金在黄铁矿表面沉淀机理的实验研究

为了研究金在黄铁矿表面沉淀的机理,于室温、常压,在氯化物溶液中进行了黄铁矿粉末吸附金的实验。在不同pH的溶液中,黄铁矿均可吸附金,而且pH值明显地影响吸附速率。扫描电镜观察表明,反应后黄铁矿粒表面有金晶体形成。XPS研究得知,黄铁矿光片与含金氯化物溶液反应后表面有A⁰存在;硫在反应初期为S⁰、S₂O₃^2-,随后转变为SO₄^2-,而铁成为Fe³⁺.黄铁矿中的Fe²⁺和S₂^2-是溶液中金的还原剂。金在黄铁矿表面沉淀可能涉及吸附、还原和晶体生长等过程。     

ON THE CHANGING AGRICULTURAL STRUCTURE AND ITS GEOGRAPHIC STUDIES

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Optically stimulated luminescence dating of young glacial sediments from the eastern Qinghai-Tibetan Plateau

Poor bleaching is a significant problem for Optically Stimulated Luminescence (OSL) dating of glacial sediments. Five young glacial samples (including two modern analogues) from different depositional settings were collected beyond the Yingpu Glacier in the eastern Qinghai-Tibetan Plateau. De was determined using different OSL methods. The luminescence characteristics and dating results showed that the large aliquot quartz Blue Stimulated Luminescence (BSL) is more applicable than polymineral infrared stimulated luminescence (IRSL) method. Small aliquot quartz BSL results showed poor luminescence properties due to low luminescence sensitivity of quartz in this area. The dating results also indicated that glaciofluvial samples deposited close to ice margin (~40 m and ~700 m) and supraglacial debris dominated lateral moraine samples are relatively well-bleached, whereas samples from ground moraine and low terminal moraine were poorly bleached, probably due to containing subglacial and englacial debris. The residual doses of glaciofluvial and lateral moraine crest samples were below a few Gy and age overestimations were below a few hundred years. The ground moraine and low terminal moraine samples had residual doses as high as ~110 Gy, and ages were overestimated by ~15-17 ka.     

Experimental study of dissolved oxygen transport by regular waves through a perforated breakwater

The perforated breakwater is an environmentally friendly coastal structure,and dissolved oxygen concentration levels are an important index to denote water quality.In this paper,oxygen transport experiments with regular waves through a vertical perforated breakwater were conducted.The oxygen scavenger method was used to reduce the dissolved oxygen concentration of inner water body with the chemicals Na_2SO_3 and Co Cl_2.The dissolved oxygen concentration and wave parameters of 36 experimental scenarios were measured with different perforated arrangements and wave conditions.It was found that the oxygen transfer coefficient through wave surface,K_1a_1,is much lower than the oxygen transport coefficient through the perforated breakwater,K_2a_2.If the effect of K_1a_1 is not considered,the dissolved oxygen concentration computation for inner water body will not be greatly affected.Considering the effect of a permeable area ratio α,relative location parameter of perforations δ and wave period T,the aforementioned data of 30 experimental scenarios,the dimensional analysis and the least squares method were used to derive an equation of K_2a_2(K_2a_2=0.0042α~(0.5)δ~(0.2)T~(-1)).It was validated with 6 other experimental scenarios data,which indicates an approximate agreement.Therefore,this equation can be used to compute the DO concentration caused by the water transport through perforated breakwater.     

喜马拉雅造山带晚中新世麻迦淡色花岗岩的构建机制

在北喜马拉雅萨迦片麻岩穹窿西南侧发育有麻迦淡色花岗岩体,出露于南北向申扎—定结裂谷正断层的下盘,属一处较大规模的晚中新世淡色花岗岩体。该岩体具有较均一的元素和同位素(Sr和Nd)组成,但与多数喜马拉雅淡色花岗岩相比,具有异常高的(~(87)Sr/~(86)Sr)_i比值(0.85033~0.85034)和异常低的_(εNd)(t)值(-19.26~-18.30)组成,指示其部分熔融源区有更成熟古老地壳物质的参与。麻迦淡色花岗岩SHRIMP锆石U-Pb定年结果显示:1该岩体主要记录了至少两阶段岩浆结晶作用,分别发生在11.6±0.2 Ma和9.6±0.2 Ma;2个别13.8~16.0 Ma的岩浆作用年龄;3多数锆石继承核年龄分布于泛非期,少数年龄为中元古代(1558~1584 Ma)。在麻迦淡色花岗岩体南侧约40km处的日玛那穹窿,同位于申扎—定结南北向正断层的下盘,出露有大量原岩年龄为古元古代的日玛那糜棱岩,元素地球化学特征上类似于变泥质岩,显示高SiO_2(70.6%~74.6%),Al_2O_3(12.3%~14.0%),K_2O(4.22%~4.93%),A/CNK(1.50~1.58)和K_2O/Na_2O(1.42~2.18),代表了部分熔融源区可能存在的古老地壳物质岩石单元。因此,以麻迦淡色花岗岩为代表的北喜马拉雅晚中新世地壳深熔作用可能与青藏高原后碰撞阶段东西向伸展作用相关,泛非期变泥质岩及少量日玛那糜棱岩所代表的更古老岩石单元在16.0 Ma开始发生部分熔融,并在11.6 Ma至9.6 Ma之间达到深熔作用峰期,熔体活动可能持续了~2myr,以岩脉汇聚的形式延南北向正断层上升,构成侵位至北喜马拉雅特提斯沉积岩系之中的晚中新世麻迦淡色花岗岩体。     

