Bleached chondrules: Evidence for widespread aqueous processes on the parent asteroids of ordinary chondrites

Abstract— We present the first detailed study of a population of texturally distinct chondrules previously described by Kurat (1969), Christophe Michel‐Lévy (1976), and Skinner et al. (1989) that are sharply depleted in alkalis and Al in their outer portions. These “bleached” chondrules, which are exclusively radial pyroxene and cryptocrystalline in texture, have porous outer zones where mesostasis has been lost. Bleached chondrules are present in all type 3 ordinary chondrites and are present in lower abundances in types 4–6. They are most abundant in the L and LL groups, apparently less common in H chondrites, and absent in enstatite chondrites. We used x‐ray mapping and traditional electron microprobe techniques to characterize bleached chondrules in a cross section of ordinary chondrites. We studied bleached chondrules from Semarkona by ion microprobe for trace elements and H isotopes, and by transmission electron microscopy. Chondrule bleaching was the result of low‐temperature alteration by aqueous fluids flowing through finegrained chondrite matrix prior to thermal metamorphism. During aqueous alteration, interstitial glass dissolved and was partially replaced by phyllosilicates, troilite was altered to pentlandite, but pyroxene was completely unaffected. Calcium‐rich zones formed at the inner margins of the bleached zones, either as the result of the early stages of metamorphism or because of fluid‐chondrule reaction. The mineralogy of bleached chondrules is extremely sensitive to thermal metamorphism in type 3 ordinary chondrites, and bleached zones provide a favorable location for the growth of metamorphic minerals in higher petrologic types. The ubiquitous presence of bleached chondrules in ordinary chondrites implies that they all experienced aqueous alteration early in their asteroidal histories, but there is no relationship between the degree of alteration and metamorphic grade. A correlation between the oxidation state of chondrite groups and their degree of aqueous alteration is consistent with the source of water being either accreted ices or water released during oxidation of organic matter. Ordinary chondrites were probably open systems after accretion, and aqueous fluids may have carried volatile elements with them during dehydration. Individual radial pyroxene and cryptocrystalline chondrules were certainly open systems in all chondrites that experienced aqueous alteration leading to bleaching.     

Mineralogy and possible origin of an unusual Cr-rich inclusion in the Los Martinez (L6) chondrite

Abstract— During a petrological study of the previously unclassified ordinary chondrite Los Martínez, we discovered a highly unusual Cr-rich inclusion which we believe is unique in both extraterrestrial and terrestrial mineralogy. The inclusion is highly zoned both compositionally and optically, with a Ca-Al rich, cloudy core and an opaque, Cr-Na-rich rim (up to 24 wt.% Cr₂O₃). Detailed SEM and TEM studies show that the inclusion now consists of a highly zoned, single crystal of plagioclase intergrown with chromium-rich spinel. The spinel has a well-developed crystallographic orientation relationship with the host plagioclase, which indicates that it is the product of exsolution. Although superficially similar to a plagioclase feldspar in composition, in detail the inclusion is Si-deficient and Al-enriched relative to a stoichiometric feldspar. We have not been able to identify a viable precursor mineral phase to the plagioclase-chromite intergrowth and suggest that it may be an unknown metastable phase. The Cr-rich precursors of the inclusion probably have close affinities to the chromite-plagioclase chondrules observed by Ramdohr (1967) in several ordinary chondrites. Based on the zoning in the inclusion, we suggest that it is the product of fractional crystallization from a melt, which may have formed as a liquid condensate, or by melting of solid condensates, in the solar nebula. Subsequent cooling of this melt condensate resulted in crystallization of the, as yet, unidentified phase. After crystallization, the inclusion was probably incorporated into a parent body where it underwent metamorphism and was probably shocked to some degree. During this period of parent body metamorphism, exsolution and decomposition of the unknown precursor occurred to produce the observed intergrowth of plagioclase and chromite. Finally, we have classified Los Martínez as an L6 ordinary chondrite breccia.     

An improvement to the volcano-scan algorithm for atmospheric correction of CRISM and OMEGA spectral data

The observations of Mars by the CRISM and OMEGA hyperspectral imaging spectrometers require correction for photometric, atmospheric and thermal effects prior to the interpretation of possible mineralogical features in the spectra. Here, we report on a simple, yet non-trivial, adaptation to the commonly-used volcano-scan correction technique for atmospheric CO₂, which allows for the improved detection of minerals with intrinsic absorption bands at wavelengths between 1.9 and 2.1 μm. This volcano-scan technique removes the absorption bands of CO₂ by ensuring that the Lambert albedo is the same at two wavelengths: 1.890 and 2.011 μm, with the first wavelength outside the CO₂ gas bands and the second wavelength deep inside the CO₂ gas bands. Our adaptation to the volcano-scan technique moves the first wavelength from 1.890 μm to be instead within the gas bands at 1.980 μm, and for CRISM data, our adaptation shifts the second wavelength slightly, to 2.007 μm. We also report on our efforts to account for a slight ∼0.001 μm shift in wavelengths due to thermal effects in the CRISM instrument.     

