Mg2+ removal in the system Mg2+—amorphous SiO2—H2O by adsorption and Mg-hydroxysilicate precipitation

Two chemical processes can remove Mg²⁺ from suspensions containing amorphous silica (am-SiO₂) at low temperatures: adsorption and precipitation of a Mg-hydroxysilicate resembling sepiolite. Mg²⁺ removal from am-SiO₂ suspensions was investigated, and the relative role of the two removal processes evaluated, as a function of: pH, ionic strength, Mg²⁺ concentration, and temperature.The extent of Mg²⁺ adsorption onto am-SiO₂ decreases with increasing NaCl concentration due to displacement of Mg²⁺ by Na⁺. At NaCl concentrations of 0.05 M and above, adsorption occurs only at pH values above 8.5, where rapid dissolution of am-SiO₂ gives rise to high concentrations of dissolved silica, resulting in supersaturation with respect to sepiolite. Removal of Mg²⁺, at concentrations of 40 to 650 μM, from am-SiO₂ suspensions in 0.70 M NaCl at 25 °C occurs at pH 9.0 and above. Experiments show that under these conditions adsorption and Mg-hydroxysilicate precipitation remove Mg²⁺ at similar rates. For 0.05 M Mg²⁺, at 0.70 M ionic strength and 25 °C, measurable Mg²⁺ removal occurs down to ca. pH 7.5 but is primarily due to Mg-hydroxysilicate precipitation. For the same solution conditions at 5°C, Mg²⁺ removal occurs above pH 8.0 and is primarily due to adsorption.Assuming that increasing pressure does not greatly enhance adsorption, Mg²⁺ adsorption onto am-SiO₂ is an insignificant process in sea water. The surface charge of pristine am-SiO₂ in sea water is primarily controlled by interactions with Na⁺. The principal reaction between Mg²⁺ and am-SiO₂ in marine sediments is sepiolite precipitation.The age distribution of sepiolite in siliceous pelagic sediments is influenced by temperatures of bottom waters and by geothermal gradients.     

Ikaite: enigmatic crystals of cold waters

Ikaite, found as a constituent of tufa chimneys and mounds in Ikka Fjord, Greenland, is only formed in waters close to freezing point. At higher temperatures it inverts to calcite, forming impressive pseudomorphs which have been found at a large number of locations world‐wide of varying ages, sometimes in association with glacial deposits. The Ikka Fjord deposits, first described by the Danish geologist Hans Pauly, were key to understanding the nature of these widely reported pseudomorphs.     

Oxygen‐18 dynamics in precipitation and streamflow in a semi‐arid agricultural watershed,Eastern Washington,USA

Understanding flow pathways and mechanisms that generate streamflow is important to understanding agrochemical contamination in surface waters in agricultural watersheds. Two environmental tracers, δ¹⁸O and electrical conductivity (EC), were monitored in tile drainage (draining 12 ha) and stream water (draining nested catchments of 6‐5700 ha) from 2000 to 2008 in the semi‐arid agricultural Missouri Flat Creek (MFC) watershed, near Pullman Washington, USA. Tile drainage and streamflow generated in the watershed were found to have baseline δ¹⁸O value of ?14·7‰ (VSMOW) year round. Winter precipitation accounted for 67% of total annual precipitation and was found to dominate streamflow, tile drainage, and groundwater recharge. ‘Old’ and ‘new’ water partitioning in streamflow were not identifiable using δ¹⁸O, but seasonal shifts of nitrate‐corrected EC suggest that deep soil pathways primarily generated summer streamflow (mean EC 250 µS/cm) while shallow soil pathways dominated streamflow generation during winter (EC declining as low as 100 µS/cm). Using summer isotopic and EC excursions from tile drainage in larger catchment (4700‐5700 ha) stream waters, summer in‐stream evaporation fractions were estimated to be from 20% to 40%, with the greatest evaporation occurring from August to October. Seasonal watershed and environmental tracer dynamics in the MFC watershed appeared to be similar to those at larger watershed scales in the Palouse River basin. A 0·9‰ enrichment, in shallow groundwater drained to streams (tile drainage and soil seepage), of δ¹⁸O values from 2000 to 2008 may be evidence of altered precipitation conditions due to the Pacific Decadal Oscillation (PDO) in the Inland Northwest. Copyright © 2009 John Wiley & Sons, Ltd.     

Trace metal composition of colloidal organic material in marine environments

Marine colloidal material (1 kDa–0.2 μm) was isolated by cross-flow ultrafiltration followed by diafiltration and freeze-drying from surface waters of the Gulf of Mexico and the Middle Atlantic Bight (MAB), as well as from estuarine waters of Galveston Bay. Elemental characterization of isolated colloidal material included organic carbon (OC) and selected trace metal (Cu, Pb, Zn, Cd, Co, Ni, Cr, Be, Fe, Al, Mn, V, Ba, and Ti) determinations. It was found that levels of these metals in marine colloids ranged from <0.1 to 50 μg/g colloidal matter, except for Fe which generally had a concentration >120 μg/g. Most metals (Cu, Pb, Zn, Ni, Al, Mn, V, and Ti) had an average concentration >1 μg/g while concentrations of Cd, Co and Be were usually <1 μg/g. Metal concentrations (μg/g) in isolated colloids were, in general, higher in Galveston Bay than in the Gulf of Mexico, suggesting either high abundance of trace metals in estuarine waters or differences in organic matter composition. Higher colloidal metal concentrations in the MAB than in the Gulf of Mexico might be due to higher terrestrial inputs in the MAB. Colloidal metal concentrations (μg/g) were generally lower than those in average soils, continental crust and suspended particles. However, metal/aluminum ratios (Me/Al) in isolated marine colloids were significantly higher than those for average soils and continental crust. Most importantly, colloids had a metal composition and metal/OC ratio (Me/C) similar to humic substances and marine plankton, suggesting that marine colloids largely originate from planktonic sources and are composed of predominately organic components. The Me/C ratios of Galveston Bay colloids followed the sequence of Cu>Ni, Cr, Zn>Mn>Co>Pb, Cd, which is similar to the Irving–Williams order except for Mn, suggesting that the interaction of metals with marine colloids is determined by the affinity of metals for specific organic ligands.     

