direct recharge is 416.10 MCM and the total annual groundwater draft through pumping is of the order of 416.63 MCM. Two scenarios were considered to predict aquifer system response under different conditions. Sensitivity analysis on model parameters was conducted to quantitatively evaluate the impact of varying model inputs. Based on the results obtained from the sensitivity analysis, it was found that the model is more sensitive to hydraulic conductivity and recharge parameter. Present study deals with importance of groundwater modelling for planning, design, implementation and management of groundwater resources.     

Fresh-water lenses and practical limitations of their three-dimensional simulation

Fresh-water lenses are the major sources of water supply in many atoll islands in the Pacific and Indian Oceans, particularly in dry seasons. Several two- and three-dimensional models are currently available for the simulation of atoll-island aquifers; however, 2D models cannot include 3D spatial variability of material properties, they must simplify the boundary conditions, and they cannot correctly simulate pumping wells. In an attempt to overcome these difficulties, a 3D model, SALTFLOW, was adopted for the simulation of Home Island in the Indian Ocean. This exercise required a discretisation on the order of a few metres and time steps of a few hours requiring significantly high CPU times. High CPU demand proved to be a difficult challenge but cannot be considered a serious practical limitation with today's advanced computers. The exhaustive data demands of the model (e.g., 3D distributions of hydraulic conductivity, porosity, dispersivities, and spatial and temporal variations of recharge and extraction rates) proved to be more problematical. Although the Home Island data set is unusually comprehensive by any standards, nonetheless the quality and quantity of the available data proved inadequate to meet the calibration needs of a highly karstic aquifer system. The Home Island modeling demonstrates the practical limitations of 3D models. It raises the concern that our ability to develop computer codes capable of simulating complex systems now exceeds our ability to supply the input data necessary for reliable calibration. Finally, the paper demonstrates the importance of the transient calibration in reliable simulation of various management options and emphasises that transient calibration should be considered as an integral part of any similar 2D or 3D modeling. Electronic Publication     

A long-term trend in precipitation of different spatial regions of Bangladesh and its teleconnections with El Niño/Southern Oscillation and Indian Ocean Dipole

A long-term (1948 to 2012) trend of precipitation (annual, pre-monsoon, monsoon, and post-monsoon seasons) in Bangladesh was analyzed in different regions using both parametric and nonparametric approaches. Moreover, the possible teleconnections of precipitation (annual and monsoon) variability with El Niño/Southern Oscillation (ENSO) episode and Indian Ocean Dipole (IOD) were investigated using both average and individual (both positive and negative) values of ENSO index and IOD. Our findings suggested that for annual precipitation, a significant increasing monotonic trend was found in whole Bangladesh (4.87 mm/year), its western region (5.82 mm/year) including Rangpur (9.41 mm/year) and Khulna (4.95 mm/year), and Sylhet (10.12 mm/year) and Barisal (6.94 mm/year) from eastern region. In pre-monsoon, only Rangpur (2.88 mm/year) showed significant increasing trend, while in monsoon, whole Bangladesh (3.04 mm/year), Sylhet (7.17 mm/year), and Barisal (6.94 mm/year) showed similar trend. In post-monsoon, there was no significant trend. Our results also revealed that the precipitation (annual or monsoon) of whole Bangladesh and almost all of the spatial regions did not show any significant correlation with ENSO events, whereas the average IOD values showed significant correlation only in monsoon precipitation of western region. The individual positive IODs showed significant correlation in whole Bangladesh, western region, and its two divisions (Rajshahi and Khulna). So, in the context of Bangladesh climate, IOD has the more teleconnection to precipitation than that of ENSO. Our findings indicate that the co-occurrence of ENSO and IOD events may suppress their influence on each other.

