Copper complexing capacity of phytoplanktonic cell exudates

Copper complexing capacity of cell exudates of Dunaliella salina in natural seawater culture medium was investigated in order to evaluate the influence of this organism on speciation of trace metals in seawater.Seawater samples were collected at 200 m and 2 miles off the coast and immediately filtered. Copper complexing capacity (CC_Cu) and stability constants (K′) of related cupric complexes were then measured. They were, respectively, 27.1 × 10⁻⁸ mol l⁻¹ and 0.56 × 10⁷ l mol⁻¹ for the samples collected at 200 m and 12.8 × 10⁻⁸ mol l⁻¹ and 6.10 × 10⁷ l mol⁻¹ for those collected 2 miles off the coast. A stock culture (20 ml, 10⁶ cells ml⁻¹) in log-phase was inoculated in 2 l of each sample of filtered natural seawater. The trend of cell influence was estimated on filtered culture medium by measuring CC_Cu and K′ after 1 h, 3 and 7 days. From the results it appears that CC_Cu increased with respect to time and this was related to the growth rate, indicating a certain relationship with cell metabolic activity.It can be concluded that a comparison between the culture referring to 200 m and 2 miles, respectively, shows that the former presents a CC_Cu two times higher than the latter while the K′ is ten times higher at 2 miles than that at 200 m.     

A statistical analysis of climate variability and ecosystem response in the German Bight

We compiled homogeneous long-term time series comprising 39 variables representing the German Bight and for the period 1975–2004. A diverse set of variables was selected to cover multiple trophic levels and different environmental forcing thus to examine long-term changes in this coastal region. Previous studies have hypothesised the presence of regime shifts in observations extending over the entire North Sea. Focusing on a smaller spatial scale, and closer to the coast, we investigated the major modes of variability in the compiled time series using principal component analysis. The results obtained confirm a previously identified regime shift in the North Sea in 1987/1988 and suggest that the German Bight is dominantly characterised by long-term modes of variability. In the German Bight, the shift of 1987/1988 is driven primarily by temperature, Gulf Stream index, frost days and Secchi depth. Changes in some of the ecosystem variables (plankton and fish) appear to be related to changes in these driving variables. In particular, we documented strong positive correlations between the long-term trend showed by the first principal component and herring, Noctiluca scintillans, and, to a lesser extent, Pleurobrachia pileus. Two gadoids, namely cod and saithe, showed negative correlations with the observed long-term mode of variability. Changes in the sum of five small calanoid copepods were, however, less marked. Phosphate and ammonium exhibited a decreasing trend over the last 30 years. Diatoms and Calanus helgolandicus did not show evidence of changes in concert to this trend. Specific analyses of the data divided into three different subsets (biological, climatic and chemical) characterise the climate of the German Bight as highly dynamic also on short timescales (a few years) as compared to much smoother biological and chemical components. The dynamic regime of the German Bight taken together with a low correlation between the major mode of variability and phytoplankton and zooplankton data suggests that the lower trophic levels of this ecosystem are remarkably resilient.     

Structural setting of the Southern Apennine fold-and-thrust belt (Italy) at hypocentral depth: The Calore Valley case history

The reconstruction of the main structural features of the Southern Apennines (Italy), in correspondence with the focal volume of some strong earthquakes that have affected this chain, can be attempted by analysing reflection seismic lines and deep well logs in comparison with surface geology.For instance, the Calore Valley and its surroundings have been the object of intense hydrocarbon exploration, and a wealth of subsurface data is available. Moreover, this area was affected by the 1688 Sannio earthquake (macroseismic magnitude 7.1), and a new location has recently been proposed for the related causative fault system. The present work defines the structural setting of the Southern Apennine chain in correspondence with this new location, and compares it with similar cases along the Italian peninsula.The analysis was focussed on the reconstruction of deep tectonic units (formed by the buried Apulia carbonate platform succession), which generally correspond to the hypocentral depths of strong earthquakes along the axis of the Southern Apennines. The results show that the Apulia platform succession is affected by three main thrusts, locally accompanied by backthrusts. The top of this succession is relatively shallow: the maximum depth does not exceed 1.8 s TWT (i.e. about 3500 m b.s.l.), while minimum depths occur in correspondence with the ramp anticlines culminations, at 0.5 s TWT (i.e. at about 500 m b.s.l.). Moreover, data suggest that the underlying Paleozoic basement is possibly involved in thrusting.In a regional perspective, extensional seismogenic structures along the axis of the Southern Apennines seem to share some common characteristics. Indeed, they develop (i) in correspondence with an uplifted Paleozoic basement; (ii) at the rear of a set of thrusts that account for the shallow Apulia units; (iii) at the surface, in proximity to the leading edge of a surficial tectonic unit formed by the Apennine carbonate platform succession. The 1688 seismogenic fault system fits in with these common traits. In the light of this, we finally speculate that these common characteristics in the architecture of the chain could provide a key to the location of the major seismicity along the axis of the Southern Apennines and an interpretative model for the identification of possible areas of seismic gap in this part of the Italian peninsula.     