How common is the Milky Way–satellite system alignment?

The highly flattened distribution of satellite galaxies in the Milky Way (MW) presents a number of puzzles. First, its polar alignment stands out from the planar alignments commonly found in other galaxies. Secondly, recent proper-motion measurements reveal that the orbital angular momentum of at least three, and possibly as many as eight, of the MW's satellites points (within  30°  ) along the axis of their flattened configuration, suggesting some form of coherent motion. In this paper, we use a high-resolution cosmological simulation to investigate whether this pattern conflicts with the expectations of the cold dark matter model of structure formation. We find that this seemingly unlikely setup occurs often: approximately 35 per cent of the time, we find systems in which the angular momentum of three individual satellites points along, or close to, the short axis of the satellite distribution. In addition, in 30 per cent of the systems we find that the net angular momentum of the six best-aligned satellites lies within  35°  of the short axis of the satellite distribution, as observed for the MW.     

Estimating palaeo-water depth from the physical rock record

Palaeo-water depth and its change with time is a key factor in environmental analysis and in sedimentology in general. The literature published on this topic and on related subjects, however, is substantial albeit scattered within and between different communities (geologists, oceanographers, engineers, physicists etc.). Here I focus on proxies for palaeo-bathymetry as obtained from the physical rock record. Floral, faunal and chemical evidence for palaeo-water depth, being equally important, must be dealt with elsewhere. An assessment of the main depth-related parameters in actualistic settings is presented and their applicability to the fossil sedimentary record discussed. The outcome reveals the full complexity of this topic. There is, for example, no such thing as an average wave-base depth applicable to a wide range of fossil case settings. This because wave and current climates in general, and particularly so in neritic and coastal settings, are intriguingly complex. Furthermore, observations from modern oceans are not a priori applicable to fossil ones. Acknowledging these problems and limitations, critically evaluated quantitative proposals for depth indicative facies and features in the sedimentary record are presented and error bars discussed.     

Submarine groundwater discharge: an outlook of recent advances and current knowledge

Driven by the hydraulic gradient, terrestrial groundwater can be discharged directly into the coastal ocean where heads are above sea level, a phenomenon known as submarine groundwater discharge (SGD). Although long overlooked, in recent years SGD has received increasing attention due largely to its potential importance in the transport of chemical constituents to the sea. Indeed, SGD occurrence and control mechanisms are still poorly understood. Submarine discharge often represents only a minor component of regional total water budgets, but because estimated fluxes are highly variable and quantification remains challenging, the process deserves to be carefully evaluated when investigating marine ecosystems and/or the safety of geological repositories in coastal areas, notably for the underground storage of CO₂. In view of the focus the topic is gaining, reflected in the large amount of information continuously being published in this field, here we present a selected review of our current knowledge of key mechanisms determining submarine groundwater discharge, and an updated compilation of most recent advances in research both in Japan and other regions of the world. In addition, we identify some potential pitfalls that need to be borne in mind in future work on SGD. Particularly in view of globally increasing urbanization and climate change, this contribution should prove useful also to local governmental authorities and scientists involved in groundwater coastal ecosystem management.     

Palaeomagnetic,geochronological and geological constraints on the tectonic evolution of the Mejillones Peninsula,northern Chile

Palaeomagnetic and geochronological data from an Early Palaeozoic high grade metamorphic complex (Jorgina Formation) and Jurassic layered basic intrusion (Moreno Complex) are reported from the Mejillones Peninsula of northern Chile (23–23°30'S). ⁴⁰Ar–³⁹Ar dates from the Lower Palaeozoic Jorgina Formation and the Moreno Complex are between 170 and 158 Ma, coincident with a phase of emplacement of the north Chilean coastal batholith. This suggests that intrusion and magnetization of the Moreno Complex and the metamorphism and remagnetization of the Jorgina Formation were related to batholith emplacement. Extracted stable components of magnetization from all units (17 sites) define site-mean directions with a scattered distribution. The scatter in site-mean directions is interpreted as being due to minor, localized, non-uniform, block-fault related (normal or strike-slip, or both) rotation after 158 Ma. The palaeomagnetic and geochronological data indicate that no significant large-scale latitudinal translation of crustal blocks has taken place in this part of northern Chile since the Late Jurassic. In addition, they indicate that the uniform clockwise rotation after the mid-Cretaceous which affected the adjacent Cordillera de la Costa either did not extend into the Mejillones Peninsula or took the form of localized block-fault rotations. The restriction of palaeomagnetically defined styles of rotation to discrete areas within the north Chilean forearc indicates that forearc wide block-fault rotation models are not applicable to the Pacific margin of northern Chile.