Natural arsenic attenuation via metal arsenate precipitation in soils contaminated with metallurgical wastes: II. Cumulative evidence and identification of minor processes

Accurate identification of individual As species in contaminated environments is critical because the toxicology, mobility and adsorptive properties of this element may vary substantially with its chemical forms and oxidation states. The goal of this work was to relate the geochemical behavior of As in soils contaminated by a lead smelter in Mexico, with its chemical speciation, and to achieve direct identification of low-solubility poorly-crystalline metal arsenates. Arsenic was identified as the most mobile trace element in the wastes from the smelting plant. Arsenic solubility in soils was significantly lower than its solubility in wastes, showing natural attenuation of this element. Its solubility in soil was quantitatively described in selected samples through thermodynamic equilibrium modeling. The results indicated that As solubility is controlled by solid Pb and Cu arsenate formation. The behaviors of the sequential chemical extractions were consistent with the presence of the predicted arsenates. Microscopic evidence of the formation of solid metal arsenates were obtained in fine soil fractions of selected samples with high As contents, by using the following complementary techniques: X-ray diffraction, scanning electron microscopy and transmission electron microscopy, both coupled with energy dispersive X-ray spectroscopy, and the latter with a high angle annular dark field detector. All results supported the formation of low-solubility Pb arsenates as controlling As mobility in the samples studied, in which As(V) adsorption to Fe (hydr)oxides was not the dominant process of natural attenuation.     

Effects of fish farm loadings on seagrass (Posidonia oceanica) distribution, growth and photosynthesis

The spatial extent and timing of the impact of fish farms on the distribution and performance of a Posidonia oceanica meadow were examined in an embayment of the south-eastern coast of Spain (Hornillo Bay, Murcia). Changes in seagrass distribution were determined using available seagrass mapping (from 1988, i.e., before the onset of aquaculture activities and 1998) and by successive sampling in 1994 and 1998. Environmental variables (light attenuation coefficient, water-column dissolved nutrients and organic content of sediments) together with plant performance (shoot biomass, leaf growth rate, photosynthetic activity, carbohydrate reserves, the number of leaves per shoot, epiphyte loads and herbivore pressure) were measured in plants affected by organic discharges, and were compared with those found in reference healthy plants over an annual growth cycle. Since the onset of fish farm activity, 11.29 ha of P. oceanica meadow has been completely lost and 9.86 ha significantly degraded, thus resulting in a total affected area which accounts for about 53% of the former meadow, or 7-fold the fish farming area. Unequal propagation of seagrass die-off or degradation reflects the relevance of local factors such as depth and hydrodynamism on the true extent of fish farm impact. Water transparency decreases and dissolved nutrient and organic content of sediments increases in the vicinity of cages compared to distant reference stations, thus supporting the notion of environmental gradients caused by the organic release from cages, which spreads outwards. Shoot size, leaf growth rate and the number of leaves per shoot in plants close to the fish farm decreased. Moreover, low leaf growth and low rhizome carbohydrate concentration (always relative to that found in an undisturbed area) indicated carbon budget imbalances. Since light reduction in the affected area was only modest (31% of light reaching the sea surface, while at the same depth this figure was 39% at the reference site), and light availability was well above the minimum requirement estimated for this species, neither this factor nor epiphyte overgrowth (epiphyte load was lower in the affected area) seem to explain such carbon imbalances or the observed meadow regression. Alternatively, the high herbivore pressure found in the affected zone suggests that overgrazing is one of the main causes of decreasing shoot sizes and hence of carbon imbalance, reduced growth and shoot mortality. The impact of fish farms on seagrasses, therefore, seems to be highly variable and depends on complex interactions between a large number of processes.     

Interacting Kasner-type cosmologies

It is well known that Kasner-type cosmologies provide a useful framework for analyzing the three-dimensional anisotropic expansion because of the simplification of the anisotropic dynamics. In this paper relativistic multi-fluid Kasner-type scenarios are studied. We first consider the general case of a superposition of two ideal cosmic fluids, as well as the particular cases of non-interacting and interacting ones, by introducing a phenomenological coupling function q(t). For two-fluid cosmological scenarios there exist only cosmological scaling solutions, while for three-fluid configurations there exist not only cosmological scaling ones, but also more general solutions. In the case of triply interacting cosmic fluids we can have energy transfer from two fluids to a third one, or energy transfer from one cosmic fluid to the other two. It is shown that by requiring the positivity of energy densities there always is a matter component which violates the dominant energy condition in this kind of anisotropic cosmological scenarios.     

