Biogeochemical effects of disturbance in shallow water sediment by macroalgae harvesting boats

In the shallow water of Orbetello lagoon, macroalgae harvesting boats produce sediment disturbance. To evaluate the effect of this, during 2001-2002, a trial study was carried out in the lagoon in order to: verify seasonal and diurnal trends in nutrients and estimate the quantity of resuspended organic sediment. An unbalanced and balanced ANOVA (one and two way) analysis was applied. The disturbance did not produce strong and lasting eutrophication effects. In the seasonal survey, dissolved inorganic nitrogen (DIN) and soluble reactive phosphorus (SRP) showed significant decreases in disturbed areas at the end of the trial, while the control area showed a constant, significant increase. Dissolved organic nitrogen (DON) and phosphorus (DOP) significantly increased everywhere. In disturbed areas, sediment redox (Eh((NHE))) increased and porosity values decreased, contrary to the control area. Total organic carbon (TOC) remained unchanged in disturbed areas, but increased in the control area, where the C:P ration increased. The fall-out of sedimentary material resuspended by boat action for as far as 50 m from the boat route, was 189 g(dw)m(-2) made up mainly of organic matter. This disturbance could be the cause of change in vegetation in the lagoon.     

Mercury distribution in Douro estuary (Portugal)

Determinations of dissolved reactive and total dissolved mercury, particulate and sedimentary mercury, dissolved organic carbon (DOC), particulate organic carbon (POC) and suspended particulate matter (SPM) have been made in the estuary of river Douro, in northern Portugal. The estuary was stratified by salinity along most of its length, it had low concentrations of SPM, typically <20 mg dm(-3), and concentrations of DOC in the range <1.0-1.8 mg dm(-3). The surface waters had a maximum dissolved concentration of reactive mercury of about 10 ng dm(-3), whereas for the more saline bottom waters it was about 65 ng dm(-3). The surface waters had maximum concentrations of total suspended particulate mercury of approximately 7 microg g(-1) and the bottom waters were always <1 microg g(-1). Concentrations of mercury in sediments was low and in the range from 0.06 to 0.18 microg g(-1). The transport of mercury in surface waters was mainly associated with organic-rich particulate matter, while in bottom waters the dissolved phase transport of mercury is more important. Lower particulate organic matter, formation of chlorocomplexes in more saline waters and eventually the presence of colloids appear to explain the difference of mercury partitioning in Douro estuarine waters.     

Geochemical processes during five years of aquifer storage recovery

A key factor in the long-term viability of aquifer storage recovery (ASR) is the extent of mineral solution interaction between two dissimilar water types and consequent impact on water quality and aquifer stability. We collected geochemical and isotopic data from three observation wells located 25, 65, and 325 m from an injection well at an experimental ASR site located in a karstic, confined carbonate aquifer in South Australia. The experiment involved five major injection cycles of a total of 2.5 x 10(5) m3 of storm water (total dissolved solids [TDS] approximately 150 mg/L) into the brackish (TDS approximately 2400 mg/L) aquifer. Approximately 60% of the mixture was pumped out during the fifth year of the experiment. The major effect on water quality within a 25 m radius of the injection well following injection of storm water was carbonate dissolution (35 +/- 6 g of CaCO3 dissolved/m3 of aquifer) and sulfide mineral oxidation (50 +/- 10 g as FeS2/m3 after one injection). < 0.005% of the total aquifer carbonate matrix was dissolved during each injection event, and approximately 0.2% of the total reduced sulfur. Increasing amounts of ambient ground water was entrained into the injected mixture during each of the storage periods. High 14C(DIC) activities and slightly more negative delta13C(DIC) values measured immediately after injection events show that substantial CO2(aq) is produced by oxidation of organic matter associated with injectant. There were no detectable geochemical reactions while pumping during the recovery phase in the fifth year of the experiment.     

