Use of Chrysotile Fibres in the Degradation of Cationic and Nonionic Surfactants in Aqueous Solutions

It was previously observed that sodium dodecylbenzenesulfonate (SDBS) is degraded in the presence of chrysotile fibres. A higher catalytic efficiency was obtained than the reported values for TiO₂ under the same conditions. Chrysotile, a clay mineral fibre of low cost and relatively abundant, probably acts as a catalyst through an Advanced Oxidative Process (AOP) involving free radical formation. In this work, experiments with non‐ionic – Triton X‐45 (octil‐phenoxy polyethoxy ethanol) – and cationic – Herquat 3500 (alkyl dimethyl benzyl ammonium chloride) – surfactants were carried out. Diluted aqueous solutions (50 ppm) of these surfactants were kept in contact with chrysotile (4.0 g) in the dark at room temperature. The aromatic ring disappearance was followed through the absorbance peaks at 224 nm (Triton X‐45) and 208 nm (Herquat 3500) in the UV spectra. After 4 h, reductions in the surfactant solution concentration of 65.0% and 35.0% were observed for the Triton X‐45 and the Herquat 3500 surfactants, respectively. In both cases, reactions carried out without aeration showed a lower reduction of the aromatic ring concentration (30.0% less) when compared to the values obtained for the systems with airflow. The system containing the non‐ionic surfactant seems to achieve equilibrium after 2 h, what is not observed for the cationic surfactant system.     

The influence of vertical water balance on modelling Pantanal (Brazil) spatio‐temporal inundation dynamics

The current benchmark approach for mathematical modelling of floodplain hydrologic regime consists of dynamically coupling one‐dimensional (1D) and two‐dimensional (2D) models for flow routing along the main channel and the floodplain, respectively. For large‐scale sites, floodplain inundation may spread over hundreds of square kilometres and may last for many months and even influence seasonal floods in following years. This paper aims at evaluating the effect of vertical water balance representation on modelling a large‐scale floodplain. The Pantanal wetland (140 000 km²; Brazil) is simulated using a 1D/2D coupled model approach, which also considers the representation of vertical water processes over the floodplain. Four scenarios are simulated: Baseline (the reference scenario), NoVertBal (in which the vertical water balance over floodplain is turned off) and ETp+1 and ETp?1 scenarios, characterized by artificially increasing or decreasing daily potential evapotranspiration (ETp) by 1 mm, respectively. The results showed that the effect of the vertical water processes scenarios on channel flow is directly dependent on the lateral exchange of water between the channel and floodplain in the upstream river reach. This influence is stronger when there is a gain of water from the floodplain to the channel. The inclusion of these vertical water processes into floodplain modelling was essential to represent the process of wetting and drying, this effect being more relevant for areas not directly connected to main channels, which is a characteristic of the Pantanal region. Copyright © 2013 John Wiley & Sons, Ltd.     

Late‐Pleistocene Wedge Structures Along the Patagonian Coast (Argentina): Chronological Constraints and Palaeo‐Environmental Implications

This paper investigates several wedge structures formed in continental deposits covering marine sediments deposited during MIS 5 along the central Patagonian coast of Argentina. The size and surface microtexture characteristics of the infilling sediments are consistent with a depositional environment dominated by aeolian transport. Fragments of Andean volcanic rocks (glass shards) in the wedge‐fill suggest long‐distance transport via a westerly component of wind direction. The wedges are interpreted as products of deep seasonal frost action in frozen ground, which produced open cracks that filled rapidly with partially non‐local aeolian sediments. Many wedges cross cut carbonate crusts that formed under permafrost conditions in coastal Patagonia. The radiocarbon dating of carbonate crusts yielded an age of 25–27 kyr bp , while wedge‐fill sediments are OSL dated to 14 670 ± 750 yr bp . This indicates that ground wedge formation occurred during a cold event (the Antarctic Cold Reversal period) that interrupted the permafrost degradation following the Last Glacial Maximum.     

