Hillslope groundwater discharges provide localized stream ecosystem buffers from regional per- and polyfluoroalkyl substances contamination

Emerging groundwater contaminants such as per- and polyfluoroalkyl substances (PFAS) may impact surface-water quality and groundwater-dependent ecosystems of gaining streams. Although complex near-surface hydrogeology of stream corridors challenges sampling efforts, recent advances in heat tracing of discharge zones enable efficient and informed data collection. For this study, we used a combination of streambed temperature push-probe and thermal infrared methods to guide a discharge-zone-oriented sample collection along approximately 6 km of a coastal trout stream on Cape Cod, MA. Eight surface-water locations and discharging groundwater from 24 streambed and bank seepages were analysed for dissolved oxygen (DO), specific conductance, stable water isotopes, and a range of PFAS compounds, which are contaminants of emerging concern in aquatic environments. The results indicate a complex system of groundwater discharge source flowpaths, where the sum of concentrations of six PFAS compounds (corresponding to the U.S. Environmental Protection Agency third Unregulated Contaminant Monitoring Rule “UCMR 3”) showed a median concentration of 52 ± 331 (SD) ng/L with two higher outliers and three discharges with PFAS concentrations below the quantification limit. Higher PFAS concentration was related (− 0.66 Spearman rank, p < .001) to discharging groundwater that showed an evaporative signature (deuterium excess), indicating flow through at least one upgradient kettle lake. Therefore, more regional groundwater flowpaths originating from outside the local river corridor tended to show higher PFAS concentrations as evaluated at their respective discharge zones. Conversely, PFAS concentrations were typically low at discharges that did not indicate evaporation and were adjacent to steep hillslopes and, therefore, were classified as locally recharged groundwater. Previous research at this stream found that the native brook trout spawn at discharge points of groundwater recharged on local hillslopes, likely in response to generally higher levels of DO. Our study shows that by targeting high oxygen discharges the trout may thereby be avoiding emerging contaminants such as PFAS in groundwater recharged farther from the stream.     

Aluminium in glacial meltwater demonstrates an association with nutrient export (Werenskiöldbreen,Svalbard)

The aluminium (Al) cycle in glacierised basins has not received a great deal of attention in studies of biogeochemical cycles. As Al may be toxic for biota, it is important to investigate the processes leading to its release into the environment. It has not yet been ascertained whether filterable Al (passing through a pore size of 0.45 μm) is incorporated into biogeochemical cycles in glacierised basins. Our study aims to determine the relationship between the processes bringing filterable Al and glacier‐derived filterable nutrients (particularly Fe and Si) into glacierised basins. We investigated the Werenskiöldbreen basin (44.1 km², 60% glacierised) situated in SW Spitsbergen, Svalbard. In 2011, we collected meltwater from a subglacial portal at the glacier front and at a downstream hydrometric station throughout the ablation season. The Al concentration, unchanged between the subglacial system and proglacial zone, reveals that aluminosilicate weathering is a dominant source of filterable Al under subglacial conditions. By examining the Al:Fe ratio compared with pH and the sulphate mass fraction index, we found that the proton source for subglacial aluminosilicate weathering is mainly associated with sulphide oxidation and, to a lesser degree, with hydrolysis and carbonation. In subglacial outflows and in the glacial river, Al and Fe are primarily in the forms of Al(OH)₄^‐ and Fe(OH)₃. The annual filterable Al yield (2.7 mmol m^‐2) was of a magnitude similar to that of nutrients such as filterable Fe (3.0 mmol m^‐2) and lower than that of dissolved Si (18.5 mmol m^‐2). Our results show that filterable Al concentrations in meltwater are significantly correlated to filterable and dissolved glacier‐derived nutrients (Fe and Si, respectively) concentrations in glaciers worldwide. We conclude that a potential bioavailable Al pool derived from glacierised basins may be incorporated in biogeochemical cycles, as it is strongly related to the concentrations and yields of glacier‐derived nutrients.     

Spatial and seasonal distribution of adult Oithona similis in the Southern Ocean: Predictions using boosted regression trees