Winds and infalling gas in Lyman break galaxies

A model for gas outflows is proposed which simultaneously explains the correlations between the (i) equivalent widths of low-ionization and Lyα lines, (ii) outflow velocity, and (iii) star formation rate observed in Lyman break galaxies (LBGs). Our interpretation implies that LBGs host short-lived (30 ± 5 Myr) starburst episodes observed at different evolutionary phases. Initially, the starburst powers a hot wind bound by a denser cold shell, which after ≈5 Myr becomes dynamically unstable and fragments; afterwards the fragment evolution is approximately ballistic while the hot bubble continues to expand. As the fragments are gravitationally decelerated, their screening ability of the starlight decreases as the ultraviolet (UV) starburst luminosity progressively dims. LBG observations sample all these evolutionary phases. Finally, the fragments fall back on to the galaxy after ≈60 Myr. This phase cannot be easily probed as it occurs when the starburst UV luminosity has already largely faded; however, galaxies dimmer in the UV than LBGs should show infalling gas.     

Combining relative and absolute gravity measurements to enhance volcano monitoring

To achieve a balance between uncertainty and efficiency in gravity measurements, we have investigated the applicability of combined measurements of absolute and relative gravity as a hybrid method for volcano monitoring. Between 2007 and 2009, three hybrid gravity surveys were conducted at Mt Etna volcano, in June 2007, July 2008, and July 2009. Absolute gravity data were collected with two absolute gravimeters, which represent the state of the art in recent advances in ballistic gravimeter technology: (1) the commercial instrument FG5#238 and (2) the prototype instrument IMGC-02. We carried out several field surveys and confirmed that both the absolute gravimeters can still achieve a 10 μGal or better uncertainty even when they are operated in severe environmental conditions. The use of absolute gravimeters in a field survey of the summit area of Mt Etna is unprecedented. The annual changes of the gravity measured over 2007–2008 and 2008–2009 provide unequivocal evidence that during the 2007–2009 period, two main phenomena of subsurface mass redistribution occurred in distinct sectors of the volcano, accompanying different eruptive episodes. From 2007 to 2008, a gravity change of ?60?μGal was concentrated around the North-East Rift. This coincided with a zone affected by strong extensional tectonics, and hence might have been related to the opening of new voids. Between 2008 and 2009, a North-South elongate feature with a maximum gravity change of +80?μGal was identified in the summit craters area. This is interpreted to indicate recharge of a deep-intermediate magma storage zone, which could have occurred when the 2008–2009 eruption was still ongoing.     

Low-temperature, polysulfide reactions of conjugated ene carbonyls: A reaction model for the geologic origin of S-heterocycles

The theoretical basis for a type of reaction of sulfur-acceptor carbon molecules with donor catenated forms of sulfur is presented. The reactions between conjugated ene carbonyls as sulfur-acceptors and polysulfide as a sulfur donor are described. The scope of this reaction is broadened by demonstrating that the room-temperature action of polysulfide on dienones produces thiophenes. Evidence is given for the structure of 2-benzoyl-5-phenylthiophene, resulting from 1,5-diphenyl-2,4-pentadien-1-one, and 2-acetyl-5-phenylthiophene, resulting from 6-phenyl-3,5-hexadien-2-one. Evidence is also presented for the structure of 2,4-dibenzoyl-3,5-diphenylthiolane, the product resulting from the action of polysulfide on the mixture of benzaldehyde and acetophenone. The same thiolane is shown to result as the minor thiolane component when chalcone reacts with polysulfide in 80% water/20% ethanol. The major component is a known rearranged thiolane identified by its physical properties. The reactiol of chalcone and polysulfide in ethanol at 0 or 25°C results in thiolane formation as evidenced by the isolation of 2,4-dibenzoyl-3,5-diphenylthiolane. However, the reaction of the same two compounds in boiling methanol (65°C) results in a competitive hydrogenation of chalcone giving dihydrochalcone in addition to the formation of thiolane. The demonstration of the low-temperature reaction of polysulfide with conjugated ene carbonyls in the present work adds an additional pathway for possible formation of S-heterocycles in the geosphere.