Relationships between glacier and rock glacier in the Maritime Alps, Schiantala Valley, Italy

In the Schiantala Valley of the Maritime Alps, the relationship between a till-like body and a contiguous rock glacier has been analyzed using geomorphologic, geoelectric and ice-petrographic methodologies. DC resistivity tomographies undertaken in the till and in the rock glacier show the presence of buried massive ice and ice-rich sediments, respectively. Ice samples from a massive ice outcrop show spherical gas inclusions and equidimensional ice crystals that are randomly orientated, confirming the typical petrographic characteristics of sedimentary ice. The rock glacier formation began after a phase of glacier expansion about 2550 ± 50 ¹⁴C yr BP. Further ice advance during the Little Ice Age (LIA) overrode the rock glacier root and caused partial shrinkage of the pre-existing permafrost. Finally, during the 19th and 20th centuries, the glacial surface became totally debris covered. Geomorphological and geophysical methods combined with analyses of ice structure and fabric can effectively interpret the genesis of landforms in an environment where glaciers and permafrost interact. Ice petrography proved especially useful for differentiating ice of past glaciers versus ice formed under permafrost conditions. These two mechanisms of ice formation are common in the Maritime Alps where many sites of modern rock glaciers were formerly occupied by LIA glaciers.     

Mechanical Behavior of Clayey Soil Reinforced with Recycled Tire Rubber Using Chips and Fibers

Geotechnical and Geological Engineering - The volume of discarded tires continues to increase each year, becoming a major topic of concern for society. Motivated by this environmental issue, this...     

U-Pb SHRIMP zircon dating of andesite from the Dolomite area (NE Italy): geochronological evidence for the early onset of Permian Volcanism in the eastern part of the southern Alps

The Athesian Volcanic District (AVD), a thick sequence of andesitic to rhyolitic lava and ignimbrite, overlies both the Variscan basement of the Dolomites and, where present, the continental basal conglomerate of Upper Carboniferous(?) to Early Permian age. This volcanic activity is known to mark the margin of the intra-Pangea megashear system between Gondwana and Laurasia, the onset age of which is determined in this study.SHRIMP U-Pb dating on zircon from Ponte Gardena/Waidbruck (Isarco/Eisack valley) basaltic andesite yields an age of 290.7 ± 3 Ma, providing the oldest record of andesite volcanic activity yet documented in the AVD. Two younger dates (279.9 ± 3.3 and 278.6 ± 3.1 Ma) obtained for the andesitic necks of M. dei Ginepri (Eores/Aferer valley) and Col Quaternà (western Comelico), respectively, probably represent a second pulse of andesite magmatic activity.Near Chiusa/Klausen, the volcanoclastic deposits at the bottom of the Funes/Villnöss valley volcano-sedimentary complex only contain detrital zircons, dated at 469 ± 6 Ma; these probably derive from erosion of Paleozoic porphyroids. Other zircons from the same sediments and inherited cores of magmatic andesite crystals give Paleoproterozoic (1953.6 ± 22.1, 1834.6 ± 69.3, 1773.6 ± 25.1 Ma), Early Neoproterozoic (1015 ± 14 Ma) and Late Neoproterozoic (728.4 ± 9.6, 687.6 ± 7.6 Ma) ages. These ancient detrital and inherited zircon ages fit the model that envisages the Dolomite region as being tectonically coherent with Africa, at least until the Lower Permian.     

Der nacheiszeitliche Bergsturz im Kandertal (Schweiz): Alter und Auswirkungen auf die damalige Umwelt

Zusammenfassung. Beim Bau des neuen AlpTransit Lötschberg Basistunnels wurden unter murgangartig verschwemmten Ablagerungen der alten Bergsturzmasse des Kandertals Stillwasserablagerungen mit zahlreichen organischen Resten und Torflagen gefunden. Die ¹⁴C-datierten Resultate der Pollen, Makrorest-, Holz- und Holzkohleanalysen ermöglichten eine Rekonstruktion der lokalen bis regionalen Umweltgeschichte. Ein Gewässer, vermutlich ein kleiner See, begann beim Tellenfeld in Frutigen um 8800 kal. Jahre v. Chr. zu verlanden. In der näheren Umgebung wuchs von 8800 v. Chr. bis 8000 v. Chr. ein Föhrenwald (Pinus silvestris), der reichlich mit Hasel (Corylus avellana) und anderen wärmeliebenden Gehölzen (Ulmen, Linden, Eichen; Ulmus, Tilia, Quercus) und Birken (Betula) durchsetzt war. Diese für die Nordalpen sehr frühe Bedeutung der Hasel ist durch ¹⁴C-datierte Corylus-Nussfragmente (9310±50 ¹⁴C BP, 8722–8337 v. Chr.) belegt. Nach 8500 v. Chr. drängte die Hasel die Waldföhre allmählich zurück. Auf Grund der paläoökologischen Resultate muss angenommen werden, dass die Wälder um 7600 v. Chr. durch ein katastrophales Ereignis stark gestört wurden. Als Reaktion darauf kam es zu einer starken Zunahme der Waldbrände und es breiteten sich zuerst Farne und Gräser sowie wenig später Waldföhren aus. Das Gewässer wurde um 7100 v. Chr. durch verschwemmtes Bergsturzmaterial zerstört. Der geomorphologische Befund deutet darauf hin, dass diese Ereignisse in engem Zusammenhang mit dem Hauptbergsturz im Kandertal stehen, der aussergewöhnliche Ausmasse hatte (ca. 800 Millionen m³). Die Zerstörung der lokalen ökosysteme als Folge des Bergsturzes um 7600–7100 v. Chr. fiel in ein frühes holozänes Wärme- und Sonneneinstrahlungsmaximum, in dem es, wie vorgängige Untersuchungen in den Alpen und in anderen Gebirgen belegen, zu überdurchschnittlich vielen Hanginstabilitäten kam.

