Molecular Structure of Kerogen in the Longmaxi Shale: Insights from Solid State NMR,FT‐IR,XRD and HRTEM

Kerogen plays an important role in shale gas adsorption, desorption and diffusion. Therefore, it is necessary to characterize the molecular structure of kerogen. In this study, four kerogen samples were isolated from the organic-rich shale of the Longmaxi Formation. Raman spectroscopy was used to determine the maturity of these kerogen samples. High-resolution transmission electron microscopy (HRTEM), 13C nuclear magnetic resonance (13C NMR) , X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy were conducted to characterize the molecular structure of the shale samples. The results demonstrate that VReqv of these kerogen samples vary from 2.3% to 2.8%, suggesting that all the kerogen samples are in the dry gas window. The macromolecular carbon skeleton of the Longmaxi Formation kerogen is mainly aromatic (fa’=0.56). In addition, the aromatic structural units are mainly composed of naphthalene (23%), anthracene (23%) and phenanthrene (29%). However, the aliphatic structure of the kerogen macromolecules is relatively low (fal*+falH=0.08), which is presumed to be distributed in the form of methyl and short aliphatic chains at the edge of the aromatic units. The oxygen-containing functional groups in the macromolecules are mainly present in the form of carbonyl groups (fac=0.23) and hydroxyl groups or ether groups (falO=0.13). The crystallite structural parameters of kerogen, including the stacking height (Lc=22.84 ?), average lateral size (La=29.29 ?) and interlayer spacing (d002=3.43 ?), are close to the aromatic structural parameters of anthracite or overmature kerogen. High-resolution transmission electron microscopy reveals that the aromatic structure is well oriented, and more than 65% of the diffractive aromatic layers are concentrated in the main direction. Due to the continuous deep burial, the longer aliphatic chains and oxygen-containing functional groups in the kerogen are substantially depleted. However, the ductility and stacking degree of the aromatic structure increases during thermal evolution. This study provides quantitative information on the molecular structure of kerogen samples based on multiple research methods, which may contribute to an improved understanding of the organic pores in black shale.     

云南保山核桃坪铅-锌矿床地质特征

保山核桃坪铅-锌矿为一中型铅-锌矿床。矿体赋存于上寒武统核桃坪组,主要受近SN向的层间断裂(F1)及次级断裂构造控制,岩石(性)控矿也十分明显,成矿作用与矽卡岩化密切相关。通过对该矿床地质特征的系统分析以及对矿床围岩蚀变、控矿因素的深入研究,认为该矿床主要矿化作用是深部高温成矿流体贯入并与围岩发生矽卡岩化蚀变,随后发生矿化作用。矿床应属矽卡岩型铅-锌矿床。     

Tooth Plates of Ceratodus (Dipnoi, Ceratodontidae) from the Upper Jurassic Shaximiao Formation of Guang’an, Sichuan Province, China

Ceratodus is a form genus of ceratodontid lungfishes. Until now, only 14 specimens have been reported from the Mesozoic of China. Detailed measurements and characteristic comparisons based on 15 well-preserved lungfish tooth plates of Ceratodus type, uncovered from the upper member of the Upper Jurassic Shaximiao Formation at Luojiashan, Qianfeng District, Guang''an, Sichuan Province in 2019, allow us to establish a new species, Ceratodus guanganensis sp. nov., on the basis of its small swollen irregular triangular tooth plate with four low and swollen radial crests on the occlusal surface without denticles. Other specimens from the same locality can be referred to C. szechuanensis and C. youngi. This is the first discovery of Ceratodus in the Guang''an region and represents the fifth Ceratodus fossil site in the Sichuan Basin. The discovery indicates that the climate was hot and arid in the Sichuan Basin during the Late Jurassic, and reveals a tectonic paleogeographic relationship between the Yangtze block in southwestern China and the Kola Basin in northern Thailand.     

