Measuring and Simulating Co(II) Sorption on Waste Calcite,Zeolite and Kaolinite

Sorption of cobalt (CoII) ions from aqueous solution by waste calcite, kaolinite and zeolite was investigated in a series of batch experiments. The sorption capacity of the sorbents was a function of the initial solution pH, contact time and sorbent/sorbate ratio. For these three sorbents, the kinetic and isotherm experimental data were well fitted to pseudo-second-order and Langmuir equations, respectively. The maximum sorption capacity (mg g^?1) of Co(II) was 4.67, 3.76 and 2.23 for waste calcite, zeolite and kaolinite, respectively. Desorption experiments showed that the desorption capacities were in the order of zeolite?>?kaolinite?>?waste calcite. The equilibrium and kinetic results indicated that waste calcite had the best performance for the removal of Co(II) compared to zeolite and kaolinite. To simulate and predict Co(II) sorption mechanisms, the surface complexation and cation exchange models in PHREEQC program were used. The model results suggested that the main mechanisms of Co(II) sorption on waste calcite and zeolite were surface complexation and cation exchange, respectively. In the case of kaolinite, the model predicted that both mechanisms were involved in the sorption of Co(II), but the surface complexation was the predominant mechanism.

     

The magmatic record in the Arghash region (northeast Iran) and tectonic implications

The area of Arghash in northeast Iran, prominent for its gold mineralization, was newly mapped on a scale of 1:20,000 with particular attention to the occurring generations of igneous rocks. In addition, geochronological and geochemical investigations were carried out. The oldest geological unit is a late Precambrian, hornblende-bearing diorite pluton with low-K composition and primitive isotope signatures. This diorite (U–Pb zircon age 554 ± 6 Ma) is most likely a remnant from a Peri-Gondwana island-arc or back-arc basin. About one-third of the map area is interpreted as an Upper Cretaceous magmatic arc consisting of a volcanic and a plutonic part. The plutonic part is represented by a suite of hornblende-bearing medium-K, I-type granitoids (minor diorite, mainly quartz–monzodiorite and granodiorite) dated at 92.8 ± 1.3 Ma (U–Pb zircon age). The volcanic part comprises medium-K andesite, dacite and tuffitic rocks and must be at least slightly older, because it is locally affected by contact metamorphism through the hornblende–granitoids. The Upper Cretaceous arc magmatism in the Arghash Massif is probably related to the northward subduction of the Sabzevar oceanic basin, which holds a back-arc position behind the main Neotethys subduction front. Small occurrences of pillow basalts and sediments (sandstone, conglomerate, limestone) tectonically intercalated in the older volcanic series may be relics of earlier Cretaceous or even pre-Cretaceous rocks. In the early Cenozoic, the Cretaceous magmatic arc was intruded by bodies of felsic, weakly peraluminous granite (U–Pb zircon age 55.4 ± 2.3 Ma). Another strong pulse of magmatism followed slightly later in the Eocene, producing large masses of andesitic to dacitic volcanic rocks. The geochemistry of this prominent Eocene volcanism is very distinct, with a high-K signature and trace element contents similar to shoshonitic series (high P, Zr, Cr, Sr and Ba). High Sr/Y ratios feature affinities to adakite magmas. The Eocene magmatism in the Arghash Massif is interpreted as related to thermal anomalies in crust and mantle that developed when the Sabzevar subduction system collapsed. The youngest magmatic activities in the Arghash Massif are lamprophyres and small intrusions of quartz–monzodiorite porphyries, which cut through all other rocks including an Oligocene–Miocene conglomerate cover series.     

Optimization of Bottom Friction Coefficient Using Inverse Modeling in the Persian Gulf

Ocean Science Journal - A practical method for the calibration of the ocean circulation model is introduced using measured water levels along the Persian Gulf coastlines. Dimensional analysis is...     