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During the construction of the new AlpTransit railway line wetland sediments containing numerous fossils and peat layers were found below rockfall masses transported by debris flows. Radiocarbon-dated results of pollen, macrofossils, wood, and charcoal along with radiocarbon dating analysis were used to reconstruct the environmental history of the site. The wetland, originally probably a small lake, started to accumulate sediments at about 8800 cal. yr BC at Frutigen Tellenfeld. A pine forest (Pinus silvestris) admixed with hazel (Corylus avellana), other thermophilous arboreal taxa (Ulmus, Tilia, Quercus) and birch (Betula) grew in the surroundings of the lake. This very early importance of hazel is documented by ¹⁴C-dated Corylus nut fragments (9310±50 ¹⁴C yr BP, 8722–8337 yr BC). After 8500 BC hazel expanded on the costs of pine. The palaeo records suggest that the forests were severely disturbed by a catastrophic event at around 7600 BC. In response, forest fires strongly increased and ferns and grasses expanded and then pine stands established. At ca. 7100 BC the lake was abruptly destroyed by rockfall masses transported by a debris flow. The geomorphic situation suggests that these events were closely related with the main Kander valley rockfall, which had an exceptional size (800 millions m³). Local environmental catastrophes as a consequence of the rockfall at 7600–7100 BC occurred during an early Holocene thermal and solar irradiation maximum. As documented by previous investigations, this period was characterised by pronounced slope instabilities in the Alps and elsewhere.

Manuskript eingegangen 9. Februar 2004 Revidierte Fassung angenommen 17. Januar 2005     

Growth and evolution of an emergent tuff cone: Considerations from structural geology, geomorphology and facies analysis of São Roque volcano, São Miguel (Azores)

The syn-eruptive and post-eruptive history of São Roque tuff cone, its geological setting and volcanological features were studied in detail to understand the role played by the different factors that contributed to the morphological evolution of this relatively simple and small volcanic edifice.In addition, attention was also focused on the series of natural changes that affected the tuff cone during the course of the years and that finally led to its structural disassembly. A novel model is proposed to explain this process.The São Roque volcanic centre, located on the island of São Miguel (Azores), consists of two well-consolidated bodies and numerous small islets that formed more than 4700 years ago during the hydromagmatic activity that took place along an intruding dyke, whose NNW–SSE trend is in agreement with the regional tectonic pattern. The eruptive vents probably migrated progressively from SSE to NNW, forming small edifices through the rapid accumulation of sediments during alternating phases of “dry” and “wet” magmatic emissions. Syn-eruptive partial collapses greatly modified the original morphological structure of these edifices, probably allowing sea water to continuously flow into the vents. The complex interaction of these factors controlled the depth of magma fragmentation, producing different types of deposits, in which the ash-lapilli ratio varies considerably. The high-water saturation degree of these deposits caused syn-eruptive and post-eruptive remobilization which resulted in collapses and some small-scale landslides.Post-eruptive, WNW–ESE trending transtensional and extensional tectonic activities operated during the initial dissection of the cone, generating instability. Furthermore, the rapid accumulation of “wet” tephra, and its following consolidation, caused selective collapses that favoured the fragmentation of the deposit and caused the formation of numerous islets separated by radially-arranged channels. Collapses also involved the lava units emplaced in more recent times around the tuff cone, which show that brittle deformation has been significant in the area for a prolonged period.