Unexpectedly high-PGE chromitite from the deeper mantle section of the northern Oman ophiolite and its tectonic implications

Unusually high, platinum-group element (PGE) enrichments are reported for the first time in a podiform chromitite of the northern Oman ophiolite. The chromitite contains Б.5 ppm of total PGE, being highly enriched in the IPGE subgroup (Ir, Os and Ru) and strongly depleted in the PPGE subgroup (Rh, Pt and Pd). Its platinum-group minerals (PGMs) are classified into three types arranged in order of abundance: (1) sulphides (Os-rich laurite, laurite-erlishmanite solid solution and an unnamed Ir sulphide), (2) alloys (Os-Ir alloy and Ir-Rh alloy), and (3) sulpharsenides (irarsite and hollingworthite). The high PGE concentrations are observed only in a discordant chromitite deep in the mantle section, which has high-Cr# (>0.7) spinel with an olivine matrix. All the other types of chromitite (in the Moho transition zone (MTZ) and concordant pods in the deeper mantle section) are poor in PGEs and tend to have spinels with lower Cr# (up to 0.6). This diversity of chromitite types suggests two stages of magmatic activity were responsible for the chromitite genesis, in response to a switch of tectonic setting. The first is residual from lower degree, partial melting of peridotite, which produced low-Cr#, PGE-poor chromitites at the Moho transition zone and, to a lesser extent, within the mantle, possibly beneath a fast-spreading mid-ocean ridge. The second chromitite-forming event involves higher degree partial melting, which produced high-Cr#, PGE-rich discordant chromitite in the upper mantle, possibly in a supra-subduction zone setting.     

Comparison of arsenic concentrations in simultaneously-collected groundwater and aquifer particles from Bangladesh,India, Vietnam,and Nepal

One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored.     

Optimal and sustainable extraction of groundwater in coastal aquifers

Four examples are investigated for the optimal and sustainable extraction of groundwater from a coastal aquifer under the threat of seawater intrusion. The objectives and constraints of these management scenarios include maximizing the total volume of water pumped, maximizing the profit of selling water, minimizing the operational and water treatment costs, minimizing the salt concentration of the pumped water, and controlling the drawdown limits. The physical model is based on the density-dependent advective-dispersive solute transport model. Genetic algorithm is used as the optimization tool. The models are tested on a hypothetical confined aquifer with four pumping wells located at various depths. These solutions establish the feasibility of simulating various management scenarios under complex three-dimensional flow and transport processes in coastal aquifers for the optimal and sustainable use of groundwater.     

Petrology and geochemistry of greywackes from Goa-Dharwar sector,western Dharwar Craton: Implications for volcanoclastic origin

Late Archaean Supracrustals of the Goa-Dharwar sector (GDS) are composed of a thick sequence of greywacke sequence with narrow intercalations of quartzite, BIF and carbonates. Mafic volcanics occupy the base of the sequence. The greywackes are predominantly tuffacious containing chlorite-sericite and hornblende. Arkosic variations containing biotite dominate the western part of the sector. Fine-grained variations occur as isolated narrow lenses within other types of greywackes. The conglomeratic greywackes are localized along the western and the eastern margins of the sector. All of the greywackes are all typically immature containing coarser clasts of mostly plagioclase (18–23%) and quartz (32–34%). Lithic fragments of felsic volcanic rocks are common. The matrix is dominated by mafic material. Biotite and amphibole are related to metamorphic recrystallization. Chlorite, sericite, epidote, carbonate and chert are products of the interplay of diagenesis and low-grade metamorphism. Fe-Ti oxide, sphene, apatite and zircon are usual accessories. But for slight enrichment in K₂O, the major element chemistry of the GDS greywackes is similar to the chemistry of Late Archaean greywackes. They also compare in respect of V, Co, Hf contents, K₂O/Na₂O, SiO₂/Al₂O₃, Na₂O/Al₂O₃, Ba/Rb, Th/U, La/Th, Sm/Nd ratios, steep REE patterns with distinct LREE enrichment and HREE depletion. The GDS greywackes however are distinctly enriched in Rb, Ba, Sr, Th, U, Cu, Zr, Ce/Ce* and depleted in Cr, Ni, and Zn. The conglomeritic and biotite bearing verities contain considerable proportions of clasts derived from the basement tonalitic/granitic terrain. The common tuffacious greywackes containing hornblende and biotite-sericite however include only volcanic clasts and bear evidence of derivation from submarine weathering of predominantly felsic volcanics erupted on a large scale to form a magmatic arc in the later stages of geosynclinal deposition. Geochemical data suggest that the GDS greywackes were laid down in progressively changing basin geometry from a passive to active continental margin and island arc setting.     

