The use of selected research methods to describe the pore space of dolomite from copper ore mine,Poland

Basic knowledge of the characteristics of copper-bearing rock such as dolomite is essential to locate those areas of the deposit which have different structural and textural properties. Those regions can be important in terms of the assessment of the possibilities of gas accumulating in them as well as in terms of gasogeodynamic hazard. To better understand those threats, it is necessary to locate, monitor and analyse those areas in detail. This article characterises the structural and textural parameters of dolomite from the Polkowice–Sieroszowice copper mine in Poland. The study involved five samples from various areas of the mine. A number of research methods were selected. Reflected and transmitted light microscopy (MS), computer microtomography (Micro-CT), gas adsorption porosimetry (LPNA), mercury porosimetry (MIP), helium and quasi-fluid pycnometry (Pycno. He, DryFlo). Each of the methods examined a different scope of the pore size, which enabled to achieve a full view of the porous nature of those rocks. We determined their porosity (open, closed, total), surface area as well as mean size and volume of the pores. Also, we studied the character and the pore size distribution from a few nm to a few mm. Comprehensive dolomite properties analyses showed that these rocks are characterised by high structural variability. They have mesopores and macropores but few micropores. The analyses presented in this paper are determined by a large petrographic diversity of the deposits containing dolomite. This article is an example of a comprehensive approach to the rock analysis in copper ore mines.     

Reaction of soil enzymes and spring barley to copper chloride and copper sulphate

Study was carried out to compare the effect of the degree of contamination of soil with copper on the soil enzyme activity, depending on the type of chemical compound with which a metal reaches the soil and on the method of soil use. An effect of increasing doses of copper on growth and the development of spring barley has been studied. The study was carried out as a pot experiment on two types of soil: loamy sand and light loam. Copper was introduced to soil as copper(II) sulphate(VI) and copper(II) chloride at four doses: 150, 300, 450 and 600 mg Cu²⁺ kg^?1 d.m. of soil. Soil without copper was used as a control sample. The experiment showed that contamination of soil with copper applied as CuCl₂ and CuSO₄·5H₂O upset the homeostasis of soil. Dehydrogenases and urease were the most sensitive to contamination of soil with Cu²⁺, both as copper(II) chloride and as copper(II) sulphate(VI), and acid phosphatase and alkaline phosphatase were the least sensitive. Greater changes in enzymatic activity were observed in loamy sand than in light loam. The differences in the impact of copper(II) sulphate(VI) and copper(II) chloride on the soil microbiome were relatively small, because mean ED₅₀ for copper(II) chloride was 341 mg Cu²⁺ kg^?1 d.m. of soil, and for copper(II) sulphate(VI) it was 364 mg Cu²⁺ kg^?1 d.m. of soil. This inhibitory effect of copper persisted throughout the period of the experiment. The sensitivity of spring barley to copper compounds was lower than the enzymes under study.     

A simulation study of capillary transport,preferential retention and distribution of salts in historic sandstone buildings

Salt crystallisation is a major problem of deterioration in historic stone buildings, monuments and sculptures. The capillary rise of soil water is one of the primary sources of salts in stone structures, which evaporates leaving the salts behind. It has been noted that the spatial distribution profile of different species of salts crystallised in historic stone buildings is not homogeneous, i.e. different salts crystallise at different locations. The capillary transport and inhomogeneous spatial distribution of different salts in the porous building materials has been considered to be a result of solubility-dependent crystallisation; however, the factors responsible for this phenomenon are not clearly known. This paper aims to investigate the factors influencing the differential distribution of salts during capillary rise of soil water. In this study, the capillary transport of salts was simulated on two different sandstones—Locharbriggs, a Permo–Triassic, red sandstone and Stoke Hall, a Carboniferous, buff sandstone. The experiments were carried out under controlled environmental conditions to eliminate the possibility of evaporation-driven crystallisation of salts depending on their solubilities. The results indicate that fractionation or differential distribution of salts takes place even in the absence of evaporation and crystallisation. The sandstones exhibit properties like an ion exchange column, and ionic species present in the salt solution show differential distribution within the porous network of sandstone.     

Changes in water chemistry along the newly formed High Arctic fluvial–lacustrine system of the Brattegg Valley (SW Spitsbergen,Svalbard)

