THE USE OF A CROSS-CORRELATION TECHNIQUE TO ENHANCE JANSSON''S DECONVOLUTION PROCEDURE

The use of a cross-correlation prefiltering technique to enhance the ability of Jansson's iterativedeconvolution procedure to deconvolve extremely noisy chromatographic data is investigated.Test casesinclude peaks whose resolutions are as low as 0.35 and whose signal-to-noise ratios are as low as 1:1.Evaluation criteria include RMS error,relative peak error and peak area repeatability.For comparisonpurposes,relative peak area errors and peak area variances are also evaluated for noisy but well resolvedpeaks that have only been prefiltered with the cross-correlation filter.Jansson's method in conjunctionwith cross-correlation prefiltering is shown not only to resolve overlapped peaks but in some cases toimprove their signal-to-noise ratios.The study also establishes some limits to the capabilities of Jansson'smethod will regard to adverse data conditions.     

REE and PGE Geochemical Constraints on the Formation of Dunites in the Luobusa Ophiolite, Southern Tibet

The Luobusa ophiolite, Southern Tibet, lies in the Indus–YarlungZangbo suture zone that separates Eurasia to the north fromthe Indian continent to the south. The ophiolite contains awell-preserved mantle sequence consisting of harzburgite, clinopyroxene(cpx)-bearing harzburgite and dunite. The harzburgite containsabundant pods of chromitite, most of which have dunite envelopes,and the cpx-bearing harzburgites host numerous dunite dykes.Dunite also exists as a massive unit similar to those of themantle–crust transition zones in other ophiolites. Allof the dunites in the ophiolite have a similar mineralogy, comprisingmainly olivine with minor orthopyroxene and chromite and tracesof clinopyroxene. They also display similar chemical compositions,including U-shaped chondrite-normalized REE patterns. Mantle-normalizedPGE patterns show variable negative Pt anomalies. Detailed analysisof a chromite-bearing dunite dyke, which grades into the hostcpx-bearing harzburgite, indicates that LREE and Ir decrease,whereas HREE, Pd and Pt increase away from the dunite. Thesefeatures are consistent with formation of the dunite dykes byinteraction of MORB peridotites with boninitic melts from whichthe chromitites were formed. Because the transition-zone dunitesare mineralogically and chemically identical to those formedby such melt–rock reaction, we infer that they are ofsimilar origin. The Luobusa ultramafic rocks originally formedas MORB-source upper mantle, which was subsequently trappedas part of a mantle wedge above a subduction zone. Hydrous meltsgenerated under the influence of the subducted slab at depthmigrated upward and reacted with the cpx-bearing harzburgitesto form the dunite dykes. The modified melts ponded in smallpockets higher in the section, where they produced podiformchromitites with dunite envelopes. At the top of the mantlesection, pervasive reaction between melts and harzburgite producedthe transition-zone dunites. KEY WORDS: melt–rock interaction; REE; PGE; hydrous melt; mantle; ophiolite; Tibet     

Climbing‐ripple successions in turbidite systems: depositional environments,sedimentation rates and accumulation times