Studying the impacts of groundwater evolution on the environment,west Qena city,Egypt

The current research has been conducted to evaluate groundwater aquifers qualitatively in the area located in the Western side of Qena city. The Quaternary aquifer represents the main groundwater source in the study area. It exists under unconfined to semiconfined conditions at depths varying between 4 m due North and 80 m in the South. The chemical analyses of the groundwater samples indicate that 77% of the total samples are fresh and 20% are brackish, while only 3% are saline. In addition, the iso-salinity contour map indicates that the salinity increases towards the central and northern parts of the study area. The total and permanent hardness increase as water salinity increases and vice versa in case of temporary hardness in the groundwater samples. The chemical water types and the ion ratios indicate meteoric origin of groundwater as well as the dissolution of terrestrial and marine salts. The contribution of recent recharge from the River Nile to a few groundwater wells in the study area varies from low to high. In addition, the most recharge sources are from the precipitation. Nitrate concentrations in groundwater increase towards the central and Northern areas significantly elevated in response to increasing anthropogenic land uses. Much of the solutes and physicochemical parameters in these waters are under the undesirable limits of World Health Organization (WHO) for drinking purpose, and a plot of sodium adsorption ratio versus EC shows that about 23% of the groundwater samples are good water quality, about 45% of groundwater samples are moderate quality, and 23% of the groundwater samples are intermediate water class, while the rest of samples (9%) are out of the range.     

Instability of a streaming jet under the influence of vacuum magnetic fields

The magnetohydrodynamic stability of a streaming liquid cylinder subject to surface tension and pervaded by a magnetic vacuum field has been elaborated for all axisymmetric and non-axisymmetric disturbances. The dispersion relation is obtained and studied analytically and numerically. the streaming has always a destabilizing effect. The axial magnetic fields inside and outside the jet have always stabilizing effects for all perturbations. The transverse magnetic field has a destabilizing effect. However, if the axial field intensity is so high and paramount over that the transverse field, the destabilizing character of the model is suppressed. The latter is satisfied if the Alfvén wave velocity is greater than the equilibrium liquid velocity.     

Approaches for delineating landslide hazard areas using different training sites in an advanced artificial neural network model

The current paper presents landslide hazard analysis around the Cameron area, Malaysia, using advanced artificial neural networks with the help of Geographic Information System (GIS) and remote sensing techniques. Landslide locations were determined in the study area by interpretation of aerial photographs and from field investigations. Topographical and geological data as well as satellite images were collected, processed, and constructed into a spatial database using GIS and image processing. Ten factors were selected for landslide hazard including: 1) factors related to topography as slope, aspect, and curvature; 2) factors related to geology as lithology and distance from lineament; 3) factors related to drainage as distance from drainage; and 4) factors extracted from TM satellite images as land cover and the vegetation index value. An advanced artificial neural network model has been used to analyze these factors in order to establish the landslide hazard map. The back-propagation training method has been used for the selection of the five different random training sites in order to calculate the factor’s weight and then the landslide hazard indices were computed for each of the five hazard maps. Finally, the landslide hazard maps (five cases) were prepared using GIS tools. Results of the landslides hazard maps have been verified using landslide test locations that were not used during the training phase of the neural network. Our findings of verification results show an accuracy of 69%, 75%, 70%, 83% and 86% for training sites 1, 2, 3, 4 and 5 respectively. GIS data was used to efficiently analyze the large volume of data, and the artificial neural network proved to be an effective tool for landslide hazard analysis. The verification results showed sufficient agreement between the presumptive hazard map and the existing data on landslide areas.     

Monitoring disasters with a constellation of satellites – type examples from the International Charter ‘Space and Major Disasters’

In the case of a major disaster, information derived from satellite observation is not only highly useful, it may at times be indispensable because of the damage caused by the disaster to ground infrastructure. The International Charter ‘Space and Major Disasters’ (‘the Charter’) has been one of the primary sources of satellite data for the past 11 years to cover events like floods, fires, tsunamis, ocean storms, earthquakes, volcanic eruptions and oil spills. With the growing membership of the Charter, an increasingly large number of sensors are now available, which can be planned with the required temporal frequency and spectral range to cover a disaster event. Some of the type Charter activation cases are reported in this article to demonstrate the innovative use of multi-satellite imagery for disaster response.     

Smoothed Particle Hydrodynamics for modelling landslide–water interaction problems

Landslides - This work aims to develop a Weakly Compressible Smoothed Particle Hydrodynamics (WCSPH) in-house code for modelling landslide–water interaction problems. While we consider the...