Changes in water chemistry along the High Arctic fluvial–lacustrine system located in Wedel Jarlsberg Land in the SW Spitsbergen (Svalbard) were investigated during the summer season of 2010 and 2011. The newly formed river–lake system consists of three lakes connected with the Brattegg River. The first bathymetric measurements of these lakes were made by the authors in 2010. The Brattegg River catchment represents a partly glaciered Arctic water system. The studied lakes are characterized by low mineralization and temperature of water. The value of the electrolytic conductivity (EC) ranges from 30.2 to 50.5 μS cm^?1 and the temperature of surface water from 1.5 to 7.8 °C. The temperature increase takes place downstream starting from Upper Lake to the outflow from Myrktjørna Lake. The waters of lakes have higher temperatures than the stream. The predominant ions are HCO₃ ^? (up to 16.5 mg L^?1), Cl^? (6.66–8.53 mg L^?1), Ca²⁺ (2.40–4.45 mg L^?1) and Na⁺ (2.65–3.36 mg L^?1). The highest values of ammonium and DOC found in the lowest Myrktjørna Lake seem to be related to the presence of aquatic organisms and also birds. From the group of 10 analyzed microelements, increased concentrations of aluminum, up to almost 500 μg L^?1, are present in the lakes’ water. Water isotopic composition ranges for δ¹⁸O and δ²H, from ?10.6 to ?10.9‰ and from ?70.8 to ?72.3‰, respectively. The vertical zonality of lake waters is manifested in a decrease in the temperature and increase in EC and chemical elements concentrations.     

Basin hydrogeological characterization using remote sensing,hydrogeochemical and isotope methods (the case of Baro-Akobo,Eastern Nile,Ethiopia)

Hydrogeochemical and isotopic signatures of the waters of the Baro-Akobo River Basin show deviation from signatures in other Ethiopian river basins. In this study, hydrogeochemical and isotope methods were employed to determine regional and local hydrogeology and characteristics of the basin. Optical, thermal and radar remote sensing products were used to update geological and structural maps of the basin and determine sampling points using the judgment sampling method. A total of 363 samples from wells, springs, rivers, lakes, swamps and rain were collected for this study, and an additional 270 water quality data sets were added from previous studies. These data were analyzed for their hydrogeochemical characteristics and isotope signatures. Analysis of the oxygen, deuterium and tritium isotopes shows the groundwater of the basin is modern water. Among all basins in Ethiopia, the Baro-Akobo Basin shows the highest enrichment. This indicates the proximity of the rainfall sources, which presumably are the Sudd and other wetlands in South Sudan. The hydrochemical properties of the waters show evapotranspiration is the dominant hydrologic process in the basin and explains the large amount of water that is lost in the lowland plain. Analysis of radon-222 shows no significant groundwater flux over the wetlands, which are part of Machar Marshes. This shows evaporation to be dominant hydrologic process in this zone. Results from all analyses help explain the limited holding capacity of the aquifers in the recharge zone and their vulnerability to anthropogenic impacts and climate variability. There is a trend of decreasing surface flow and rainfall and increasing water soil erosion.     

Landfill site selection using combination of fuzzy logic and multi-attribute decision-making approach

During the last decades, growth of urbanization and industrialization led to an increase in solid waste generation. Landfilling is the most prevalent ultimate disposal method for the municipal solid wastes in developing countries. The rapid municipal solid waste generation in Markazi province (central part of Iran) causes the need for precision in finding a suitable landfill site selection. In the present study, 12 factors (environmental and socioeconomic factors) have been applied to select the landfill site in Markazi province, Iran. The different methods including the analytic network process (ANP) combined with fuzzy linguistic quantifier, ordered weighted average (OWA), and weighted linear combination (WLC) approach in geographic information system was applied to find an appropriate landfill site. The OWA operator function permits the evaluation of the wide spectrum of consequences (with different scenario) obtained from different management strategies. Results revealed that integration of fuzzy logic, ANP, and OWA provides flexible and better ideas compared to the Boolean logic and WLC to select a suitable landfill site.     

Submersion simulation in a typical debris flow watershed of Jianzhuangchuan catchment,Loess Plateau

Debris flow is one of the most serious and frequent geological disasters that occur in the Loess Plateau. The outbreak of a debris flow is sudden, ferocious, swift, and destructive. The characteristics and mechanism of debris flow were explored in this study via survey, numerical simulation, and simulation analysis in a Loess Plateau area (Huangling County, Shaanxi Province, China). Numerical models and formulas corresponding to the occurrence and movement mechanism were established based on the HEC-RAS, HEC-GeoRAS, and SWAT results. The range of debris flow deposition was determined through capturing the debris flow free surface. A hydrological model and critical rainfall threshold were determined in order to provide technical support for debris flow forecasting in the Loess Plateau. The results suggest that 10-year floods do not submerge any portion of the basin. One village area was affected by the 100-year flood (total area of 0.648 km²) while four villages areas were submerged by the 1000-year flood (total area of 1.39 km²). The method presented here may provide a reliable scientific basis for mitigating loss due to debris flow hazards.     

Hydrological situation of a typical watershed in the Loess Tableland Area of China over the past 30 years

Due to deficient water resources in the Loess Plateau, watershed management plays a very important role, not only for ecological and environmental protection but also for the social development of the region. To better understand the hydrological and water resource variations in the typical watershed of the Loess Plateau and the Qinghe River Basin, the influences of land cover and climate change were analysed, and a SWAT model was built to simulate the response of the hydrological situation to land cover changes that have occurred over the past 30 years. The results demonstrated that the main land cover change occurring in the Qinghe River Basin was the conversion of land cover from grassland to woodland and farmland from the late 1980s to 2010. Woodland and farmland took 87.36 and 10.55%, respectively, from the overall area transferred over 20 years and more than 18% of the total watershed area. Hydrological simulation results indicated that land cover played a predominant role in the hydrological variation of the Qinghe River Basin, although the effects of climate change should not be discounted. The significant changes in land cover could be superimposed by policy orientation and economic requirements. Although it is hard to evaluate the land cover changes and the corresponding hydrological responses in a simple language, related analyses have demonstrated an increasing trend of runoff in the dry season, while there is a somewhat decreasing trend during the flood season in the river basin. There results could be significant and provide a positive influence on both future flood control and the conservation of water and soil.     

