Geochemical processes regulating groundwater chemistry with special reference to nitrate and fluoride enrichment in Chhatarpur area, Madhya Pradesh, India

The present study focuses on the hydrogeochemical composition of groundwater in Chhatarpur area with special focus on nitrate and fluoride contamination, considering the fact that groundwater is the only major source of drinking water here. Carbonate and silicate mineral weathering followed by ground water–surface water interactions, ion exchange and anthropogenic activities are mainly responsible for high concentrations of cations and anions in the groundwater in the region. The average concentration of nitrate and fluoride found in 27 samples is 1.08 and 61.4 mg/L, respectively. Nitrate enrichment mainly occurs in areas occupied with intense fertilizer practice in agricultural fields. Since the area is not dominated by industrialization, the possibility of anthropogenic input of fluoride is almost negligible, thus the enrichment of fluoride in groundwater is only possible due to rock–water interaction. The highly alkaline conditions, which favor the fluorite dissolution, are the main process responsible for high concentration of fluoride.     

Use of DEM data to monitor height changes due to deforestation

Deforestation has been a major cause of climate change and other environmental problems. An accurate estimation of the volume of deforested area is needed for United Nations Reducing Emissions from Deforestation and Forest Degradation (UN-REDD+) policies implementation and global carbon accounting. Accurate information about three-dimensional (3-D) structure of forests is required to quantify forest carbon stock. This study demonstrates the use of different digital elevation models (DEMs) to monitor changes in height due to deforestation in Cambodia to support climate change mitigation policies of UN-REDD+. The Shuttle Radar Topographic Mission-DEM (SRTM-DEM), Advanced Spaceborne Thermal Emission and Reflection Radiometer Global DEM (ASTER-GDEM) and Panchromatic Remote sensing Instrument for Stereo Mapping-Digital Surface Model (PRISM-DSM) data were calibrated using Ice Cloud and land Elevation Satellite Geoscience Laser Altimeter System (ICESat–GLAS) data. The results obtained from this study clearly indicate the changes in the height of forests due to deforestation activity. The height of cutover forest generated from the PRISM-DSM and SRTM-DEM is more reliable than that from the PRISM-DSM and ASTER-GDEM data. Field data has also been used to validate the height of the cutover forests, which shows ±5 m uncertainties in the estimation.     

Depositional environment in and around Tamiraparani estuary,and off Tuticorin,Tamil Nadu,India: clues from grain size studies

The sediments of the estuaries and offshore Tuticorin along the southern coast of Tamil Nadu were studied for their textural variation. Ninety sediment samples were collected from three sectors (river, estuary, offshore) on the basis of prevailing energy conditions and oceanographic parameters. Frequency curves show unimodal to bimodal in nature. Offshore samples also fall in bimodal with medium and fine sand where sediment is additionally deposited by the Tamiraparani River. The mean values ranging from 1.69 to 2.01 φ with medium to fine sand. The fine sand in the riverine region indicates the depositional nature of the sediments. In pre-monsoon, the standard deviation ranges from 0.29 to 0.81 φ, which falls in the very well sorted to moderately well sorted. Estuary ranges from 0.63 to 1.30 φ, with moderately sorted, whereas in the marine sediments ranges from 0.4 to 1.01 φ, with moderately to moderately well- sorted and some patches of poorly sorted is observed. In both monsoons, the grain size variations are mostly influenced in river and offshore samples compared to the estuaries. The CM pattern indicates the deposition of sediments in graded suspension. In estuary, the sediments are medium sand with moderately to poorly sorted, fine skewed which are indicative of denudation processes taking place there. In marine, the sediments are medium-to-fine, moderately-to-well sorted, and fine skewed to very fine skewed sediments, probably as a result of the influence of palaeo-sediments deposited by rivers from inland as well as by waves and currents from offshore. Further, the marine samples also highlight depositional processes.     