Climbing‐ripple cross‐lamination is most commonly deposited by turbidity currents when suspended load fallout and bedload transport occur contemporaneously. The angle of ripple climb reflects the ratio of suspended load fallout and bedload sedimentation rates, allowing for the calculation of the flow properties and durations of turbidity currents. Three areas exhibiting thick (>50 m) sections of deep‐water climbing‐ripple cross‐lamination deposits are the focus of this study: (i) the Miocene upper Mount Messenger Formation in the Taranaki Basin, New Zealand; (ii) the Permian Skoorsteenberg Formation in the Tanqua depocentre of the Karoo Basin, South Africa; and (iii) the lower Pleistocene Magnolia Field in the Titan Basin, Gulf of Mexico. Facies distributions and local contextual information indicate that climbing‐ripple cross‐lamination in each area was deposited in an ‘off‐axis’ setting where flows were expanding due to loss of confinement or a decrease in slope gradient. The resultant reduction in flow thickness, Reynolds number, shear stress and capacity promoted suspension fallout and thus climbing‐ripple cross‐lamination formation. Climbing‐ripple cross‐lamination in the New Zealand study area was deposited both outside of and within channels at an inferred break in slope, where flows were decelerating and expanding. In the South Africa study area, climbing‐ripple cross‐lamination was deposited due to a loss of flow confinement. In the Magnolia study area, an abrupt decrease in gradient near a basin sill caused flow deceleration and climbing‐ripple cross‐lamination deposition in off‐axis settings. Sedimentation rate and accumulation time were calculated for 44 climbing‐ripple cross‐lamination sedimentation units from the three areas using TDURE, a mathematical model developed by Baas et al. (2000) . For T_c divisions and T_bc beds averaging 26 cm and 37 cm thick, respectively, average climbing‐ripple cross‐lamination and whole bed sedimentation rates were 0·15 mm sec^?1 and 0·26 mm sec^?1 and average accumulation times were 27 min and 35 min, respectively. In some instances, distinct stratigraphic trends of sedimentation rate give insight into the evolution of the depositional environment. Climbing‐ripple cross‐lamination in the three study areas is developed in very fine‐grained to fine‐grained sand, suggesting a grain size dependence on turbidite climbing‐ripple cross‐lamination formation. Indeed, the calculated sedimentation rates correlate well with the rate of sedimentation due to hindered settling of very fine‐grained and fine‐grained sand–water suspensions at concentrations of up to 20% and 2·5%, respectively. For coarser grains, hindered settling rates at all concentrations are much too high to form climbing‐ripple cross‐lamination, resulting in the formation of massive/structureless S₃ or T_a divisions.     

Relationship between Late Pleistocene sea‐level variations,carbonate platform morphology and aragonite production (Maldives,Indian Ocean)

A piston core from the Maldives carbonate platform was investigated for carbonate mineralogy, grain‐size distributions, calcium carbonate content and organic carbon. The sedimentary record was linked to Late Pleistocene sea‐level variations, using an age model based on oxygen isotopes obtained from planktonic foramanifera, nannofossil biostratigraphy and ¹⁴C age determinations. The correlation between the sedimentary record and Late Pleistocene sea‐level showed that variations in aragonite and mud during the past 150 000 years were clearly related to flooding and sea floor exposure of the main lagoons of the atolls of the Maldives carbonate platform. Platform flooding events were characterized by strongly increased deposition of aragonite and mud within the Inner Sea of the Maldives. Exposure events, in contrast, can be recognized by rapid decreases in the values of both proxy records. The results show that sediments on the Maldives carbonate platform contain a continuous record of Pleistocene sea‐level variations. These sediments may, therefore, contribute to a better understanding of regional and even global sea‐level changes, and yield new insights into the interplay between ocean currents and carbonate platform morphology.     

Magnetic mineral transport and sorting in the swash‐zone: northern Lake Erie,Canada

A combined field and laboratory study in northern Lake Erie has provided new insights into the origin and dynamics of heavy mineral placer deposits on beaches consisting primarily of non‐magnetic sediment. Work was conducted on the cross‐shore and longshore transport of heavy magnetic minerals using magnetic susceptibility and fluorescent paints to trace the movement, in the field, of samples of magnetic (magnetite) and non‐magnetic (quartz and calcite) grains, respectively. Laboratory experiments examined how the burial of small, dense magnetic minerals is affected by the grain size of the non‐magnetic host material, and how grain burial affects magnetic susceptibility measurements at the surface. The field experiments demonstrated that the magnetic mineral tracers were buried rapidly beneath coarser, non‐magnetic grains under low to moderate wave conditions, and subsequently were unable to move in the longshore or cross‐shore directions. The laboratory experiments showed that the magnetic susceptibility rapidly decreased with the rate and depth of burial of the magnetic minerals, and that magnetic grain burial was most effective beneath coarser rather than finer non‐magnetic sand and, for the latter sediments, under less rather than more energetic conditions. The results imply that magnetic mineral concentrations develop in this area through magnetic grain burial under fairly mild conditions, and subsequent settling, exposure and concentration in the upper swash zone during more energetic periods, when the non‐magnetic grains are eroded. It is probably during these erosional periods, when the magnetic minerals are exposed in fairly homogeneous deposits, that longshore and cross‐shore transport takes place.     