Mineralogy and petrogenesis of lunar magnesian granulitic meteorite Northwest Africa 5744

Lunar meteorite Northwest Africa (NWA) 5744 is a granulitic breccia with an anorthositic troctolite composition that may represent a distinct crustal lithology not previously described. This meteorite is the namesake and first‐discovered stone of its pairing group. Bulk rock major element abundances show the greatest affinity to Mg‐suite rocks, yet trace element abundances are more consistent with those of ferroan anorthosites. The relatively low abundances of incompatible trace elements (including K, P, Th, U, and rare earth elements) in NWA 5744 could indicate derivation from a highlands crustal lithology or mixture of lithologies that are distinct from the Procellarum KREEP terrane on the lunar nearside. Impact‐related thermal and shock metamorphism of NWA 5744 was intense enough to recrystallize mafic minerals in the matrix, but not intense enough to chemically equilibrate the constituent minerals. Thus, we infer that NWA 5744 was likely metamorphosed near the lunar surface, either as a lithic component within an impact melt sheet or from impact‐induced shock.     

Sirius Passet,Greenland and the Cambrian Explosion

Throughout Earth history there have been many important milestones: e.g. the emergence of life, the rise of oxygen in the atmosphere, snowball Earth events. One of these major events was the emergence of multicellular life, which, as we are all told in Palaeontology lectures, took place in the Cambrian, when a sudden flowering of life forms emerged, including all of the major groups we have today: the ‘Cambrian explosion’. Two great questions emerge: what happened before this (a problem which worried Darwin as it seemed to threaten his thesis of steady evolution) and how, in detail did this ‘explosion’ take place?     

From dog sledge to satellite: Knud Ellitsgaard‐Rasmussen (1923–2009), geologist

Knud Ellitsgaard‐Rasmussen's career spanned an astounding period of change in the science. He was not a geologist whose name was widely known and it is probably true to say that few students today, even in his native Denmark, have heard of him. He was nevertheless a figure of huge importance to geological research in his role as someone who directed geology along very productive lines, creating an environment which was highly conducive to the successful careers of many talented researchers. He saw and presided over geology as it evolved from the heroic days of an individual with a dog‐sledge and a microscope to later days with armies of personnel, aircraft, marine geophysical vessels, the GPS and the ICP‐MS. He led the mapping of a subcontinent.     

HUMAN GEOGRAPHY OF THE AMERICAN TROPICS: A FORTY-YEAR REVIEW

For a decade or so after World War II, human geographers working in the American tropics found socio-political conditions and resultant research topics little changed from those before the war. This was in contrast to the Old World tropics where decolonization processes and the demands of economic development and new nation building produced divergent research currents, For the first half of the period under review, the American tropics continued to be the province largely of geographers with culturalhistorical questions grounded in natural historical bases. The legacy is Humboldt's; the practitioners most notably students of Carl Sauer or German counterparts such as Carl Troll. French and British regionalist approaches, strong in the region before World War II, survived less successfully. By the 1980s, however, broad pan-tropical currents of geographic discourse and debate had become established. New practices and theories were formulated and tested as North Atlantic geographers borrowed from antipodean innovators and others working in the Asian and African tropics. Since the 1980s, there have been greater efforts at dialogue and collaboration with host country colleagues. As might be expected in this era of ‘globalization’, national research styles and agendas have become less evident. This paper offers a highly selective map of research nodes within tropical Americanist geography since the early 1950s. The selection of examples includes qualitative criteria, but more importantly, research that signify stasis or intensification as well as turning points and departures in the overall development of this literature. The contours of this history suggest some highly evolved, even idiosyncratic enterprises, but in the main, it is an unfolding that suggests broad congruencies with human geographic work elsewhere in the tropics.     

Evolution of Pangea: paleomagnetic constraints from the Southern Alps, Italy

A new early Late Triassic paleopole for Adria has been obtained from the Val Sabbia Sandstone in the Southern Alps. As Early Permian and Jurassic-Cretaceous paleomagnetic data from para-autochthonous regions of Adria such as the Southern Alps are consistent with ‘African’ APWPs[1–2], paleomagnetic data from this region can be used to bolster the West Gondwana APWP in the poorly known Late Permian-Triassic time interval. The Southern Alpine paleopoles are integrated with the West Gondwana and Laurussia APWPs of Van der Voo [1] and used to generate a tectonic model for the evolution of Pangea. The Early Permian overall mean paleopole for West Gondwana and Adria, in conjunction with the coeval Laurussia paleopole, support Pangea B of Morel and Irving [3]. The Late Permian/Early Triassic and the Middle/Late Triassic paleopoles from Adria and Laurussia support Pangea A-2 of Van der Voo and French [4]. The phase of transcurrent motion between Laurasia and Gondwana[5] that caused the Pangea B to A-2 transition occurred essentially in the Permian (at the end of Variscan orogeny) with an average relative velocity of approximately 10 cm/yr. Finally, the Late Triassic/Early Jurassic paleopoles from West Gondwana and Laurussia agree with Pangea A-1 of Bullard et al. [6], the widely accepted Pangea configuration at the time of the Jurassic breakup.