Soil contamination by metals with high ecological risk in urban and rural areas

Industrial development, intensive agriculture and fast urbanization have caused the metal contents of soils to increase to many times the allowable limits. To assess this impact on urban and rural soils, we quantified the Cd, Cr, Cu, Pb, Ni and Zn contents of 258 soil samples from the Recife metropolitan region (RMR). The objectives of the study were to estimate the probability of ecological risk, to determine the spatial pattern of the metals’ accumulation in the soil and to identify potential sources for the metals using a multivariate geostatistical approach. Mean concentrations of Zn, Cr, Pb, Cu, Ni and Cd in soils were 65.2, 17.9, 16.5, 12.8, 6.3 and 1.5 mg kg^?1, respectively. The results demonstrated that the Cd was anthropogenic in origin, the Cr and Ni were lithogenic (natural) in origin and the Cu, Pb and Zn were mixed in origin. Cd contaminated 91% of the samples; the median content of Cd (1.4 mg kg^?1) was three times the quality reference value for soil. The Cd contents of sugarcane fields exceeded the allowable limit (3.0 mg kg^?1) for agricultural areas. The spatial variability of the metals in the RMR showed that metallurgy, cement production, vehicle exhaust and vehicular traffic were the main sources of metals in urban areas, while phosphate-based fertilizers were the main sources in rural areas. More than 80% of the metropolitan region surveyed in the study was at moderate to high ecological risk.     

Study of geothermal water intrusion due to groundwater exploitation in the Puebla Valley aquifer system, Mexico

Significant intrusion of geothermal water into fresh groundwater takes place in the Puebla Valley aquifer system, Mexico. The decline in the potentiometric surface due to the overexploitation of the groundwater induces this intrusion. This hydrological system comprises three aquifers located in Plio-Quaternary volcanic sediments and Mesozoic calcareous rocks. The hydraulic balance of the aquifer shows that the annual output exceeds the natural inputs by 12 million m³. Between 1973 and 2002, a drop in the potentiometric surface, with an 80 m cone of depression, was identified in a 5-km-wide area located southwest of the city of Puebla. Chemical analyses performed on water samples since 1990 have shown an increase in total dissolved solids (TDS) of more than 500 mg/L, coinciding with the region showing a cone of depression in the potentiometric surface. A three-dimensional flow and transport model, based on the hydrogeological and geophysical studies, was computed by using the MODFLOW and MT3D software. This model reproduces the evolution of the aquifer system during the last 30 years and predicts for 2010 an additional drawdown in the potentiometric surface of 15 m, and an increase in the geothermal water intrusion.     

Fine sediment transport and accumulations at the mouth of the Seine estuary (France)

A comprehensive study of fine sediment transport in the macrotidal Seine estuary has been conducted, including observations of suspended particulate matter (SPM), surficial sediment, and bathymetric data, as well as use of a three dimensional mathematical model. Tide, river regime, wind, and wave forcings are accounted. The simulated turbidity maximum (TM) is described in terms of concentration and location according to tidal amplitude and the discharge of the Seine River. The TM is mainly generated by tidal pumping, but can be concentrated or stretched by the salinity front. The computed deposition patterns depend on the TM location and are seasonally dependent. The agreement with observations is reasonable, although resuspension by waves may be overestimated. Although wave resuspension is likely to increase the TM mass, it generally occurs simultaneously with westerly winds that induce a transverse circulation at the mouth of the estuary and then disperse the suspended material. The resulting effect is an output of material related to wind and wave events, more than to high river discharge. The mass of the computed TM remains stable over 6 months and independent of the river regime, depending mainly on the spring tide amplitude. Computed fluxes at different cross-sections of the lower estuary show the shift to the TM according to the river flow and point out the rapidity of the TM adjustment to any change of river discharge. The time for renewing the TM by riverine particles has been estimated to be one year.     

Revisiting wintertime cold air intrusions at the east of the Andes: propagating features from subtropical Argentina to Peruvian Amazon and relationship with large-scale circulation patterns

This study investigates the spatial and temporal characteristics of cold surges that propagates northward along the eastern flank of the Andes from subtropical to tropical South America analysing wintertime in situ daily minimum temperature observations from Argentina, Bolivia and Peru and ERA-40 reanalysis over the 1975–2001 period. Cold surges usually last 2 or 3 days but are generally less persistent in the southern La Plata basin compared to tropical regions. On average, three to four cold surges are reported each year. Our analysis reveals that 52 % of cold episodes registered in the south of La Plata basin propagate northward to the northern Peruvian Amazon at a speed of around 20 m s^?1. In comparison to cold surges that do not reach the tropical region, we demonstrate that these cold surges are characterized, before they reach the tropical region, by a higher occurrence of a specific circulation pattern associated to southern low-level winds progression toward low latitudes combined with subsidence and dry condition in the middle and low troposphere that reinforce the cold episode through a radiative effect. Finally, the relationship between cold surges and atmosphere dynamics is illustrated for the two most severe cold intrusions that reached the Peruvian and Bolivian Amazon in the last 20 years.     

Can the faint submillimetre galaxies be explained in the Λ cold dark matter model?