     

Rock mass rating and Kinematic analysis for slope stability investigation of Utari dam,Lalitpur district,Uttar Pradesh

Rock mass characterization of Utari dam in Lalitpur district of Uttar Pradesh was done to identify different stability classes of rock mass. For better stability of Utari dam, foundation conditions were carefully studied by detailed field investigations of the site supplemented by laboratory tests. During feasibility and preliminary stages, rock mass characterization of slopes was conducted to identify the vulnerable zones of failure. Rock mass characterization was done by compilation of information obtained from intact rock as well as from rock mass to determine its grade and long term slope stability of the site. On the basis of Rock Mass Rating (RMR) and Geological Strength Index (GSI) slope stability is identified which lies under good quality rock mass. Kinematic analysis was conducted to find out the probability for different types of structurally controlled slope failure. Microscopic analyses were conducted to identify the degree of chemical alteration of feldspar. Clay formation by sericitization along joint planes is harmful for the stability of dam structure. Remedial measures must be taken to reduce the extent of chemical alteration. Granitoids at dam site forms a compact and stable foundation consisting of four sets of joints in which two sets were prominent which are dipping on the upstream side of the dam which reveals good condition on the dam site as leakage from reservoir will be minimum and least up-thrust on the dam structure.     

SMR geomechanics and kinematic analysis near Rasulpur,Fatehpur Sikri,Uttar Pradesh

Slope stability of mine slopes is often associated with safety and economics during excavation. Sandstone is excavated from Rasulpur area of Fatehpur Sikri in Uttar Pradesh for the purpose of crushed, decorative and dimension stones. In the present paper an attempt has been made to characterize the rock slope faces into different stability classes. Characterization is based on geological and geotechnical parameters recorded on the outcrop during field investigation and supplemented by geomechanical properties by the laboratory test for strength of the rock intact. SMR Geomechanics classification is used to identify the stability class and remedial measures are also suggested to reduce any possible hazard. Kinematic analysis of slope was also investigated to determine the probability of any possible structurally controlled failure. On the basis of SMR Geomechanics calculations slope under investigation lies under good stability class i.e. 2a and 2b. Installation of nets during excavation can be done and for better safety spot and systematic rock bolting can be done. Kinematic study reveals that toppling failures may occur, special care must be given to the joint set which can trigger toppling failure.     

Assessing factors affecting drought,earthquake, and flood risk perception: empirical evidence from Bangladesh

Natural Hazards - Understanding household disaster risk perception is crucial to formulate and apply disaster risk reduction strategies. Using survey data from 300 households from three highly...     

Re‐examining green revolution diffusion and factor/input markets in Bangladesh after market liberalization

This paper re‐examines the effect of green revolution (GR) diffusion on factor/inputs demand in Bangladesh using an empirical model that allows for simultaneous determination of factors influencing adoption of GR technology at the current mature stage, as well as access to irrigation. Results reveal some alignments with conventional wisdom as well as few surprises. For example, while an increased demand for major inputs is expected, an increased demand for organic manure is an unexpected positive outcome. The GR adoption rate is significantly higher in villages with access to irrigation and fertile soils and, surprisingly, in infrastructurally underdeveloped villages. Together with other expected findings of GR technology uptake with higher cereal prices and irrigation use encouraged by access to credit, tenurial status and fertile soils, our findings suggest that investment in irrigation and soil conservation, as well as implementing measures to improve cereal prices and provide agricultural credit, could boost GR technology adoption.     

“Shock event”, an impact phenomenon observed in water wells around the Arabian Gulf coastal city Dammam,Saudi Arabia: possible relationship with Sumatra tsunami event of December 26, 2004

A sudden disturbance in water level was recorded by hydrographs monitoring wells in the coastal city Dammam, Saudi Arabia on December 26, 2004. The water level was being recorded from the shallow (1–3 M deep) coastal aquifer at that time. In two wells, this disturbance was observed ~12 h after the Sumatra earthquake/tsunami event of December 26, 2004. The timing of this event is synchronous in two wells near the coast, but an inland well away from the coast line did not show any such disturbance. It is hypothesized that this disturbance, we call it the “shock event”, is resulted by sudden impact of tsunamis traveling in the Arabian Gulf from southeast toward northwest. As the tsunamis propagated, they suddenly impacted the coastal shallow groundwater aquifer resulting in the “shock event”.