Surface flow boundary conditions in modeling land subsidence due to fluid withdrawal

Land subsidence due to subsurface fluid (water, gas, oil) withdrawal is often predicted by either finite element or finite difference numerical models based on coupled poroelastic theory, where the soil is represented as a semi-infinite medium bounded by the traction-free (ground) surface. One of the variables playing a most important role on the final outcome is the flow condition used on the traction-free boundary, which may be assumed as either permeable or impermeable. Although occasionally justified, the assumption of no-flow surface seems to be in general rather unrealistic. A permeable boundary where the fluid pressure is fixed to the external atmospheric pressure appears to be more appropriate. This paper addresses the response, in terms of land subsidence, obtained with a coupled poroelastic finite element model that simulates a distributed pumping from a horizontal aquifer confined between two relatively impervious layers, and takes either a permeable boundary surface, i.e., constant hydraulic potential, or an impermeable boundary, i.e., a zero Neumann flow condition. The analysis reveals that land subsidence is rather sensitive to the flow condition implemented on the traction-free boundary. In general, the no-flow condition leads to an overestimate of the predicted ground surface settlement, which could even be 1 order of magnitude larger than that obtained with the permeable boundary.     

Monitoring chemical contamination levels in the Mediterranean based on the use of mussel caging

Within the framework of the biointegrator network (RINBIO), 92 man-made cages containing mussels (Mytilus galloprovincialis), distributed over 1800 km of the French Mediterranean coast, made it possible to assess chemical contamination by heavy metals (Cd, Hg, Zn, Pb, Cu, Ni, Cr, As) and organic compounds (DDT, PCBs, HAP). The caging technique was adopted to compensate for the scarcity of natural shellfish stocks in the Mediterranean and to enable comparison of the sites regardless of their physicochemical and trophic characteristics. Models linking a biometric parameter (the condition index) to pollutant levels make it possible to adjust raw data on contamination for a reference individual, by making a clear distinction between physiological factors (growth) and environmental ones. The results demonstrate significant levels of pollutants in sites heretofore unsampled; the pollution occurs at limited areas, and the sources have been identified. Moreover, average contamination levels are comparable to those measured in wild species and in other areas. Overall, the research demonstrates the reliability of this methodological approach for monitoring marine pollution, especially in the Mediterranean.     

Protective effect of phospholipid hydroperoxide glutathione peroxidase (PHGPx) against lipid peroxidation in mussels Perna perna exposed to different metals

Levels of antioxidant defenses and lipid peroxidation were evaluated in mussels exposed to lead (200 mg/l), iron (500 microg/l), cadmium (200 microg/l) and copper (40 microg/l), for 12, 24, 72 and 120 h. Glutathione S-transferase (GST) activity was unchanged with all treatments. Catalase (CAT) increased after 120 h of exposure to all metals. Mussels exposed to Cd for 12 h, and to Cu and Fe for 120 h had increased lipid peroxidation, which might be associated to decreased levels of reduced glutathione (GSH) and glutathione peroxidase (GPx) activity. Pb exposure caused GSH depletion after 12 h and increased GPx activity after 120 h. Negative correlations were observed between the enzyme phospholipid hydroperoxide glutathione peroxidase (PHGPx) and malonaldehyde (MDA) levels after Fe and Cu exposure, indicating a protective role of PHGPx against lipid peroxidation, and suggesting the use of this enzyme as a new potential biomarker of toxicity associated with contaminant exposure in mussels.     

克瑞吉法和矿块的平均品位

储量计算和品位控制中最重要的一个问题,就是在样品数量十分有限的情况下如何精确估计一个矿块的品位的问题.由于在采矿场中经常有出乎预料的品位变化,许多矿山的日产量很不稳定.因此,需要对各个矿块的品位作出最佳的估计.(1)样品与它所代表的矿块品位之间普遍存在着差异.如果研究下述的实例,对此就会有很好的理解.假设每个10×10平方英尺     

THE GRANITISATION OF CHINA

If they are separated according to their geological age and reported on amap,the post-Palaeozoic granites of China seem to betray a regular distributionin space and time.They emerge along a definite net of tectonic fissures; andthey shift gradually eastward toward the pacific margin of the land. This peculiar distribution suggests that granitisation is a specific andperennial geological process,possibly playing a fundamental part in the buildingof continents.     

ON THE PRESUMABLE EXISTENCE OF A WORLD-WIDE SUB-ARCTIC SHEET OF HUMAN CULTURE AT THE DAWN OF THE NEOLITHIC

1. The facts. On a particular day of July 1931,during the Haardt-Citroentrans-asiatic Expedition,I happened to collect,near Chikuchinze,in theTurfan area (Chinese Turkestan),two perfectly similar,rostrated     

THE NEW PETROLOGY

I suppose that one is not far wrong in saying that Petrology is thescience of rocks.But we have not made ourselves very clear by saying it.To the average student of the subject.who must judge from what he is taught,