计算横向非均匀介质体波理论地震图的Maslov渐近法

本文运用Maslov渐近理论编写的二维横向非均匀介质中的理论地震图程序,与其它类型算法作了精确对比,结果表明,在层状介质模型中,本程序的结果无论振幅还是波形对比都与反射率法基本相同。对于二维横向非均匀模型,在射线理论的非奇点处,本算法与射线方法基本一致,在射线理论的奇异点处,Maslov方法消除了射线理论所固有奇点,提高了计算精度。     

甘肃地层研究现状、存在问题及今后方向

地层学是地质学重要的基础性学科,是地质工作的基础和支撑。近年来甘肃省地层古生物研究取得重大进展,积累了一批为全省地层研究修史立典的材料,及时总结这些成果素材,按照最新的理论、方法对区域地层进行划分、对比和精准化研究,是一个省区基础地质工作的重要内容。本文通过系统总结和梳理近年来甘肃地层学研究的最新成果,按照时间顺序和学科特点,系统性提出了按照多重地层划分对比理论和《中国地层指南及中国地层指南说明书》（2016年版）和《中国地层表》（2014）的框架和序列,全面提高甘肃地层研究精准度,为全省地质调查和相关研究提供基础支撑;对全省不同地区和不同地质单元地层界线层型和单位层型进行对比研究和厘定,建立新一代甘肃地层表的建议和路径。     

矿集区大地电磁噪声场源分析及噪声特点

结合长江中下游某矿集区大地电磁观测环境,分析大型矿山、通讯基站及其他主要电磁噪声源对视电阻率曲线的影响.依据时域波形将噪声分为脉冲噪声、周期噪声、三角波噪声、方波噪声、阶跃噪声、似充放电模式的三角噪声,便于在后期资料处理过程中针对不同的噪声类型对大地电磁数据进行降噪处理.     

巴布亚新几内亚波格拉斑岩型铜-金矿床富Nb碱性火成岩成因新解

巴布亚新几内亚波格拉(Porgera)斑岩铜-金矿床的侵入杂岩岩石类型为碱性玄武岩→夏威夷岩(粗面玄武岩)→橄榄粗安岩套.微量元素总体特征是富集大离子亲石元素(LILE)(Sr、Ba)和高场强元素(HFSE)(Zr、Nb、Th) .在微量元素蛛网图上显示宽的Th、Nb、U峰和Ti、Hf、Y的谷.该矿床夏威夷岩和橄榄粗安岩是一套板内富Nb碱性玄武岩系列,属于大陆OIB碱性侵入岩,而不是洋岛OIB系列,与地幔柱活动相关.波格拉侵入杂岩形成于弧-陆碰撞环境,为新生代主动大陆边缘板内碱性玄武岩的典型代表之一.     

基于多卫星遥感产品的极端降水监测研究

以中国气象局提供的地面观测站点逐小时降水数据为基准数据,综合评估了目前国际上主流的高分辨率多卫星遥感降水在2015年强台风灿鸿所带来的极端降水事件中的表现。结果表明:1所有的卫星遥感降水产品在此次极端降水事件中对实际降水都存在着低估,其中IMERG系列下经过校正的Final产品IMERG-Final-Calibrated表现得最好;2IMERG-Late-Calibrated在实时产品中表现最好,一定程度上可以满足极端降水事件监测对实时性的要求;3总的来说,在此次极端降水事件中,不管是滞时类产品还是实时类产品,IMERG系列卫星降水的表现均要好于TMPA系列下卫星降水的表现。     

刚-柔性桩复合地基中桩荷载传递规律试验研究

为了解刚-柔性桩复合地基中刚性桩和柔性桩的荷载传递规律,在温州地区选择了2幢采用刚-柔性桩复合地基的建筑物进行原位试验。试验前在钻孔灌注桩桩身埋设了钢筋应力计,在水泥搅拌桩桩身埋设了振弦式应变计,在建筑物施工过程中同步检测传感器的变化情况。试验结果表明,不同部位及不同类型桩荷载传递规律不同,中部刚性桩摩阻力相对于边部刚性桩重心下降,刚性桩荷载传递长度大于柔性桩。无褥垫层刚-柔性桩复合地基中部刚性桩在层数低时会出现负摩阻力,有褥垫层刚-柔性桩复合地基中在施工期间始终存在负摩阻力。中部桩端承力要高于边部桩端承力。     

近12000年以来北京地区地球磁场变化机理探讨

距今12000年以来北京地区地球磁场长期变化由长周期(大于1000年)和短周期(约500年)两部分组成，长周期和短周期分量分别受控于漂移场和稳定场的变化.与日本地区相比，北京地区地球磁场最显著的特征是在距今(5110-4670)±110年之间曾发生短极性漂移事件，这样的短极性地磁事件可能与地球外核流体运动的异常变化有关.