Natural Radioactivity at the Sin Quyen Iron-Oxide-Copper-Gold Deposit in North Vietnam

The field radiometric and laboratory measurements were performed at the Sin Quyen copper deposit in North Vietnam. The field gamma-ray spectrometry indicated the concentration of uranium ranging from 5.5 to 87 ppm, thorium from 5.6 to 33.2 ppm, and potassium from 0.3 to 4.7%. The measured dose rates ranged from 115 to 582 nGy/h, the highest doses being at the copper ore. Concentrations in the solid samples were in the range of 20–1700 Bq/kg for uranium, 20–92.7 Bq/kg for thorium, and 7–1345 Bq/kg for potassium. The calculated doses were from 22 to 896 nGy/h; both measured and calculated dose rates are mostly related to uranium. Concentrations of radium in water samples were below 0.17 Bq/L. Uranium in water samples was significantly higher than the hydrogeological background; the maximum of 13 Bq/L was at the waste zone pool, but neither radium nor uranium were present in tap water. Radon concentration in the dwelling air was from 42 to 278 Bq/m³ for ²²²Rn and from 8 to 193 Bq/m³ for ²²⁰Rn. The estimated committed dose rates were principally related to ²²²Rn concentration and ranged from 1.1 to 8.1 mSv/y.     

The Impact of Hurricane Katrina on the Coastal Vegetation of the Weeks Bay Reserve,Alabama from NDVI Data

Normalized Difference Vegetation Index (NDVI) data were used to investigate vegetation changes after Hurricane Katrina (2005) for the Weeks Bay Reserve and surrounding area of coastal AL. Landsat 5 satellite images were acquired before landfall (March 24, 2005), after landfall (September 16, 2005), and 8 months after landfall (April 28, 2006). The March 2005 to September 2005 image comparison showed that average NDVI values decreased by 49% after landfall. Continuing into the next year, average NDVI values were −44% lower in April 2006 than they were in March 2005. Among habitat types, the estuarine emergent wetland experienced the largest average NDVI value decrease (−64%). The estuarine emergent wetland NDVI values continued to decrease by −27% from September 2005 to April 2006, whereas other habitats increased in NDVI. This continued suppression of NDVI values was attributed to increased salinity from the storm surge and to regional drought conditions that occurred after landfall. These results provide insight into the sensitivity of coastal vegetation from the interactions of both tropical cyclones and long-term environmental conditions.     

Quantitative dam break analysis on a reservoir earth dam

Mathematical simulations on dam break or failure using BOSS DAMBRK hydrodynamic flood routing dam break model were carried out to determine the extent of flooding downstream, flood travel times, flood water velocities and impacts on downstream affected residences, properties and environmental sensitive areas due to floodwaters released by failure of the dam structure. Computer simulations for one of the worse case scenarios on dam failure using BOSS DAMBRK software accounted for dam failure, storage effects, floodplains, over bank flow and flood wave attenuation. The simulated results reviewed a maximum flow velocity of 2.40 m/s with a discharge of approximately 242 mз /s occurred at 1.00 km downstream. The maximum discharge increased from 244 m³/s (flow velocity = 1.74 m/s occurred at 8^th. km) to 263 m³/s (flow velocity = 1.37 m/s occurred at 12^th. km); about a 39% drop in flow velocity over a distance of 4.00 km downstream. If the entire dam gives way instantly, some spots stretching from 0.00 km (at dam site) to approximately 3.40 km downstream of the dam may be categorized as “danger zone”, while downstream hazard and economic loss beyond 3.40 km downstream can be classified as “low” or “minimal” zones.     

