A molecular and carbon isotopic study towards the origin and diagenetic fate of diaromatic carotenoids

Pyrolysates of high-molecular-weight sedimentary fractions of the Duvernay Formation (Western Canada Basin) are dominated by 1,2,3,4- and 1,2,3,5-tetramethylbenzene, which, generated via beta-cleavage, indicate the presence of diaromatic carotenoids in the macromolecular aggregates. This was substantiated by desulphurization of sulphur-rich aggregates of the polar fraction, which released (partly) hydrogenated carotenoids. Furthermore, these components were important constituents of the aromatic hydrocarbon fractions and related oils. Apart from renieratane and isorenieratane, 1H NMR analysis established the aromatic substitution pattern of the most abundant component present, which was identified as a diaromatic compound with an unprecedented 2,3,6-/3,4,5-trimethyl aromatic substitution pattern. Molecular and isotopic analyses of both soluble and insoluble fractions of organic matter revealed relationships between diagenetically-derived carotenoids found in bitumen and related oils and their precursors incorporated into high-molecular-weight fractions. Aryl isoprenoids, important components in extracts and oils, were apparently derived from thermal cracking of bound diaromatic carotenoids rather than cleavage of free carotenoids as previously suggested. Furthermore, products derived from diaromatic carotenoids were substantially enriched in 13C relative to n-alkanes of algal origin. Together with the characteristic carotenoids, this isotopic enrichment provides evidence of significant contributions from photosynthetic green sulphur bacteria (Chlorobiaceae), which fix carbon via the reversed tricarboxylic acid (TCA) cycle. In spite of the prominence of these molecular signals, the overall isotopic composition of the organic matter indicated that only a very small portion of the preserved organic carbon was derived from the biomass of photosynthetic green sulphur bacteria.     

The discovery of a new infrared emission feature at 1905 wavenumbers (5.25 microns) in the spectrum of BD +30 degrees 3639 and its relation to the polycyclic aromatic hydrocarbon model

We have discovered a new IR emission feature at 1905 cm-1 (5.25 microns) in the spectrum of BD +30 degrees 3639. This feature joins the family of well-known IR emission features at 3040, 2940, 1750, 1610, "1310," 1160, and 890 cm-1 (3.3, 3.4, 5.7, 6.2, "7.7," 8.6, and 11.2 microns). The origin of this new feature is discussed and it is assigned to an overtone or combination band involving C-H bending modes of polycyclic aromatic hydrocarbons (PAHs). Laboratory work suggests that spectral studies of the 2000-1650 cm-1 (5.0-6.1 microns) region may be very useful in elucidating the molecular structure of interstellar PAHs. The new feature, in conjunction with other recently discovered spectral structure, suggests that the narrow IR emission features originate in PAH molecules rather than large carbon grains. Larger species are likely to be the source of the broad underlying "plateaus" seen in many of the spectra.     

Responses of four Indo-West Pacific seagrass species to shading

Seagrasses of the Great Barrier Reef predominantly occur in coastal regions where terrestrial inputs modify water quality and photosynthetic light is highly variable. Responses to shading were tested for Cymodocea serrulata, Halodule uninervis, Thalassia hemprichii and Zostera muelleri. In aquaria, four light treatments - high (66% surface light), moderate (31%), low (14%) and very low light (1%) treatments - were applied for 102d. Stress responses in the low and very low light treatments occurred in the following sequence: metabolic and physiological changes (reduced growth, increased pigment concentrations and photosynthetic efficiency); shedding (leaf loss, shoot loss) and production of new, altered tissue (leaves with reduced length, width and thickness). Complete shoot loss was projected after 76 (Z. muelleri) to 130d (T. hemprichii). Responses were slower in the low than in the very low treatment, therefore, efforts to minimize water quality degradation will be rewarded with delayed impacts to seagrasses.     

用小震估计强地面运动

引言虽然我们能够使用不同的正演模拟技术成功地模拟低频地面运动,但使用目前的计算技术和关于地球结构知识对3～5Hz以上频率地面反应的确定性模拟仍是一个未能解决的课题。最近,我们在多源模型(Tumarkin and Archuleta,1994)的基础上发展了一种地面运动预测的经验方法。利用多种经验格林函数方法的思路都是利     

Comparing tiltmeters for crustal deformation measurement--a preliminary report

A collection of high-precision tiltmeters is being operated at Pinon Flat Observatory, southern California, both to compare instruments and to measure tectonic deformation. We report on 1.2 years of data from four of these: two Michelson-Gale long fluid tiltmeters, one long center-pressure tiltmeter, and a shallow borehole tiltmeter. The three long-base instruments are all located on the same baseline, with a precise leveling line running between their end-monuments. At nontidal frequencies, only the two Michelson-Gale instruments show some coherence (gamma 2 = .3 for periods of 2 to 4 days), while the center-pressure instrument is correlated with air temperature at periods from a few days to a few weeks. The most stable tilt record shows a secular rate of 0.28 mu rad/a, which may be real. Over much longer times, leveling to specially stabilized bench-marks should confirm this. Comparing instruments has identified more and less successful measurement techniques; it appears that low-noise data will most probably be produced only by relatively complex and expensive instruments, though even for these, the operating costs over any reasonable lifetime will exceed the capital cost. Even the best existing sensors must be improved to measure continuous tectonic motions.