Population dynamics of the seagrass Cymodocea nodosa in Ria Formosa lagoon following inlet artificial relocation

The population dynamics of the seagrass Cymodocea nodosa was investigated in three meadows differently affected by the artificial relocation of an inlet in the western sector of the Ria Formosa lagoon, southern Portugal. One meadow was subjected to increasing currents that caused erosion, another one was subjected to an initial episode of burial and a third meadow was undisturbed by the inlet opening. The hydrodynamic/sedimentary condition of meadows was assessed through comparative sediment analysis between the meadow and the adjacent unvegetated area.     

200?years of European temperature variability: insights from and tests of the proxy surrogate reconstruction analog method

Spatially resolved climate reconstructions are commonly derived from long instrumental series and proxy data via linear regression based approaches that use the main modes of the climate system. Such reconstructions have been shown to underestimate climate variability and are based upon the assumption that the main modes of climate variability are stationary back in time. Climate models simulate physically consistent climate fields but cannot be taken to represent the real past climate trajectory because of their necessarily simplified scope and chaotic internal variability. Here, we present sensitivity tests of, and a 200-year temperature reconstruction from, the PSR (Proxy Surrogate Reconstruction) method. This method simultaneously capitalizes on the individual strengths of instrumental/proxy data based reconstructions and model simulations by selecting the model states (analogs) that are most similar with proxy/instrumental data available at specific places and specific moments of time. Sensitivity experiments reveal an optimal PSR configuration and indicate that 6,500 simulation years of existing climate models provide a sufficient pool of possible analogs to skillfully reconstruct monthly European temperature fields during the past 200?years. Reconstruction verification based upon only seven instrumental stations indicates potential for extensions back in time using sparse proxy data. Additionally the PSR method allows evaluation of single time series, in this case the homogeneity of instrumental series, by identifying inconsistencies with the reconstructed climate field. We present an updated European temperature reconstruction including newly homogenized instrumental records performed with the computationally efficient PSR method that proves to capture the total variance of the target.     

Using an Enhanced Dataset for Reassessing the Source Region of the 2003 Armer��a, Mexico Earthquake

We present a fresh look at the source region of the 22 January 2003 M _w 7.4 Armería earthquake, which occurred off the Pacific coast of the state of Colima, Mexico, near the town of Armería. The effects of this earthquake in the neighboring states of Colima and Jalisco were different and stronger than those of previous recent major earthquakes in the region. This earthquake and its aftershocks were recorded by two local telemetered seismograph networks (RESCO and RESJAL). From 22 January to 24 January 2003, no important seismicity was located on the plates interface, or within the Rivera Plate, and most epicenters were located west of the Armería River, which is the western border of the Colima Graben, and is located outside of the Colima Gap region. From 24 January to 31 January, the seismicity recorded by both networks showed a migration in depth, with an almost vertical offshore distribution between 4 and 24?km in depth. For this period, a seven-station portable digital seismograph network, equipped with three-component seismometers, was deployed in the epicentral area to study the aftershock sequence in detail. With this denser network more than 200 M _L?>?2.0 aftershocks were recorded. The aftershock foci were deeper than those recorded during the early period and most of them locate on a hypothetical 12° dipping interface between the Rivera and North American Plates. Composite focal mechanism solutions for the aftershocks located during both periods indicate a reverse fault character that changes with time. Analysis of the new dataset still indicates that the earthquake was a shallow intraplate event.     

Isolation and characterization of 45 Polymorphie microsatellite loci of turbot (Scophthalmus maximus) and cross-species amplification

Turbot(Scophthalmus maximus) is a flatfish species commercially important for aquaculture.In this study,we generated a microsatellite-enriched genomic DNA library for Scophthalmus maximus,and then isolated and characterized 45 microsatellite loci by genotyping 30 individuals.The observed number of alleles ranged from 2 to 19 with an average of 6.24,while the effective number of alleles ranged from 1.30 to 11.11 with an average of 3.66.The expected heterozygosities varied from 0.235 to 0.925 4 and polymorphic information content ranged from 0.204 4 to 0.903 3,with an average of 0.622.Twelve loci deviated significantly from Hardy-Weinberg equilibrium,and no significant linkage disequilibrium was observed between any pair of loci after Bonferroni correction.In cross-species amplification,five flatfish species(Paralichthys lethostigma,Verasper moseri,platichthys stellatus,Hippoglossoides dubius and Cynoglossus semilaevis) showed at least one polymorphic locus.These polymorphic microsatellite loci should prove useful for population analysis of turbot and other related species.     

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