We present predictions for the abundance of submillimetre galaxies (SMGs) and Lyman-break galaxies (LBGs) in the Λ cold dark matter cosmology. A key feature of our model is the self-consistent calculation of the absorption and emission of radiation by dust. The new model successfully matches the LBG luminosity function, as well as reproducing the properties of the local galaxy population in the optical and infrared. The model can also explain the observed galaxy number counts at 850 μm, but only if we assume a top-heavy initial mass function for the stars formed in bursts. The predicted redshift distribution of SMGs depends relatively little on their flux over the range 1–10 mJy, with a median value of   z ≈ 2.0  at a flux of 5 mJy, in good agreement with the recent measurement by Chapman et al. The counts of SMGs are predicted to be dominated by ongoing starbursts. However, in the model these bursts are responsible for making only a few per cent of the stellar mass locked up in massive ellipticals at the present day.     

Throughfall patterns in sugarcane and riparian forest: understanding the effect of sugarcane age and land use conversion

Sugarcane is an annual crop with a dynamic canopy that changes over time mainly because of genetic adaptation. There is uncertainty about the temporal trends of throughfall (TF) in this important commercial crop. In the present paper, we used troughs to measure TF in a third and fourth ratoon and subsequently in a fourth and fifth ratoon. Additional measurements were carried out in an adjacent riparian forest. There were no significant differences between cycles of sugarcane, growth phases and riparian forest. The TF results for ratoon crop and riparian forest in 2011/2012 were 76% and 79.5% of gross rainfall, respectively, while in 2012/2013, they were 79% and 78%, respectively. However, TF was remarkably lower in the riparian forest relative to ratoon from the second half of the culm formation and elongation phase (280 days after harvest) until harvest. Copyright © 2016 John Wiley & Sons, Ltd.     

Observational study of the seasonality of the submonthly and intraseasonal signal over the tropics

Summary Atmospheric variability in outgoing long-wave radiation (OLR) and tropospheric relative vorticity (VOR) over the South American region was studied from 1979 to 1996 using the complex Morlet wavelet function. The analyses focus on spatial variation in intraseasonal and submonthly scales. Scalograms were used to measure submonthly intraseasonal oscillations in convection, which were found to be predominant in the tropical regions. However, 7-day and 15-day oscillations were observed at tropical and extratropical latitudes in spring and winter, indicating that transient disturbances play a more prominent role. Regarding VOR, tropical energy intensities were highest in the spring and summer, whereas subtropical and extratropical energy intensities were highest in the autumn and winter. The dynamics of the 25-day and 45-day VOR oscillations indicates a possible correlation with Rossby waves over the eastern tropical Pacific Ocean, mainly during the summer. During winter, the 7-day and 15-day VOR oscillations are more frequent at higher latitudes and are enhanced along storm tracks. It was also observed that convection amplitudes in the regions of maximum intensity change appreciably from year to year and from season to season, showing that the behavior of the submonthly and intraseasonal oscillations is nonperiodic and correlates strongly with El Ni?o/Southern Oscillation years. These results confirm the efficiency of wavelet analysis for time-scale studies of atmospheric variability.     

Analysis of the Devonian (Frasnian) platform from Belgium: a multi‐faceted approach for basin evolution reconstruction

This study undertakes a multi‐disciplinary approach (sedimentology, carbon isotopes, magnetic susceptibility and thickness distribution) to improve understanding of a major Palaeozoic carbonate platform, the Frasnian platform of Belgium. These combined techniques are used to reconstruct the platform history, which evolved in two main steps. During the first phase, the basin was strongly influenced by faulting, producing notable thickness and facies variations, with open ocean conditions, with good water circulation and no/or limited barrier reef. The second phase of platform development was less influenced by differential subsidence, as indicated by homogeneous facies distribution. However, this platform developed under restricted waters, with low circulation which is likely related to the development of a barrier reef.     

U–Pb zircon chronostratigraphy of early-Pliocene ignimbrites from La Pacana, north Chile: implications for the formation of stratified magma chambers

High spatial resolution U–Pb dates of zircons from two consanguineous ignimbrites of contrasting composition, the high-silica rhyolitic Toconao and the overlying dacitic Atana ignimbrites, erupted from La Pacana caldera, north Chile, are presented in this study. Zircons from Atana and Toconao pumice clasts yield apparent ²³⁸U/²⁰⁶Pb ages of 4.11±0.20 Ma and 4.65±0.13 Ma (2σ), respectively. These data combined with previously published geochemical and stratigraphic data, reveal that the two ignimbrites were erupted from a stratified magma chamber. The Atana zircon U–Pb ages closely agree with the eruption age of Atana previously determined by K–Ar dating (4.0±0.1 Ma) and do not support long (>1 Ma) residence times. Xenocrystic zircons were found only in the Toconao bulk ignimbrite, which were probably entrained during eruption and transport. Apparent ²³⁸U/²⁰⁶Pb zircon ages of 13 Ma in these xenocrysts provide the first evidence that the onset of felsic magmatism within the Altiplano–Puna ignimbrite province occurred approximately 3 Myr earlier than previously documented.