We applied a multivariate statistical modelling technique called boosted regression trees to derive relationships between environmental conditions and the distribution of the adult stage of the cyclopoid copepod Oithona similis in the Southern Ocean. Nearly 20 000 samples from the Southern Ocean Continuous Plankton Recorder survey (87% from East Antarctica) were used to model the probability of detection (presence) and relative abundance of adults of this zooplankton species in surface waters. We demonstrate that it is possible to obtain reasonable models for both the presence (area under the Receiver Operating Characteristic curve of 0.77) and relative abundance (28–35% variance explained) of adult O. similis between November and March in much of the Southern Ocean. No investigation was possible where the environmental characteristics were not well represented by the SO-CPR dataset, namely, the Argentine shelf, Weddell Sea, and the frontal region north of the Amundsen Sea, or under sea-ice. Our analyses support the hypothesis that adult O. similis abundance is related to environmental conditions in a broadly similar way throughout the Southern Ocean. Compared to a compilation of net-haul data from the literature, the abundance model explained 34% of the variance in surface concentrations of adult stages of this species, and 23–59% of the variance in depth-integrated abundance of copepodite and adult stages combined. The models show higher occurrence and elevated abundances in a broad circumpolar band between the Antarctic Polar Front and the southern boundary of the Antarctic Circumpolar Current (approximately 54–64°S). Evidence of diel vertical migration by adults of this species north of 65°S was found, with surface abundances 20% higher at night than during the day. There was no evidence of diel migration south of 65°S. Five potential “hotspots” of adult O. similis were identified: in the southern Scotia Sea, two areas off east Antarctica, in the frontal zone north of the Amundsen Sea, and a small area in the outer Bellingshausen Sea. We recommend that a database of all available net-haul data on Oithona similis in the Southern Ocean be created to facilitate further investigations on the circumpolar distribution of this species.     

Imaging hyporheic zone solute transport using electrical resistivity

Traditional characterization of hyporheic processes relies upon modelling observed in‐stream and subsurface breakthrough curves to estimate hyporheic zone size and infer exchange rates. Solute data integrate upstream behaviour and lack spatial coverage, limiting our ability to accurately quantify spatially heterogeneous exchange dynamics. Here, we demonstrate the application of near‐surface electrical resistivity imaging (ERI) methods, coupled with experiments using an electrically conductive stream tracer (dissolved NaCl), to provide in situ imaging of spatial and temporal dynamics of hyporheic exchange. Tracer‐labelled water in the stream enters the hyporheic zone, reducing electrical resistivity in the subsurface (to which subsurface ERI is sensitive). Comparison of background measurements with those recording tracer presence provides distributed characterization of hyporheic area (in this application, ∼0·5 m²). Results demonstrate the first application of ERI for two‐dimensional imaging of stream‐aquifer exchange and hyporheic extent. Future application of this technique will greatly enhance our ability to quantify processes controlling solute transport and fate in hyporheic zones, and provide data necessary to inform more complete numerical models. Copyright © 2010 John Wiley & Sons, Ltd.     

Power spectral analysis of Jupiter’s clouds and kinetic energy from Cassini

We present suggestive evidence for an inverse energy cascade within Jupiter’s atmosphere through a calculation of the power spectrum of its kinetic energy and its cloud patterns. Using Cassini observations, we composed full-longitudinal mosaics of Jupiter’s atmosphere at several wavelengths. We also utilized image pairs derived from these observations to generate full-longitudinal maps of wind vectors and atmospheric kinetic energy within Jupiter’s troposphere. We computed power spectra of the image mosaics and kinetic energy maps using spherical harmonic analysis. Power spectra of Jupiter’s cloud patterns imaged at certain wavelengths resemble theoretical spectra of two-dimensional turbulence, with power-law slopes near −5/3 and −3 at low and high wavenumbers, respectively. The slopes of the kinetic energy power spectrum are also near −5/3 at low wavenumbers. At high wavenumbers, however, the spectral slopes are relatively flatter than the theoretical prediction of −3. In addition, the image mosaic and kinetic energy power spectra differ with respect to the location of the transition in slopes. The transition in slope is near planetary wavenumber 70 for the kinetic energy spectra, but is typically above 200 for the image mosaic spectra. Our results also show the importance of calculating spectral slopes from full 2D velocity maps rather than 1D zonal mean velocity profiles, since at large wavenumbers the spectra differ significantly, though at low wavenumbers, the 1D zonal and full 2D kinetic energy spectra are practically indistinguishable. Furthermore, the difference between the image and kinetic energy spectra suggests some caution in the interpretation of power spectrum results solely from image mosaics and its significance for the underlying dynamics. Finally, we also report prominent variations in kinetic energy within the equatorial jet stream that appear to be associated with the 5 μm hotspots. Other eddies are present within the flow collar of the Great Red Spot, suggesting caution when interpreting snapshots of the flow inside these features as representative of a time-averaged state.     

Volcanic tsunami: a review of source mechanisms, past events and hazards in Southeast Asia (Indonesia, Philippines, Papua New Guinea)

Southeast Asia has had both volcanic tsunamis and possesses some of the most densely populated, economically important and rapidly developing coastlines in the world. This contribution provides a review of volcanic tsunami hazard in Southeast Asia. Source mechanisms of tsunami related to eruptive and gravitational processes are presented, together with a history of past events in the region. A review of available data shows that many volcanoes are potentially tsunamigenic and present often neglected hazard to the rapidly developing coasts of the region. We highlight crucial volcanic provinces in Indonesia, the Philippines and Papua New Guinea and propose strategies for facing future events.     

