Metal-enriched nanoparticles and black carbon: A perspective from the Brazil railway system air pollution

Having a better understanding of air pollutants in railway systems is crucial to ensure a clean public transport. This study measured, for the first time in Brazil, nanoparticles (NPs) and black carbon (BC) on two ground-level platforms and inside trains of the Metropolitan Area of Porto Alegre (MAPA). An intense sampling campaign during thirteen consecutive months was carried out and the chemical composition of NPs was examined by advanced microscopy techniques. The results showed that highest concentrations of the pollutants occur in colder seasons and influenced by variables such as frequency of the trains and passenger densities. Also, internal and external sources of pollution at the stations were identified. The predominance of NPs enriched with metals that increase oxidative stress like Cd, Fe, Pb, Cr, Zn, Ni, V, Hg, Sn, and Ba both on the platforms and inside trains, including Fe-minerals as hematite and magnetite, represents a critical risk to the health of passengers and employees of the system. This interdisciplinary and multi-analytical study aims to provide an improved understanding of reported adverse health effects induced by railway system aerosols.     

Estimating the economic impact of the Prestige oil spill on the Death Coast (NW Spain) fisheries

This paper presents an estimation of the economic effects of the Prestige oil spill in Galicia, focusing on the Death Coast fisheries and using fish landings as a market technique. Examining the evolution of landings in the Death Coast before and after the accident, the analysis reveals two opposing trends, with landings of some species increasing and those of other species diminishing.     

Estimation of seismic hazard parameters in TERESA test areas

A general overview of some of the problems involved in earthquake catalogue handling is given as part of the works carried out into the ESC/SC8-TERESA project related with the seismic hazard assessment in two selected test areas: Sannio-Matese in Italy and the northern Rhine region (BGN). Furthermore, the necessary input data to be used in the calculation of seismic hazard has been obtained, including earthquake source zones and their seismic hazard parameters.The importance is pointed out of detailed analysis of seismic catalogues, mainly in relation to the use of aftershock information, the historical records of the region, and the possible temporal and spatial variation of seismicity, which could have an important influence on short-term hazard assessment.     

Mineralogical data on a sulphosalt from the Rhodope mountains,Bulgaria

Zusammenfassung Bei dem Versuch, die Kristallstruktur von Bonchevit zu bestimmen, stellte sich heraus, daß dieses Mineral—bis dahin PbBi₄S₇—aus zwei Phasen besteht. Der Hauptanteil wurde eindeutig als Galenobismutit identifiziert. Der Rest wies nach den Gitterkonstanten (a₀=13,58±0,02 Å, b₀=20,51±0,07 Å, c₀=4,09±0,07 Å) auf ein bisher unbekanntes Mineral hin. Die Raumgruppe ist Bbmm. Ein indiziertes Pulverdiagramm und die dazugehörigen d-Werte werden angegeben.Die Emissionsspektralanalyse zeigt Pb und Bi als Hauptkomponenten, Cu und Ag als Nebenkomponenten und Spuren von Zn und Sn. Die Strukturanalyse führte zu der Formel Me₅S₆, wobei die Me-Atome etwa gleich schwer sind, so daß als chemischo Formel nur Pb₃Bi₂S₆ mit Z=4 in Frage kommt.Strukturell gehört das Mineral in die Gruppe Andorit-Ramdohrit-Fizelyit. Die Verwandtschaft bzw. Identität des Minerals mit anderen Mineralen und synthetischen Verbindungen wird diskutiert.

---

Mineralogical data on a sulphosalt from the Rhodope mountains, Bulgaria

Summary During an attempt to determine the crystal structure of bonchevite, this mineral was found to consist of two phases. Previously it was thought to have the composition PbBi₄S₇. The main constituent could unambiguously be identified as galenobismutite. For the rest the lattice constants (a₀=13.58±0,02 Å, b₀=20.51±0,07 Å, c₀=4.09±0.07 Å), indicated a new mineral. Space group is Bbmm. An indexed powder diagram (with d-values) is given.The emission spectrographic analysis shows Pb and Bi to be main components, Cu and Ag to be minor components, and traces only of Zn and Sn. The structure analysis has led to the formula Me₅S₆, with Me-atoms of approximately the same atomic number; therefore, the chemical formula has to be Pb₃Bi₂S₆, with Z=4.In a structural classification the mineral belongs to the andoriteramdohrite-fizelyite-group. The relationships to or the identity with other minerals and synthetic compounds are discussed.

