Glacier recession and human vulnerability in the Yanamarey watershed of the Cordillera Blanca, Peru

Glaciers in the Cordillera Blanca, Peru, are undergoing rapid retreat, in large part due to climate change. These changes are significantly altering water availability in the region and pose critical risks to local populations that are highly dependent on these resources for livelihoods. We examine these issues through an interdisciplinary and linked evaluation of hydrological change and livelihood vulnerability in the Yanamarey watershed. Physical observations of the Yanamarey glacier show acceleration in frontal retreat at a rate of 8 m decade^???1 since 1970, accompanied by total volume loss on the order of 0.022 km³. Hydrological and hydrochemical analyses document a possible transformation of stream flow over the past decade as the seasonal storage capacity of the glacier has degraded. Recent stream discharge measurements from the proglacial lake below the glacier are more coincident with the highly variable seasonal precipitation than they were during the 1998?C1999 hydrological year. Local household perceptions of glacier recession and seasonal hydrological variability agree with this trend, which is increasing human vulnerability in the watershed. Household case-study survey results demonstrate that shifting water resources, increasing weather extremes and climate-related threats to tourism are all new vectors of vulnerability for household livelihoods.     

Polycyclic aromatic hydrocarbons in commercial fish and lobsters from the coastal waters of Madagascar following an oil spill in August 2009

Concentrations of polycyclic aromatic hydrocarbons were determined in species of commercial fish and lobsters following an oil-spill just off the protected Madagascan coastline. Samples were collected along the coastline within and outside the affected area. Summed PAH concentrations ranged from 1.9 μg kg⁻¹ to 63 μg kg⁻¹ wet weight, but with no higher molecular weight PAHs (>202 Da) being detected. All concentrations of benzo[a]pyrene, benz[a]anthracene and dibenz[a,h]anthracene were <0.1 μg kg⁻¹ wet weight, well within the EU and UK set limits for the protection of human health. Additionally, samples were calculated as the benzo[a]pyrene toxic equivalency quotient (TEQ) and found to be well below the level of concern in relation to health of human consumers. Evaluation of the biota PAH data indicated the origin of PAH was predominantly petrogenic with >80% arising from oil sources. Profile studies indicate a low-level multisource petrogenic contamination probably representing a pre-spill background for the area.     

Gold solubility in oxidized and reduced, water-saturated mafic melt

We have performed experiments to evaluate Au solubility in natural, water-saturated basaltic melts as a function of oxygen fugacity. Experiments were carried out at 1000 °C and 200 MPa, and oxygen fugacity was controlled at the fayalite-magnetite-quartz (FMQ) oxygen fugacity buffer and FMQ + 4. All experiments were saturated with a metal-chloride aqueous solution loaded initially as a 10 wt% NaCl eq. fluid. The stable phase assemblage at FMQ consists of basalt melt, olivine, clinopyroxene, a single-phase aqueous fluid, and metallic Au. The stable phase assemblage at FMQ + 4 consists of basalt melt, clinopyroxene, magnetite-spinel solid solution, a single-phase aqueous fluid, and metallic Au. Silicate glasses (i.e., quenched melt) and their contained crystalline material were analyzed by using both electron probe microanalysis (EPMA) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Measured Au concentrations in the quenched melt range from 4.8 μg g⁻¹ to 0.64 μg g⁻¹ at FMQ + 4, and 0.54 μg g⁻¹ to 0.1 μg g⁻¹ at FMQ. The measured solubility of Au in olivine and clinopyroxene was consistently below the LA-ICP-MS limit of detection (i.e., 0.1 μg g⁻¹). These melt solubility data place important limitations on the dissolved Au content of water-saturated, Cl- and S-bearing basaltic liquids at geologically relevant fO₂ values. The new data are compared to published, experimentally-determined values for Au solubility in dry and hydrous silicate liquids spanning the compositional range from basalt to rhyolite, and the effects of melt composition, oxygen fugacity, pressure and temperature are discussed.     

By design: The architecture of microbial redox cycling

The authors’ work on mine systems, combines field and laboratory integrated microbial geochemical investigation with high-resolution techniques enabling characterization and visualization at the bacterium scale (i.e. STXM). The results indicate a repeated motif of socially organized microbial cooperation occurring within microbial consortial macrostructures (pods). The pod structure directly enables the specific geochemical processes linked to the metabolic function of the consortial members. These microbially linked geochemical processes have important ramifications for bulk system geochemistry that were previously unknown. Results from two examples: (1) microbial metal interactions within AMD biofilms and (2) sulfur redox cycling by a novel consortia within mine waters, illustrate how the ecology of the pod consortia is linked to pod biogeochemical macrostructure as well as to the resulting geochemistry associated with pod metabolism. In both instances the pod structures enabled the associated consortia to carry out reactions not predicted by classic geochemical understanding of these systems. Investigation of AMD biofilm biogeochemical architecture capturing the micro-scale linkages amongst geochemical gradients, metal dynamics and depth resolved micro-organism community structure, illustrated a novel biomineralization process driven by biofilm associated pods controlling biofilm metal capture. Similarly, the groups’ recent discovery of an environmental S redox cycling, pod-forming, consortium revealed ecologically driven S cycling with previously unknown implications for both AMD mitigation and AMD carbon flux modeling. These results highlight how microbes cooperatively orchestrate their geochemical environment, underscoring the need to consider syntrophic community activity in environmental processes and the requirement for integrated, high-resolution techniques spanning geochemistry, molecular microbiology and imaging to reveal the biogeochemistry involved.     