The Lake Michigan meteotsunamis of 1954 revisited

Two large meteotsunami wave events on Lake Michigan impacted the Chicago coastline within 10 days of each other in 1954. Initial data analysis suggested that the fatal first event (June 26) was caused by a Proudman resonant non-trapped wave, while the second event (July 6) was caused by Greenspan resonant trapped edge waves. In this study, a numerical hydrodynamic model was used to reveal the detailed behavior of these events. For both events, the atmospheric pressure and wind perturbations were found to be essential to explain the magnitude of the wave activity, in contrast to the initial conclusions that the waves were primarily pressure-driven. In the June 26 meteotsunami, Proudman resonance wave was the primary cause of the destructive wave, though the storm also generated edge waves which persisted for many hours, hindering rescue efforts. The maximum wave heights for the July 6 event were found to be the product of a superposition of edge waves and non-trapped waves rather than purely edge waves as originally thought. The results from these events demonstrate the enclosed Lake Michigan basin retained and focused wave energy, leading to their large magnitude, long duration, and destructive nature.     

Weiwoboidae fam.nov.of 'Higher' Fulgoroidea (Hemiptera:Fulgoromorpha) from the Eocene Deposits of Yunnan,China

<正>A new family of so-called‘higher' planthoppers,Weiwoboidae fam.nov.,from the Lower Eocene of Yunnan is described.A new monotypic genus,Weiwoboa gen.nov.,with Weiwoboa meridiana sp.nov.is also described and illustrated.The characters of tegmen venation of the new family,its evolution,and supposed relationships are briefly discussed.     

Raman spectra of nitrogen-containing organic compounds obtained in high altitude sites using a portable spectrometer: Possible application for remote robotic Titan studies

Well-resolved Raman spectra of examples of nitrogen-containing compounds were detected using a portable Raman instrument (Ahura First Defender XL) outdoors at a low temperature of −15 °C at an altitude of 2860 m (Pitztall, Austria). The portable Raman spectrometer tested here is equipped with a 785 nm diode laser and fixed frontal probe. Solid forms of formamide, urea, 3-methylpyridine, aniline, indene, 1-(2-aminoethyl)piperazine, benzofuran and indoline were detected unambiguously under field high-mountain conditions. The main Raman features (strong, medium and partially weak bands) were observed at their correct wavenumber positions (spectral resolution 7-10 cm⁻¹) in the range 200-2000 cm⁻¹. The results obtained demonstrate the possibility of applying a miniaturised Raman spectrometer as key instrument for investigating the presence of nitrogen-containing organic compounds and biomolecules under low temperature field conditions. Within the payload designed by ESA and NASA for future missions focusing not only on Mars, Raman spectroscopy will be an important non-destructive analytical tool for the in-situ identification of both organic and inorganic compounds relevant to life detection on planetary surfaces or near sub-surfaces.     

Spectral bandwidth enhancement of GPR profiling data using multiple-frequency compositing

The amplitude spectrum of ground penetrating radar (GPR) reflection data acquired with a particular antenna set is normally concentrated over a spectral bandwidth of a single octave, limiting the resolving power of the GPR wavelet. Where variously-sized GPR targets are located at numerous depths in the ground, it is often necessary to acquire several profiles of GPR data using antennas of different nominal frequencies. The most complete understanding of the subsurface is obtained when those frequency-limited radargrams are jointly interpreted, since each frequency yields a particular response to subsurface reflectivity. The application of deconvolution to GPR data could improve image quality, but is often hindered by limited spectral bandwidth.We present multiple-frequency compositing as a means of combining data from several frequency-limited datasets and improving the spectral bandwidth of the GPR profile. A multiple-frequency composite is built by summing together a number of spatially-coincident radargrams, each acquired with antennae of different centre frequency. The goal of the compositing process is therefore to produce a composite radargram with balanced contributions from frequency-limited radargrams and obtain a composite wavelet that has properties approximating a delta function (i.e. short in duration and having a broad, uniform spectral bandwidth).A synthetic investigation of the compositing process was performed using Berlage wavelets as proxies for GPR source pulses. This investigation suggests that a balanced, broad bandwidth, effective source pulse is obtained by a compositing process that equalises the spectral maxima of frequency-limited wavelets prior to summation into the composite. The compositing of real GPR data was examined using a set of 225, 450 and 900 MHz GPR common offset profiles acquired at a site on the Waterloo Moraine in Ontario, Canada. The most successful compositing strategy involved derivation of scaling factors from a time-variant least squares analysis of the amplitude spectra of each frequency-limited dataset. Contributions to the composite from each nominal acquisition frequency are clear, and the trace averaged amplitude spectrum of the corresponding composite is broadened uniformly over a bandwidth approaching two-octaves. Improvements to wavelet resolution are clear when a composite radargram is treated with a spiking deconvolution algorithm. Such improvement suggests that multiple-frequency compositing is a useful imaging tool, and a promising foundation for improving deconvolution of GPR data.