Subsolidus and Partial Melting Reactions in the Quartz-excess CaO+MgO+Al2O3+SiO2+H2O System under Water-excess and Water-deficient Conditions to 10 kb: Some Implications for the Origin of Peraluminous Melts from Mafic Rocks

Experimental results up to 10 kb pressure are presented on thestability of amphibole in the quartz-excess CaO+MgO+Al₂O₃ (CMASH)system under H₂O)-excess and H₂O deficient conditions. Amphiboleis stable above the solidus under H₂O-excess conditions whereasunder H₂O-deficient conditions dehydration melting of amphibole-bearingassemblages defines the solidus. The successive appearance ofamphibole, talc, and zoisite with increasing pressure considerablymodifies the plagioclase-pyroxene-garnet-kyanite reactions documentedexperimentally in the CaO+MgO+Al₂O₃+SiO₂ system for gabbro-granulite-eclogitetransitions. Although both clino pyroxene and cordierite (withanorthite+orthopyroxene+quartz) may melt eutectically at oneatmosphere to form diopside-normative and corundum-normativemelts respectively, at higher pressures under H₂O-excess conditionsthe peritectic melting of mafic rock compositions produces corundum-normativeliquids together with either clinopyroxene or amphibole. Dehydrationmelting produces melts which are not corundum-normative. Thesedata are used to discuss the origins and evolution of contrastingbasalt-andesite-dacite-rhyolite volcanic suites and graniticplutons, many of whose silicic variants are corundum-normativein character, such as the Toba luff ignimbrites, Indonesia (Beddoc-Stephenset al., 1983) and I-type granite minimum melts (White &Chappell, 1977). In contrast, it is proposed that for the Cascadesbasalt-andesite-dacite-rhyolite suite the ortho pyroxene-plagioclase-quartzthermal divide was maintained up to rhyolite compositions, therebyprohibiting the derivation of corundum-normative rocks fromdiopside-normative parent magmas. The deduced reaction relations between pyroxenes, amphibole,plagioclase, quartz, and liquid are used to explain the absenceor extreme scarcity of hydrous phases in some hydrous magmas.These phase relations can also explain the development of laterplagioclase overgrowths on resorbed plagioclase cores in graniticintrusives, and the general absence of resorption and overgrowthsin chemically equivalent extrusive rocks. A theoretical analysis of the partial melting of forsterite-bearingassemblages in the CaO+MgO+Al₂O₃+SiO₂+H₂O system shows thatunder H₂O-excess conditions partial melting may generate corundum-normative(but low SiO₂) melts from a peridotite source at shallow depths.     

Wetland sustainability and the evolution of indigenous knowledge in Ethiopia

Much research in recent years has addressed the contribution of indigenous knowledge (IK) to development initiatives in developing countries. An IK system that continuously evolves and adapts in response to environmental and socio-economic change is often considered to be at the core of sustainable natural resource management practices and rural livelihoods. In the context of indigenous wetland management in western Ethiopia, this paper examines the relationship between IK and wetland sustainability, focusing on the mechanisms through which IK evolves and how local adaptive capacity is built up. A series of participatory research activities undertaken in four wetland communities revealed spatial variations in the degree of innovation and communication taking place. The paper argues that these mechanisms are key factors influencing adaptive capacity, suggesting a key link between wetland sustainability and the occurrence of innovation and communication among communities.     

Oxygen Thermobarometry of Orogenic Lherzolite Massifs

The oxidation state has been determined for spinel peridotitesfrom 13 orogenic lherzolite massifs including Beni Bousera,Ronda, and 11 smaller massifs in the French Pyrenees. The oxygenfugacity (f_o2) was calculated for 67 samples from microprobeanalyses using a set of secondary spinel standards to correctthe ferric iron content in the spinels. The utility of thismethod is confirmed by the good agreement between the calculatedvalues and those determined by Mossbauer spectroscopy on 28samples. The spinel peridotites of Ronda and Beni Bousera are relativelyreduced, averaging -11 and -1.5 log units relative to fayalite-magnetite-quartz(FMQ) respectively, which is in agreement with values from abyssalperidotites and mid-ocean ridge basalt (MORB) glasses. The Pyreneanmassifs are relatively oxidized and are intermediate between the abyssal peridotites and continentalxenolith suites. No systematic gradients are observable. Instead,variations of up to 2 log units in f_o2 occur at a localizedscale. This type of variation is also observed for trace elementsand radiogenic isotopes. The harzburgites at Beni Bousera recordthe most reduced conditions. Local oxidation coincides withthe appearance of amphibolc, indicating that metasomatizingfluids or melts are generally oxidized compared with the hostperidotites. Partial re-equilibration in the plagioclase peridotitefades has occurred at Ronda, causing the spinels to become Crrich. Re-equilibration is extremely heterogeneous. Mild oxidationappears to attend the crystallization of fine-grained plagioclase. The similarity in fo₂ values at Beni Bousera and Ronda indicatesa fairly uniform oxidation state at a scale of {small tilde}200 km. This scale of homogeneity is also observed in the Pyrenees,where no significant variation in f_o2 is apparent along 200km of strike in the Northern Pyrenean Zone.     