黔中茶店桥地下河流域不同水体硫酸盐浓度特征及来源识别

茶店桥地下河位于西南岩溶区,流域内"三水"转换迅速,地下水是当地的重要饮用水源。本文对流域内雨水、地表水、地下水中的SO_4~(2-)浓度进行了测试,利用氘(δD_(H_2O))、氧(δ~(18) O_(H_2O))同位素示踪地表水、地下水补给来源,用硫酸盐硫(δ~(34)S_(SO4))、氧(δ~(18) O_(SO4))同位素探讨了地表水、地下水中SO_4~(2-)的来源,并计算了地下河出口河水中不同SO_4~(2-)来源的贡献比例。结果表明:1不同水体中SO_4~(2-)浓度大小顺序为地表水地下水雨水,与邻近区域相比,茶店桥地下河流域雨水、地表水、地下水呈现富集SO_4~(2-)的特征。2地表水、地下水的主要补给来源为大气降水,硫酸不仅和HCO_3~-共同参与了流域内碳酸盐岩的溶解,也参与了雨水中含钙镁颗粒物的溶解。3地表水δ~(34)S_(SO4)、δ~(18) O_(SO4)值分别介于-12.98‰~-10.19‰和-0.54‰~+9.13‰之间,地下水δ~(34)S_(SO4)、δ~(18) O_(SO4)值分别介于-14.32‰~+16.58‰和+2.81‰~+14.35‰之间,SW02的SO_4~(2-)主要来源于大气降水,SW01、SW03、GW02、GW03、GW06主要来源于煤层,GW05主要来源于石膏,GW01、GW04为混合输入源。4地下河出口河水中大气降水带来的SO_4~(2-)贡献比例为13%,煤层硫化物氧化的贡献比例为40%,石膏溶解的贡献比例为47%。     

Extraction and Analysis of Land Cover Heterogeneity over China

Spatial heterogeneity exists in land surface at every scale, and it is one of key factors to bring uncertainty to land parameter retrieval from remote-sensed data. This paper proposed a methodology to use the boundary length among different land cover types to characterize and quantify land surface heterogeneity based on high-resolution land cover images. Then the heterogeneity feature at 1 kilometer scale in China was extracted from “GlobalLand30” land cover datasets with the spatial resolution of 30 m. The mixed structure, degree of fragmentation and intra-heterogeneity of eight main vegetation biomes from MODIS land cover product over heterogeneous surface in china were analyzed. Mountain area and ecotone are more heterogeneous than other regions. Savanna biome (average boundary length is 7 426 meters) is the most heterogeneous zone followed by forest, grass/crop and shrub biome with average boundary length of 4 323, 3 160, 1 779 meters, respectively.     

南海北部冬、夏季海表浮游植物光合作用速率对光强的响应特征

本文通过南海北部冬、夏季航次的现场观测,研究了海表浮游植物光合作用速率对光强的响应特征(P-E曲线)。结果表明南海北部浮游植物P-E曲线存在明显的季节变化。在冬季,P-E曲线呈现高P_mB、高α、高β的特征,这表明冬季浮游植物在低光照环境中光合作用速率增加迅速,其最大光合作用速率较高但容易受到光抑制。与冬季相反,夏季P-E曲线呈现低P_mB、低α、低β的特征,浮游植物受光抑制影响小,但最大光合作用速率低于冬季。水温和粒级结构等指标与P-E参数存在显著相关,这意味着环境和群落的季节变化可能对光合作用特性有一定影响。通过P-E参数模拟得到真光层内光合作用速率,模拟值与现场结果之间呈明显的线性相关但存在高估。此研究有助于认识南海浮游植物光合作用特征,并为初级生产力模型研究提供依据。     

2013年夏季琼东海域营养盐与叶绿素a的周日波动及其影响因素

基于2013年8月琼东海域两个连续站的观测资料,对比分析了近岸站位和陆架站位的营养盐和叶绿素a浓度周日变化特征及其影响因素。结果表明:在垂直分布上,近岸站位S1与陆架站位S2的温跃层减弱了营养盐的向上输运;在时间变化上,S1站底层硅酸盐、硝酸盐和磷酸盐浓度具有半日波动的特点,而S2站的营养盐则不具有周日波动的现象,这说明近岸站位的营养盐受到潮汐作用的影响更显著。S1站的叶绿素a分层不明显,夜间的低值可能体现浮游动物的摄食作用,S2站位的叶绿素a分层明显,夜间没体现浮游动物的摄食作用。总体上,琼东海域近岸站位S1和陆架区站位S2叶绿素a和营养盐周日波动都受到温跃层、潮汐、生物作用和光照的影响,但S1站受潮汐作用影响更显著,且S1站叶绿素a浓度还受到浮游动物摄食作用影响。由于叶绿素a和营养盐受到多种环境要素的影响,使得两者相关性不显著。