Chromospheric Sunspot Oscillations in Hα and Ca ii 8542 Å

We study chromospheric oscillations including umbral flashes and running penumbral waves in a sunspot of active region NOAA 11242 using scanning spectroscopy in Hα and Ca?ii 8542 Å with the Fast Imaging Solar Spectrograph (FISS) at the 1.6 meter New Solar Telescope at the Big Bear Solar Observatory. A bisector method is applied to spectral observations to construct chromospheric Doppler-velocity maps. Temporal-sequence analysis of these shows enhanced high-frequency oscillations inside the sunspot umbra in both lines. Their peak frequency gradually decreases outward from the umbra. The oscillation power is found to be associated with magnetic-field strength and inclination, with different relationships in different frequency bands.     

Velocities and Temperatures of an Ellerman Bomb and Its Associated Features

We investigated the velocity and temperature characteristics of an Ellerman bomb (EB) and its associated features based on observations made with the Fast Imaging Solar Spectrograph (FISS) and a broadband TiO filter of the 1.6 meter New Solar Telescope at Big Bear Solar Observatory. In the TiO images of the photospheric level, we found a granular cell expanding in two opposite directions near the site of the EB. When one end of this granule reached the EB site, the transverse speed of the tip of the expanding granule rapidly decreased and the EB brightened. The wings of the Hα profile of the EB indicated that the EB was blueshifted up to 7 km?s^?1. About 260 s after the EB brightening, a surge was seen in absorption and varied from a blueshift of 20 km?s^?1 to a redshift of 40 km?s^?1 seen in the Hα and Ca ii 8542 Å lines. From the Doppler absorption width of the two lines determined by applying the cloud model, we estimated the mean temperature of the surge material to be about 29000 K and the mean speed of nonthermal motion to be about 11 km?s^?1. We discuss the physical implications of our results in terms of magnetic reconnection and processes related to it.     

Aeromagnetic anomalies uncover the Precambrian basement in the Chhattisgarh basin area,Central India

This paper presents aeromagnetic images for the Chhattisgarh basin region, in Central India, to provide a new window on Precambrian basement geology and structure. On the basis of aeromagnetic patterns, the Chhattisgarh basin is sub-divided into a northern low (negative) anomaly zone and a southern high (positive) anomaly zone. The northern portion of the main Chhattisgarh basin has been further divided into two subbasins, the Hirri sub-basin in the west, and Baradwar sub-basin in the east. A prominent negative anomaly delineates a NW-SE trending greenstone belt separating these sub-basins. Positive magnetic anomalies delineate the extent of the Dongargarh granite and equivalents, while the weak magnetic anomaly in the southeast of the Dongargarh granite and equivalents reflect granulite gneisses of the Eastern Ghat Mobile Belt. By applying the reduced-to-the-equator filter we enhanced the possible magnetic sources and structural lineaments within the Chhattisgarh basin. A new sketch map of structural elements was then compiled from aeromagnetic interpretation over the Chhattisgarh basin area. It includes possible faults, folds and an inferred lithological boundary.     

The relationship between reference canopy conductance and simplified hydraulic architecture

Terrestrial ecosystems are dominated by vascular plants that form a mosaic of hydraulic conduits to water movement from the soil to the atmosphere. Together with canopy leaf area, canopy stomatal conductance regulates plant water use and thereby photosynthesis and growth. Although stomatal conductance is coordinated with plant hydraulic conductance, governing relationships across species has not yet been formulated at a practical level that can be employed in large-scale models. Here, combinations of published conductance measurements obtained with several methodologies across boreal to tropical climates were used to explore relationships between canopy conductance rates and hydraulic constraints. A parsimonious hydraulic model requiring sapwood-to-leaf area ratio and canopy height generated acceptable agreement with measurements across a range of biomes (r²=0.75)$(r^2=0.75)$. The results suggest that, at long time scales, the functional convergence among ecosystems in the relationship between water-use and hydraulic architecture eclipses inter-specific variation in physiology and anatomy of the transport system. Prognostic applicability of this model requires independent knowledge of sapwood-to-leaf area. In this study, we did not find a strong relationship between sapwood-to-leaf area and physical or climatic variables that are readily determinable at coarse scales, though the results suggest that climate may have a mediating influence on the relationship between sapwood-to-leaf area and height. Within temperate forests, canopy height alone explained a large amount of the variance in reference canopy conductance (r²=0.68)$(r^2=0.68)$ and this relationship may be more immediately applicable in the terrestrial ecosystem models.     