Equivalent-linear site response analysis on the site of the historical Trakošćan Castle,Croatia, using HVSR method

This paper presents a major extension of seismic vulnerability research project on the site of Trako??an Castle based on the initial horizontal-to-vertical-spectral-ratio (HVSR) results from Stanko et al. (2016). The estimated HVSR site frequencies and HV amplification at Trako??an Castle can only be used as an indication of the initial soil site frequency and amplification, so-called natural soil model, corresponding to the subsoil profile without the influence of an earthquake. The equivalent-linear (EQL) site response analysis has been carried out for different earthquake scenarios for a maximum input rock peak ground acceleration (PGA_ROCK) that corresponds to return periods of 95 (0.08 g), 475 (0.18 g) and 1000 years (0.31 g). The aim of the research is to evaluate structural seismic design responses and to determine type and degree of damage caused by local site effect, which is the result of an alluvial basin and topographic influences. The main objective of this research is the formation of local microseismic zones based on an EQL analysis: surface spectral acceleration and amplification maps at the predominant frequency. Based on the HVSR frequency response of the core structure of Trako??an Castle and the Tower itself (fundamental and higher frequency modes), maps of surface spectral acceleration and soil amplification at different frequencies (3, 5 and 10 Hz) are developed for different input PGA_ROCK levels (0.08, 0.18 and 0.31 g) to evaluate seismic response of the Castle. Observed amplifications are correlated with ground motion polarization and directionality of the ground motion from the alluvial basin to the hilltop. Shortening of predominant frequencies (lengthening of the period), particularly in the alluvial basin, has been observed with higher input PGA_ROCK in the EQL analysis. This effect is not manifested in the Trako??an hill, and predominant frequencies match HVSR frequencies. The use of certain geophysical survey methods at historical sites is a big problem, because terrain features (e.g. steep hills, mountains, ridges, slopes, cliffs) create lack of space and make it impossible to carry out geophysical investigation. Microtremor measurements at historical sites can overcome this limitation and provide local seismic response and vulnerability behaviour of historical monuments without destroying their authenticity. Also, computational modelling can greatly improve the results. The EQL site response analysis on the site of Trako??an Castle has confirmed and improved the results of seismic response and vulnerability based on HVSR method.     

Assessment of land use land cover change impact on hydrological regime of a basin

The sustainability of water resources mainly depends on planning and management of land use; a small change in it may affect water yield largely, as both are linked through relevant hydrological processes, explicitly. However, human activities, especially a significant increase in population, in-migration and accelerated socio-economic activities, are constantly modifying the land use and land cover (LULC) pattern. The impact of such changes in LULC on the hydrological regime of a basin is of widespread concern and a great challenge to the water resource engineers. While studying these impacts, the issue that prevails is the selection of a hydrological model that may be able to accommodate spatial and temporal dynamics of the basin with higher accuracy. Therefore, in the present study, the capabilities of variable infiltration capacity hydrological model to hydrologically simulate the basin under varying LULC scenarios have been investigated. For the present analysis, the Pennar River Basin, Andhra Pradesh, which falls under a water scarce region in India, has been chosen. The water balance components such as runoff potential, evapotranspiration (ET) and baseflow of Pennar Basin have been simulated under different LULC scenarios to study the impact of change on hydrological regime of a basin. Majorly, increase in built-up (13.94% approx.) and decrease in deciduous forest cover (2.44%) are the significant changes observed in the basin during the last three decades. It was found that the impact of LULC change on hydrology is balancing out at basin scale (considering the entire basin, while routing the runoff at the basin outlet). Therefore, an analysis on spatial variation in each of the water balance components considered in the study was done at grid scale. It was observed that the impact of LULC is considerable spatially at grid level, and the maximum increase of 265 mm (1985–2005) and the decrease of 48 mm (1985–1995) in runoff generation at grid were estimated. On the contrary, ET component showed the maximum increase of 400 and decrease of 570 mm under different LULC change scenario. Similarly, in the base flow parameter, an increase of 70 mm and the decrease of 100 mm were observed. It was noticed that the upper basin is showing an increasing trend in almost all hydrological components as compared to the lower basin. Based on this basin scale study, it was concluded that change in the land cover alters the hydrology; however, it needs to be studied at finer spatial scale rather than the entire basin as a whole. The information like the spatial variation in hydrological components may be very useful for local authority and decision-makers to plan mitigation strategies accordingly.