Modeling a major source of economic resilience to disasters: recapturing lost production

Terrorist attacks and natural disasters have potentially severe economic consequences in terms of property damage and business interruption. However, experience from the September 11 World Trade Center attack and other disasters indicates that the economy has a great deal of resilience. This refers to the ability to dampen the maximum potential economic output (business interruption) loss. One of the most prominent sources of resilience is the ability of businesses to reschedule, or recapture, lost production after the event. Although there have been applications of a fixed parameter recapture factor for each of several aggregated sectors of the economy, there has been little formal analysis of this resilience action. This study offers a theoretic framework for analyzing production rescheduling. It distinguishes the major conditions influencing two aspects that have previously been neglected: (1) the maximum time span over which the rescheduling can take place and (2) the likely decline of the maximum recapture as the business interruption increases. We divide the relevant time path into two periods after recovery. One is a function of a recaptured output path after recovery to the status of normal production. The other is a function for the maximum recaptured production, based on the recaptured output path. The recaptured output path function is assumed to follow a normal distribution function, and hence, total recaptured output follows the cumulative normal distribution function over time after productive capacity is restored. Also, we develop a new cumulative normal distribution function for interruption time duration, which is symmetric with respect to the output axis. This recapture function has unknown parameters. Empirical data on the recaptured amounts following an actual disaster can be used to estimate the parameters of this function using simulation methods.     

Virtual wave gauges based upon stereo imaging for measuring surface wave characteristics

A virtual wave gauge (VWG) technique based on stereo imaging is developed to remotely measure water wave height, period, and direction. VWG minimizes computational costs by directly tracking the elevation of the water surface at selected points of interest using a Eulerian based dynamic searching algorithm. Results show that the VWG technique developed in this paper dramatically improves efficiency by two orders of magnitude compared to the traditional Lagrangian–Eulerian based point cloud method of stereo image processing. VWG is tested against traditional wave wire gauges to within 98% accuracy for significant wave height. Furthermore, the flexibility of the VWG is demonstrated in two field applications. First in an offshore breaking wave case, an array of VWGs is used to efficiently measure wave directionality. Second to investigate the reflection coefficient of a rock-mounted structure interacting with nearshore waves, linear and spatial VWG arrays are designed and implemented based on a priori information of the wave field from a preliminary VWG measurement. Overall, we demonstrate that the flexible and computational efficient VWG technique has the potential to make real-time remote stereo imaging wave measurements a reality.     

Tectono-sedimentary evolution of the Upper Prealpine nappe (Switzerland and France): nappe formation by Late Cretaceous-Paleogene accretion

Abstract

The Upper Prealpine nappe of the Swiss and French Prealps consists of a composite stack of various tectonic slivers (Gets, Simme, Dranse and Sarine sub-nappes, from top to bottom). The structural superposition and stratigraphic content of the individual sub-nappes suggests a successive stacking at the South Penninic/Adriatic transition zone during the Late Cretaceous and Early Paleogene. The present paper deals with two aspects. (1) new data obtained from the Complexe de base Series of the Dranse sub-nappe which underlies the Helminthoid Sandstone Formation, and (2) the development of a geodynamic accretionary model for the Upper Prealpine nappe stacking.

The Complexe de base Series reveals a succession of black shales at the base, grading upward into variegated red/green and red shales which were deposited in an abyssal plain environment starved of clastic input. It is overlain by the Helminthoid Sandstone Formation. The combined analysis of planktic and agglutinated benthic foraminifera and comparisons with other Tethyan series suggest an Albian to Campanian age of the Complexe de base succession. Tectonic transport of the abyssal plain segment into a trench environment allowed for the stratigraphic superposition by the Helminthoid sandstone sequence. The present findings combine well with the general scheme of the Upper Prealpine nappe stack and several single results on parts of the nappe stack. We take that opportunity to present a comprehensive model for the tectono-sedimentary evolution of the Upper Prealpine nappe.