Statistical Optimization of Anaerobic Biological Processes for Dye Treatment

In the present study both the synthetic media composition as well as some process parameters in the anaerobic decolorization of Reactive Black 5 (RB5) by activated sludge were studied and optimized using statistical design of experiments (DOEs). Statistical analysis of the results of Plackett–Burman DOE showed that the addition of Mn or Fe, or increase in concentration of Mg, had a positive effect on the anaerobic decolorization efficiency whereas the effect of increase in concentration of glucose, ammonium chloride, and calcium chloride was negative. The effect of change in the concentration of glucose, mixed liquor suspended solid (MLSS), and RB5 on the anaerobic decolorization efficiency and rate and chemical oxygen demand (COD) removal was studied using central composite design methodology. Statistical analysis of the data showed that all the factors had significant effect on both the dye decolorization efficiency and rate. The interaction of glucose with MLSS and with dye and the interaction of MLSS with glucose and with dye were significant when the response was decolorization efficiency and rate, respectively. When COD removal was the response, the effect of change in glucose and MLSS concentration and the interaction between these two factors had statistically significant effect on the response.     

Simulating winter wheat production potential under near-future climate change in arid regions of northeast Iran

Theoretical and Applied Climatology - Water scarcity is the key challenge in arid regions, which exacerbates under climate change (CC) and must be considered to assess the impacts of CC on cropping...     

Experimental comparison of some techniques for estimating natural raindrop size distribution on the south coast of the Caspian Sea,Iran

Abstract

Knowledge of the relationship between rainfall intensity and kinetic energy and its variations in time and space is important for the prediction of erosion hazard. Kinetic energy and erosivity are also strongly controlled by raindrop size. However, studies on raindrop measurement and different practical techniques have been rarely documented. The current study therefore aimed to apply existing raindrop-size measurement techniques—the photographic, flour-pellet and stain methods, as well as an innovative flour-stain method—and to evaluate their applicability at several intensities in Mazandaran Province, Iran. The distribution of raindrop size obtained by the different methods was recorded and compared with those obtained through applying a high-speed imaging technique. All the analyses were made with the help of a SPSS software package. The results showed that the raindrop diameters ranged from 0.2 to 5.16 mm at different rainfall intensities. Statistical comparison of the methods using the Duncan test showed that the flour-pellet method presented similar results to the photographic technique; it was concluded that this can be used as a practical and inexpensive method to estimate a wide range of raindrop sizes.

Editor Z.W. Kundzewicz

Citation Sadeghi, S.H., Abdollahi, Z., and Khaledi Darvishan, A., 2013. Experimental comparison of some techniques for estimating natural raindrop size distribution on the south coast of the Caspian Sea, Iran. Hydrological Sciences Journal, 58 (6), 1374–1382.     

Petrogenesis of Rabor-Lalehzar magmatic rocks (SE Iran): Constraints from whole rock chemistry and Sr-Nd isotopes

The Urumieh-Dokhtar magmatic arc (UDMA) of Central Iran has been formed during Neotethyan Ocean subduction underneath Eurasia. The Rabor-Lalehzar magmatic complex (RLMC), covers an area ～1000?km² in the Kerman magmatic belt (KMB), SE of UDMA. RLMC magmatic rocks include both granitoids and volcanic rocks with calc-alkaline and adakitic signatures but with different ages.Miocene adakitic rocks are characterd by relatively enrichmented in incompatible elements, high (Sr/Y)_(N) (>40), and (La/Yb)_(N) (>10) ratios with slightly negative Eu anomalies (Eu_N/Eu*≈ 0.9), depletion in HFSEs, and relatively non-radiogenic Sr isotope signatures (⁸⁷Sr/⁸⁶Sr?=?0.7048–0.7049). In contrast, the Oligocene granitoids exhibit low Sr/Y (<20) and La/Yb (<9) ratios, negative Eu anomalies (Eu_N/Eu*?≈?0.5), and enrichment in HFSEs and radiogenic Sr isotope signatures (⁸⁷Sr/⁸⁶Sr?=?0.7050–0.7052), showing affinity to the island arc rocks. Eocene volcanic rocks which crusscut the younger granitoid rocks comprise andesites and dacites. Geochemically, lavas show calc-alkaline character without any Eu anomaly (Eu_N/Eu*?≈?1.0). Based on the geochemical and isotopic data we propose that melt source for both calc-alkaline and adakitic rocks from the RLMC can be related to the melting of a sub-continental lithospheric mantle (SCLM). Basaltic melts derived from a metasomatized mantle wedge might be emplaced at the mantle-crust boundary and formed the juvenile mafic lower crust. However, some melts fractionated in the shallow magma chambers and continued to rise forming the volcanic intermediate-mafic rocks at the surface. On the other hand, the assimilation and fractional crystallization in the shallow magma chambers of may have been responsible for the development of Oligocene granitoids with calc-alkaline affinity. In the mid-Late Miocene, following the collision between Afro-Arabia and Iranian block the juvenile mafic crust of UDMA underwent thickening and metamorphosed into garnet-amphibolites. Subsequent upwelling of a hot asthenosphere during Miocene was responsible for partial melting of thickened juvenile crust of the SE UDMA (RLM complex). The adakitic melts ascended to the shallow crust to form the adakitic rocks in the KMB.     