     

The study of metal contamination in urban topsoils of Mexico City using GIS

This research presents and discusses information concerning the spatial distribution of heavy metals (Pb, Cu, Zn, Ba, Co, Cr, Ni and V) in the urban environments of Mexico City using geographical information system and statistical analysis. Superficial soil samples (n = 146) were analyzed. The highest contamination indices were found in the north and center zone of the metropolitan area. In contrast, the surrounding rural fields show a lower impact grade. The higher concentrations of Pb, Cu, Zn and Ba were observed as being related to high vehicular traffic, nevertheless other elements such as Co, Cr, Ni and V do not show anthropogenic influence and their content can be attributed to the parental rock. The results are compared with previous surveys carried out in 2003 in order to evaluate temporal deposition trends. No changes were found on reported concentrations except for Cu and Zn, whose concentration has increased in later years. The results suggest that spatial distribution analysis and results in comparison with previous studies could be useful for the management and sustainable development of the metropolitan area of Mexico City.     

Barium-rich fluids and melts in a subduction environment (La Corea and Sierra del Convento mélanges,eastern Cuba)

Whole-rock compositions of muscovite-bearing amphibolite, trondhjemite, pegmatite and quartz-muscovite rocks from Sierra del Convento and La Corea mélanges (eastern Cuba), as well as mineralogy, record complex circulation of Ba-rich fluids and melts in the subduction environment. Partial melting of fluid-fluxed, MORB-derived amphibolite produced trondhjemite magmas that crystallized at depth, in some cases evolving into pegmatites. Qtz-Ms rocks probably crystallized from primary fluids derived from subducted sediments. All these rocks have elevated concentrations of large-ion lithophile elements, especially Ba (up to 11,810 ppm), presumably released from slab sediments by fluids and/or melts. Fluid–rock interaction produced crystallization of phengite in parental amphibolites. The phengite crystallized in all types of rocks is rich in Ba, with concentric zoning, characterized by Ba-rich cores and Ba-poor rims, indicating a compatible behaviour of Ba in the studied systems. Zoning in phengite is governed primarily by the celadonite (tschermak) exchange vector ((Mg,Fe)Si-(Al)_-2), with more moderate contributions of the celsian (BaAl-(KSi)_-1) and paragonite (NaK_-1) exchange vectors. Late remobilization of Ba at relatively low temperature formed retrograde celsian. The compatible behaviour of Ba in the studied rocks strengthens the importance of the stability of phengite for the transfer of LIL elements from the subduction to the volcanic arc environments.     

Vegetation and environmental conditions in the Doñana Natural Park coastal area (SW Iberia) at the beginning of the last glacial cycle

Detailed reconstructions of the vegetation of Iberia during the last glacial inception are rare due to the limited number of terrestrial sites recording this period. Active retreat of El Asperillo cliff, located on the Atlantic coast of southwestern Iberia, has exposed a fossil organic level dating back to one of the early stades of the last glacial cycle. Pollen and macrofossil analyses from this site show that the Doñana area was covered mainly by steppic vegetation; temperate trees survived the coldest periods, albeit in reduced numbers. Mediterranean taxa are extremely reduced, in contrast with other dry areas of southern Iberia over this time span. This vegetation suggests cold and arid climatic conditions, in accordance with paleoclimatic reconstructions based on several Atlantic marine cores.     

The 2011 submarine volcanic eruption in El Hierro (Canary Islands)

Forty years after the Teneguía Volcano (La Palma, 1971), a submarine eruption took place off the town of La Restinga, south of El Hierro, the smallest and youngest island of the Canarian Archipelago. Precursors allowed an early detection of the event and its approximate location, suggesting it was submarine. Uncertainties derived from insufficient scientific information available to the authorities during the eruption, leading to disproportionate civil protection measures, which had an impact on the island's economy—based primarily on tourism—while residents experienced extra fear and distress.     

Implications of chloride-enhanced cadmium uptake in saline agriculture: modeling cadmium uptake by maize and tobacco

Chloride salinity has been strongly related to enhanced cadmium (Cd) uptake by plants due to increased solubility in the soil solution, even in agricultural soil with very low levels of cadmium. This finding is relevant because the cadmium content of food crops is an important concern for human health. Therefore, the aim of this study was to predict and discuss the chlorine-enhanced uptake of cadmium by two common crops: maize and tobacco under ??non-saline?? (1?mM) and ??very strongly saline?? (200?mM) scenarios using a modified ??biotic ligand model?? and datasets from a set of soil and hydroponic experiments. Results indicated that predicted cadmium uptake rates (expressed as cadmium in plant ??mol?m^?2 root) by maize and tobacco plants were consistently higher (54 and 15%, respectively) assuming conditions of ??very strong salinity?? soil compared to the simulated ??non-saline?? soil. In the light of the results of the present research, valuable information is given on modeled cadmium phytoavailability as an indication of the potential risk due to increased cadmium uptake by crops under saline conditions, especially as the enhancement of cadmium uptake in the presence of Cl^? salinity may be a general trend that occurs in many edible crops. The biotic ligand model parameterization applied in the present study attempted to simulate conditions commonly found in natural cadmium and salt-affected soils. However, caution is needed to extrapolate results obtained from these models to real soil conditions.