We suggest that Late Jurassic-Early Cretaceous asymmetric (?) extension at the South Penninic-Adriatic margin created an extensional alloehthon. Later during the mid-Cretaceous, the start of convergence drove the obduction of oceanic crust on the northern margin of the extensional allochthon. The resulting ophiolitic/continental source supplied clasts to the trench basin in front (Manche turbidite series), and the backarc basin (Mocausa Formation) and abyssal plain (Perrières turbidite series) to the South. During Middle to Late Coniacian the main Adriatic margin was thrusted over the obductionrelated mixed belt and established an incipient accretionary prism containing the former trench, backarc and abyssal plain basin fill series. During this stage the Gueyraz (melange) Complex formed, which separates the trench series from the retroarc and abyssal plain formations. On top of the incipient accretionary prism a forearc basin developed hosting the Hundsrück Formation. The frontal abyssal plain formation (Complexe de base) still received few turbiditic intercalations. From Campanian time on, the forearc basin was bypassed and deposition of the Helminthoid Sandstone Formation occurred on the Complexe de base succession. During the Maastrichtian the abyssal plain and trench fill succession (Dranse nappe) was accreted to the incipient wedge, and in front of a newly active buttress, the Gurnigel trench basin was established. Another accretionary event during latest Paleocene/earliest Eocene added parts of that trench series to the base of the wedge (Sarine nappe). During the Late Eocene the accretionary wedge and remaining trench fill series (Gurnigel nappe) were thrusted en-bloc over the Middle Penninic limestone nappes and partly overtook the latter. Continued shortening of the resulting nappe pile and out-of-sequence thrusting accomplished the overriding of the Middle Penninic units over the former South Penninic Gurnigel trench series (inversion of palaeogeographic domains).     

Application of trichloroacetic acid (TCA) to extraction of soft body for the determination of tissue Cd, Cu, Pb and Zn in the prosobranch Hydrobia ulvae (Pennant)

The application of trichloroacetic acid (TCA) as a shell extractant for preparation of soft body parts with reference to tissue metal concentrations (Cd, Cu, Pb, Zn) in shellfish has been evaluated on the example of the mud snail Hydrobia ulvae, a small marine prosobranch densely present in rocky and soft-bottom habitats of the eastern Atlantic. A solution of 0.1 M TCA was tested on individuals treated according to two different protocols: (1) thawed after freezing ("non-dried") and (2) thawed and air-dried to a constant weight ("dried"). Two points were investigated in detail to improve the method: individual soft tissue dry weight and tissue metal concentration following a standard digestion method. In both instances, the results were compared with those from manually dissected snails. Conditions for total shell decalcification of 60 individuals (3-4 mm long) were 5.5 h in 20 ml of 0.1 M TCA.No differences in individual soft tissue weight were observed between the treatments, indicating good efficiency of the TCA extraction with respect to weight of soft body parts. In contrast, tissue metal concentrations varied among treatments. The TCA extraction of the dried animals had a good recovery for Cd, most likely due to the lower solubility of Cd vital cellular components (proteins and mineral concretions) from the dried tissue. Satisfactory recoveries of the tissue concentrations of Cu and Pb were obtained for the non-dried individuals. This might be related to the specific distribution of metals in the organism (namely in the digestive glands and gonads) and their different chemical reactivity with TCA after the tissue was dried. Limited susceptibility of Zn-bearing protein bindings to complexing with TCA also accounts for significantly lower concentrations of Zn in the mud snail's soft tissue that was extracted. The 0.1 M TCA solution is therefore recommended for extraction of the shells of Hydrobia ulvae for tissue determination of Cd, Cu and Pb; however the treatment protocol does affect metal recovery and thus a consistent procedure should be followed.The extracted metals from the soft tissues and shells of the mud snails (on the basis of both metal concentrations and contents) were ranked in order of increasing contribution of soft body parts to the total (shell+tissue): Pb相似文献   

Polycyclic aromatic hydrocarbons in sediments,mussels and crustacea around a former gasworks site in Shoreham-by-Sea,UK

Concentrations of polycyclic aromatic hydrocarbons have been determined in sediments, mussels and crustacea in the vicinity of a former gasworks site by Shoreham Harbour, UK. Very high concentrations of PAH were found in the substrate, an ash-like material deposited on the former gasworks site, which exhibited a profile consistent with the major source of contamination being coal or coke tar produced during the period of gas production at the site. Elevated PAH concentrations were also found in mussels both from the beach below the former gasworks site, and from sites further to the east in Portslade and Hove. The significance of these concentrations were assessed using an approach which involved the calculation of benzo[a]pyrene equivalent conoentrations (BaPEs), summing concentrations of individual PAH on the basis of their comparative potency as carcinogens. BaPE ranged from values of, or close to, zero for crustacea, to 336 microg kg(-1) wet weight in mussels from Southwick Beach. The contaminated mussels are not exploited commercially but may be taken by casual gatherers, and notices have been posted to warn potential consumers.