Alteration Mapping for Porphyry Copper Exploration Using ASTER and QuickBird Multispectral Images,Sonajeel Prospect,NW Iran

The Sonajeel prospect is located in the Arasbaran belt which is one of the significant copper mineralization belts in NW Iran. There are mostly Eocene volcano-sedimentary rocks and Post Eocene intrusive units which are the source for mineralization in the area. ASTER multispectral images were used for delineation of alteration zones as a key feature of porphyry copper mineralization. Due to the need for geometric correction and ortho-rectification of the ASTER images, a high resolution QuickBird image with pixel width of about 60 cm (in PAN) was employed as a reference image in order to boost the rectification process. Ortho-rectification has been done by using digital elevation model which is created by topographic map in scale 1:1000. Potassic alteration as one of the essential alteration types in porphyry copper deposits, distributed mostly in the north of the Sonajeel prospect that determined by Thermal infrared bands processing. Phyllic and argillic alteration zones detected by creating relative absorption band-depth grids which are comparable to field observations. Moreover, silica rich areas which are remnants of hydrothermal circulation and form at the top of porphyry copper systems were detected for recognition of epithermal deposits (with 1 km distance from Sonajeel porphyry system). Finally, Remote Sensing results were compared by field evidences especially for determination of an epithermal system. Most parts of the alteration zones were observed of the surface confirmed with the remote sensing alteration (in average about 75% matched fittingly), displayed concentrations anomalous in the NE and NW parts of the studied area.     

A spatiotemporal Bayesian maximum entropy-based methodology for dealing with sparse data in revising groundwater quality monitoring networks: the Tehran region experience

Data inadequacy is a common problem in designing or updating groundwater monitoring systems. The developed methodologies for the optimal design of groundwater monitoring systems usually assume that there is a complete set of data obtained from existing monitoring wells and provide a revised configuration for the system by analyzing the current data. These methodologies are not usually applicable when the current groundwater quantity and quality data are highly sparse. In this paper, a new simulation–optimization approach based on Bayesian maximum entropy theory (BME) is proposed for revising spatial and temporal monitoring frequencies in a sparsely monitored aquifer. The BME is used to simulate the spatial and spatiotemporal variations of groundwater indicators, incorporating the space/time uncertainties due to insufficient data. Comparing the obtained estimations with observations, the best BME model was selected to be linked with an optimization model. The main goal of optimization was to find out the spatial and temporal sampling characteristics of the monitoring stations using the concepts of Entropy theory and a groundwater vulnerability index. The results show the BME estimations are less biased and more accurate than Ordinary Kriging in both spatial and spatiotemporal analysis. The improvements in the BME estimates are mostly related to incorporating hard (accurate) and soft (uncertain) data in the estimation process. The applicability and efficiency of the proposed methodology have been evaluated by applying it to the Tehran aquifer in Iran which is suffering from high groundwater table fluctuations and nitrate pollution. Based on the results, in addition to the existing monitoring wells, seven new monitoring stations have been proposed. Few stations which potentially can be removed or combined with other stations have been identified and a monthly sampling frequency has been suggested.     

Geochemistry of garnet in pegmatites from the Boroujerd Intrusive Complex,Sanandaj-Sirjan Zone,western Iran: implications for the origin of pegmatite melts

Mineralogy and Petrology - Pegmatite-hosted garnets from four localities in the Boroujerd region, Lorestan (Western Iran), have been analysed for major and selected trace element compositions. The...