Melting of Biotite + Plagioclase + Quartz Gneisses: the Role of H2O in the Stability of Amphibole

Biotite + plagioclase + quartz (BPQ) is a common assemblagein gneisses, metasediments and metamorphosed granitic to granodioriticintrusions. Melting experiments on an assemblage consistingof 24 vol. % quartz, 25 vol. % biotite (XMg = 0·38–0·40),42 vol. % plagioclase (An_26–29), 9 vol. % alkali feldsparand minor apatite, titanite and epidote were conducted at 10,15 and 20 kbar between 800 and 900°C under fluid-absentconditions and with small amounts (2 and 4 wt %) of water addedto the system. At 10 kbar when 4 wt % of water was added tothe system the biotite melting reaction occurred below 800°Cand produced garnet + amphibole + melt. At 15 kbar the meltingreaction produced garnet + amphibole + melt with 2 wt % addedwater. At 20 kbar the amphibole occurred only at high temperature(900°C) and with 4 wt % added water. In this last case themelting reaction produced amphibole + clinopyroxene ±garnet + melt. Under fluid-absent conditions the melting reactionproduced garnet + plagioclase II + melt and left behind a plagioclaseI ± quartz residuum, with an increase in the modal amountof garnet with increasing pressure. The results show that itis not possible to generate hornblende in such compositionswithout the addition of at least 2–4 wt % H₂O. This reflectsthe fact that conditions of low aH₂O may prevent hornblendefrom being produced with peraluminous granitic liquids fromthe melting of biotite gneiss. Thus growth of hornblende inanatectic BPQ gneisses is an indication of addition of externalH₂O-rich fluids during the partial melting event. KEY WORDS: biotite; dehydration; gneisses; hornblende; melt     

Paucity of sulfide in a large slab of Esquel: New perspectives on pallasite formation

Abstract— The 0.7 ton Esquel meteorite, found in Patagonia before 1951, is a typical main-group pallasite in most respects. We examined petrographically a slab ～1 m long having an area of 3000 cm² that shows the typical pallasitic texture with fragmental olivine. Phase abundances (in vol%) are olivine (66%), metal (32%), schreibersite (0.76%), troilite (0.46%) and chromite (0.31%). Esquel can be divided into four lithologies: (1) “pallasitic” matrix consisting of olivine fragments embedded in metal (81%); (2) large (>5 cm) olivine nodules having low metal contents (18%); (3) massive metal (0.3%); and (4) zones dominated by FeS and fine olivine (0.7%). Main-group pallasites appear to have formed by the intrusion of a highly evolved (low Ir, high Ni, Au and S) metallic magma into fragmented olivine. This model implies that FeS should be abundant in main-group pallasites, and we had speculated that examination of an exceptionally large slab might reveal a high troilite content. We found instead an exceptionally low FeS content. New compositional data confirm that Esquel has a lower Au content than other main-group pallasites having similar Ir contents. Literature data (based, however, on relatively small sections) suggest that high-Au pallasites have higher S contents than Esquel but have lower S contents than expected from a trapped-melt model. We conclude that a relatively complex model is required to explain the origin of main-group pallasites. After intrusion, the degree of crystallization of the metallic magma varied from location to location but, in almost all cases, an FeS-rich liquid either escaped or formed FeS-rich pallasitic rocks that are underrepresented in the meteorite inventory.     