A study on soil physico-chemical, microbial and metal content in Sukinda chromite mine of Odisha, India

Soil samples from chromite mining site and its adjacent overburden dumps and fallow land of Sukinda, Odisha, were analysed for their physico-chemical, microbial and metal contents. Chromite mine soils were heterogenous mixture of clay, mud, minerals and rocks. The pH of the soils ranges between 5.87 and 7.36. The nutrient contents of the mine soils (N, P, K and organic C) were found to be extremely low. Analysis of chromite mine soils revealed accumulation of a number of metals in high concentrations (Fe > Cr > Mn > Ni > Zn > Pb > Sr) which exceeded ecotoxicological limits in soil. Correlation and cluster analysis of metals revealed a strong relation between Cr, Ni, Fe, Mn among the different attributes studied. Assessment of different microbial groups such as fungi, actinomycetes and bacteria (heterotrophic, spore forming, free-living nitrogen fixing, phosphate solubilising and cellulose degrading) from mine soils were found to be either extremely low or absent in some soil samples. Further chromium tolerant bacteria (CTB) were isolated using 100 mg/L Cr(VI) enriched nutrient agar medium and were screened for their tolerance towards increasing concentrations of hexavalent chromium and other toxic metals. Out of 23 CTB isolates, three bacteria tolerated up to 900 mg/L, 6 up to 500 mg/L, 20 up to 200 mg/L of Cr(VI). These bacteria were also found to be sensitive towards Cu > Co > Cd and very few CTB strains could show multiple metal tolerance. These strains have great scope for their application in bioremediation of toxic chromium ions in presence of other metals ions, which needs to be explored for their biotechnological applications.     

Photodegradation of amaranth in aqueous solution catalyzed by immobilized nanoparticles of titanium dioxide

The use of suspensions of nanoparticles of titanium dioxide in photocatalytic degradation of dye solution has disadvantages of inconvenient separation of fine particles for reuse and limited penetration of light for effective degradation. These problems can be minimized by supporting titanium dioxide on various inert supports. The present study involves the preparation of immobilized titanium dioxide films by three different techniques and characterization of the prepared films. The immobilized films of nanocrystals of titanium dioxide were prepared using sol?Cgel technique, polyvinyl alcohol?Cformaldehyde binder and acrylic emulsion. The photocatalytic performance of the prepared films for degradation of amaranth dye has also been evaluated and compared. Combination of photodegradation and adsorption processes induces strong beneficial effects on removal of dyes. Addition of high adsorption capacity activated carbon to photoactive titanium dioxide in photodegradation of dyes improves the efficiency of dye mineralization. The activated carbon has also been immobilized along with titanium dioxide in the present work to examine the dual effect of photodegradation and adsorption in the removal of amaranth. The films formed with the help of polyvinyl alcohol?Cformaldehyde binder showed better dye degradation capabilities.     

Preparation and characterization of biosorbents and copper sequestration from simulated wastewater

This paper reports the potential of chemically treated wood chips to remove copper (II) ions from aqueous solution a function of pH, adsorbent dose, initial copper (II) concentration and contact time by batch technique. The wood chips were treated with (a) boiling, (b) formaldehyde and (c) concentrated sulphuric acid and characterized by Fourier transform infrared spectroscopy, scanning electron microscopy and energy dispersive analysis X-ray. pH 5.0 was optimum with 86.1, 88.5 and 93.9 % copper (II) removal by boiled, formaldehyde-treated and concentrated sulphuric acid-treated wood chips, respectively, for dilute solutions at 20 g L^?1 adsorbent dose. The experimental data were analysed using Freundlich, Langmuir, Dubinin–Radushkevich and Temkin isotherm models. It was found that Freundlich and Langmuir models fitted better the equilibrium adsorption data and the adsorption process followed pseudo-second-order reaction kinetics. The results showed that the copper (II) is considerably adsorbed on wood chips and it could be an economical option for the removal of copper from aqueous systems.