Characteristics and Influence of Phosphorus Accumulated in the Bed Sediments of a Stream Located in an Agricultural Watershed

We investigated the accumulation and influence of bioavailable P (BAP) in sediments of a stream located in an agricultural area of the Lake Mendota watershed in Wisconsin, USA. During hydrologic events, the stream carried high concentrations of suspended sediment (up to 250 mg/l) and BAP (up to 2.5 mg/l). Bed sediments were highly enriched in BAP, as inventories of BAP in the top 10 cm of sediment ranged from 143 to 14,500 μg P/cm². Space variations in BAP inventories were related to site-specific hydrodynamics and geochemical factors, including iron (Fe; r ² = 0.71) and aluminum (Al; r ² = 0.54) concentrations. Most sites behaved as potential sinks for dissolved reactive phosphate during hydrologic events and potential sources during base-flow periods. Through the combination of site-specific factors and geochemical controls, Dorn Creek modifies the amount, timing, and composition of P delivered from the watershed to downstream sites and water bodies.     

An evolutionary algorithm for multicriteria path optimization problems

For many years researchers and decision makers (DMs) faced with multicriteria shortest path problems (MSPPs) have resorted to reductions to the classical shortest path problem (SPP) by means of weighted linear combinations of the criteria. Algorithmic and approximation schemes are available to solve MSPPs but these approaches often display complexities prohibitive to their implementation on real‐world applications. This paper describes the development of an Evolutionary Algorithm (EA) approach to MSPPs on networks with multiple independent criteria. The EA approach is shown to sufficiently explore the underlying network space, generate large candidate path sets, and evolve high quality approximations to the optimal MSPP solution(s). Opportunities for early termination of the EA in time‐critical applications are also offered. Among the issues for further work is the integration of the EA as a tool within a GIS for path optimization.     

Reconstructing epilimnetic total phosphorus using diatoms: statistical and ecological constraints

Diatoms respond rapidly to eutrophication and diatom-based models for inferring total phosphorus (TP) have found wide application in palaeolimnology, especially in tracking trajectories of past and recent nutrient enrichment and in establishing pre-disturbance targets for restoration. Using new analysis of existing training sets and sediment-cores we examine the statistical and ecological constraints of diatom-inferred TP (DI-TP) models. Although the models show an apparently strong relationship between measured and inferred TP in the training sets, even under cross-validation, the models display three fundamental weaknesses, namely (1) the relationship between TP and diatom relative abundance is heavily confounded with secondary variables such as alkalinity and lake depth, (2) the models contain many taxa that are not significantly related to TP, and (3) comparison between different models shows poor or no spatial replicability. At some sites the sediment-core diatom assemblage change tracks the TP gradient in the training sets and DI-TP reconstructions are consistent with monitored TP data and known catchment histories for the recent past. At others diatom species turnover is apparently related to variables other than TP, and DI-TP fails to even reproduce plausible trends. Pre-disturbance DI-TP values are also questionable at most sites. We argue that these problems pervade many DI-TP models, particularly those where violations of the basic assumptions of the transfer function approach are ignored.     

Exploring links between juvenile offenders and social disorganization at a large map scale: a Bayesian spatial modeling approach

This paper adopts a Bayesian spatial modeling approach to investigate the distribution of young offender residences in York Region, Southern Ontario, Canada, at the census dissemination area level. Few geographic researches have analyzed offender (as opposed to offense) data at a large map scale (i.e., using a relatively small areal unit of analysis) to minimize aggregation effects. Providing context is the social disorganization theory, which hypothesizes that areas with economic deprivation, high population turnover, and high ethnic heterogeneity exhibit social disorganization and are expected to facilitate higher instances of young offenders. Non-spatial and spatial Poisson models indicate that spatial methods are superior to non-spatial models with respect to model fit and that index of ethnic heterogeneity, residential mobility (1 year moving rate), and percentage of residents receiving government transfer payments are, respectively, the most significant explanatory variables related to young offender location. These findings provide overwhelming support for social disorganization theory as it applies to offender location in York Region, Ontario. Targeting areas where prevalence of young offenders could or could not be explained by social disorganization through decomposing the estimated risk map are helpful for dealing with juvenile offenders in the region. Results prompt discussion into geographically targeted police services and young offender placement pertaining to risk of recidivism. We discuss possible reasons for differences and similarities between the previous findings (that analyzed offense data and/or were conducted at a smaller map scale) and our findings, limitations of our study, and practical outcomes of this research from a law enforcement perspective.     