秘鲁南部阿雷基帕段海岸岩基带找矿方向探讨

通过详细的岩相学和锆石U-Pb年龄的研究,秘鲁海岸岩基带阿雷基帕段的填图工作得到了补充,该岩基带岩浆活动可分为7个阶段和4个旋回,各阶段都显示出不同的岩浆容量,其地貌主要表现为岩基和岩脉。旋回Ⅰ和旋回Ⅱ代表侏罗纪岩浆活动阶段（201~145Ma）,岩浆分异为辉长岩到花岗岩;旋回Ⅲ和旋回Ⅳ代表白垩纪岩浆,岩浆分异为英云闪长岩-二长花岗岩、闪长岩与花岗闪长岩及英云闪长岩-花岗闪长岩。对角闪石和黑云母矿物晶体的数量关系研究表明,旋回Ⅰ的侵入岩有大量辉石和角闪石结晶,并伴随金-铁成矿作用;旋回Ⅱ有大量的群集角闪石晶体和呈定向排列或群集的六边形黑云母,且伴随铜-金-铁成矿作用;旋回Ⅲ侵入岩内发育角闪石和黑云母,伴随着金-铜和铁成矿作用;旋回Ⅳ发育大量角闪石和六边形黑云母,岩石更偏长英质,并伴随铜-锌-金-银-铁和铜-金-钼成矿作用。     

Some Thermal Constraints on Crustal Assimilation during Fractionation of Hydrous, Mantle-derived Magmas with Examples from Central Alpine Batholiths

We provide a model for the fractional crystallization of hydrousmantle-derived magma to form calc-alkaline plutons, based uponmass balance for geological examples of fractionation sequencesin the lower continental crust. This is complemented by a thermalmodel for the heat budget obtained from a projected phase diagramand thermodynamic data. Fractional crystallization (FC) andassimilation–fractional crystallization (AFC) paths havebeen calculated with these models and the mass ratio of assimilationto crystallization as a function of parent magma type and temperature,crustal rock fertility and temperature, and mechanism of assimilation,have been determined. When these results are combined with F(melt fraction) and r (ratio of mass assimilated/crystallized)values evaluated from geochemical data then new information,not available with the methods separately, can be deduced. Thisincludes when and at what depth and temperature in the crustthe assimilation took place, as well as the likely parent magmatype and temperature of the assimilant. Our results are presentedin simple graphical fashion to facilitate future studies thatexamine the evolution of individual calc-alkaline plutons andthe mechanisms of crustal contamination, and to improve meltmodels involving hydrous magma in volcanic arcs and in the lowercontinental crust KEY WORDS: assimilation; hydrous mantle magma; thermal models; fractional crystallization; magma mixing; Alpine batholiths; Adamello; Bergell     

The Liquid Line of Descent of Anhydrous, Mantle-Derived, Tholeiitic Liquids by Fractional and Equilibrium Crystallization--an Experimental Study at 1{middle dot}0 GPa

Two series of anhydrous experiments have been performed in anend-loaded piston cylinder apparatus on a primitive, mantle-derivedtholeiitic basalt at 1·0 GPa pressure and temperaturesin the range 1060–1330°C. The experimental data provideconstraints on phase equilibria, and solid and liquid compositionsalong the liquid line of descent of primary basaltic magmasdifferentiating in storage reservoirs located at the base ofthe continental crust. The first series are equilibrium crystallizationexperiments on a single basaltic bulk composition; the secondseries are fractionation experiments where near-perfect fractionalcrystallization was approached in a stepwise manner using 30°Ctemperature steps and starting compositions corresponding tothe liquid composition of the previous, higher-temperature glasscomposition. Liquids in the fractional crystallization experimentsevolve with progressive SiO₂ increase from basalts to dacites,whereas the liquids in the equilibrium crystallization experimentsremain basaltic and display only a moderate SiO₂ increase accompaniedby more pronounced Al₂O₃ enrichment. The principal phase equilibriacontrols responsible for these contrasting trends are suppressionof the peritectic olivine + liquid = opx reaction and earlierplagioclase saturation in the fractionation experiments comparedwith the equilibrium experiments. Both crystallization processeslead to the formation of large volumes of ultramafic cumulatesrelated to the suppression of plagioclase crystallization relativeto pyroxenes at high pressures. This is in contrast to low-pressurefractionation of tholeiitic liquids, where early plagioclasesaturation leads to the production of troctolites followed by(olivine-) gabbros at an early stage of differentiation. KEY WORDS: liquid line of descent; tholeiitic magmas; equilibrium crystallization; fractional crystallization