Using palaeoenvironmental DNA to reconstruct past environments: progress and prospects

Palaeoenvironmental DNA (PalEnDNA) is defined as ancient DNA (aDNA) originating from disseminated genetic material within palaeoenvironmental samples. Sources of PalEnDNA include marine and lake sediments, peat, loess, till, ice, permafrost, palaeosols, coprolites, preserved gut contents, dental calculus, tephras, and soils as well as deposits in caves/rockshelters and at archaeological sites. PalEnDNA analysis provides a relatively new tool for Quaternary and archaeological sciences and its applications have included palaeoenvironmental and palaeodietary reconstructions, testing hypotheses regarding megafaunal extinctions, human–environment interactions, taxonomic studies, and studies of DNA damage. Because PalEnDNA samples comprise markedly different materials, and represent wide‐ranging depositional and taphonomic contexts, various issues must be addressed to achieve robust, reproducible findings. Such issues include climatic and temporal limitations, the biological origin and state (free versus bound) of PalEnDNA, stratigraphic reliability, sterile sampling, ability to distinguish modern from aDNA signals, DNA damage and PCR amplification, DNA extraction methods, and taxonomic resolution. In this review, we provide a non‐specialist introduction to the use of PalEnDNA for Quaternary and archaeological researchers, assess attributes and limitations of this palaeoenvironmental tool, and discuss future prospects of using PalEnDNA to reconstruct past environments.     

Turbidite deposition on the glacially influenced,canyon‐dominated Southwest Grand Banks Slope,Canada

The deeply dissected Southwest Grand Banks Slope offshore the Grand Banks of Newfoundland was investigated using multiple data sets in order to determine how canyons and intercanyon ridges developed and what sedimentary processes acted on glacially influenced slopes. The canyons are a product of Quaternary ice‐related processes that operated along the margin, such as ice stream outwash and proglacial plume fallout. Three types of canyon are defined based on their dimensions, axial sedimentary processes and the location of the canyon head. There are canyons formed by glacial outwash with aggradational and erosional floors, and canyons formed on the slope by retrogressive failure. The steep, narrow intercanyon ridges that separate the canyons are composite morphological features formed by a complex history of sediment aggradation and degradation. Ridge aggradation occurred as a result of mid to late Quaternary background sedimentation (proglacial plume fallout and hemipelagic settling) and turbidite deposition. Intercanyon ridge degradation was caused mainly by sediment removal due to local slump failures and erosive sediment gravity flows. Levée‐like deposits are present as little as 15 km from the shelf break. At 30 km from the shelf, turbidity currents spilled over a 400 m high ridge and reconfined in a canyon formed by retrogressive failure, where a thalweg channel was developed. These observations imply that turbidity currents evolved rapidly in this slope‐proximal environment and attained flow depths of hundreds of metres over distances of a few tens of kilometres, suggesting turbulent subglacial outwash from tunnel valleys as the principal turbidity current‐generating mechanism.     

Noble Metal Enrichment Processes in the Merensky Reef, Bushveld Complex

We have analysed sulphides, silicates, and chromites of theMerensky Reef for platinum-group elements (PGEs), Re and Auusing laser ablation-inductively coupled plasma mass spectrometryand synthetic pyrrhotite standards annealed with known quantitiesof noble metals. Os, Ir and Ru reside in solid solution in pyrrhotiteand pentlandite, Rh and part of the Reef’s Pd in pentlandite,whereas Pt, Au, Re and some Pd form discrete phases. Olivineand chromite, often suspected to carry Os, Ir and Ru, are PGEfree. All phases analysed contain noble metals as discrete micro-inclusionswith diameters typically <100 nm. Inclusions in sulphidescommonly have the element combinations Os–Ir–Ptand Pt–Pd–Au. Inclusions in olivine and chromiteare dominated by Pt ± Au–Pd. Few inclusion spectracan be related to discrete noble metal phases, and few inclusionshave formed by sub-solidus exsolution. Rather, some PGE inclusions,notably those in olivine and chromite, are early-magmatic nuggetstrapped when their host phases crystallized. We suggest thatthe silicate melt layer that preceded the Merensky Reef wasPGE oversaturated at early cumulus times. Experiments combinedwith available sulphide–silicate partition coefficientssuggest that a silicate melt in equilibrium with a sulphidemelt containing the PGE spectrum of the Merensky ore would indeedbe oversaturated with respect to the least soluble noble metals.Sulphide melt apparently played little role in enriching thenoble metals in the Merensky Reef; rather, its role was to immobilizea pre-existing in situ stratiform PGE anomaly in the liquid-stratifiedmagma chamber. KEY WORDS: Bushveld Complex; Merensky Reef; laser-ablation ICP-MS; platinum-group mineralization