Glacier recession and human vulnerability in the Yanamarey watershed of the Cordillera Blanca, Peru

Glaciers in the Cordillera Blanca, Peru, are undergoing rapid retreat, in large part due to climate change. These changes are significantly altering water availability in the region and pose critical risks to local populations that are highly dependent on these resources for livelihoods. We examine these issues through an interdisciplinary and linked evaluation of hydrological change and livelihood vulnerability in the Yanamarey watershed. Physical observations of the Yanamarey glacier show acceleration in frontal retreat at a rate of 8 m decade^???1 since 1970, accompanied by total volume loss on the order of 0.022 km³. Hydrological and hydrochemical analyses document a possible transformation of stream flow over the past decade as the seasonal storage capacity of the glacier has degraded. Recent stream discharge measurements from the proglacial lake below the glacier are more coincident with the highly variable seasonal precipitation than they were during the 1998?C1999 hydrological year. Local household perceptions of glacier recession and seasonal hydrological variability agree with this trend, which is increasing human vulnerability in the watershed. Household case-study survey results demonstrate that shifting water resources, increasing weather extremes and climate-related threats to tourism are all new vectors of vulnerability for household livelihoods.     

Polycyclic aromatic hydrocarbons in commercial fish and lobsters from the coastal waters of Madagascar following an oil spill in August 2009

Concentrations of polycyclic aromatic hydrocarbons were determined in species of commercial fish and lobsters following an oil-spill just off the protected Madagascan coastline. Samples were collected along the coastline within and outside the affected area. Summed PAH concentrations ranged from 1.9 μg kg⁻¹ to 63 μg kg⁻¹ wet weight, but with no higher molecular weight PAHs (>202 Da) being detected. All concentrations of benzo[a]pyrene, benz[a]anthracene and dibenz[a,h]anthracene were <0.1 μg kg⁻¹ wet weight, well within the EU and UK set limits for the protection of human health. Additionally, samples were calculated as the benzo[a]pyrene toxic equivalency quotient (TEQ) and found to be well below the level of concern in relation to health of human consumers. Evaluation of the biota PAH data indicated the origin of PAH was predominantly petrogenic with >80% arising from oil sources. Profile studies indicate a low-level multisource petrogenic contamination probably representing a pre-spill background for the area.     

Gold solubility in oxidized and reduced, water-saturated mafic melt

We have performed experiments to evaluate Au solubility in natural, water-saturated basaltic melts as a function of oxygen fugacity. Experiments were carried out at 1000 °C and 200 MPa, and oxygen fugacity was controlled at the fayalite-magnetite-quartz (FMQ) oxygen fugacity buffer and FMQ + 4. All experiments were saturated with a metal-chloride aqueous solution loaded initially as a 10 wt% NaCl eq. fluid. The stable phase assemblage at FMQ consists of basalt melt, olivine, clinopyroxene, a single-phase aqueous fluid, and metallic Au. The stable phase assemblage at FMQ + 4 consists of basalt melt, clinopyroxene, magnetite-spinel solid solution, a single-phase aqueous fluid, and metallic Au. Silicate glasses (i.e., quenched melt) and their contained crystalline material were analyzed by using both electron probe microanalysis (EPMA) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Measured Au concentrations in the quenched melt range from 4.8 μg g⁻¹ to 0.64 μg g⁻¹ at FMQ + 4, and 0.54 μg g⁻¹ to 0.1 μg g⁻¹ at FMQ. The measured solubility of Au in olivine and clinopyroxene was consistently below the LA-ICP-MS limit of detection (i.e., 0.1 μg g⁻¹). These melt solubility data place important limitations on the dissolved Au content of water-saturated, Cl- and S-bearing basaltic liquids at geologically relevant fO₂ values. The new data are compared to published, experimentally-determined values for Au solubility in dry and hydrous silicate liquids spanning the compositional range from basalt to rhyolite, and the effects of melt composition, oxygen fugacity, pressure and temperature are discussed.