中心外缺陷对带隙型光子晶体光纤色散特性的影响

利用时域有限差分法(FDTD)模拟仿真了在中心缺陷外出现点缺陷、空气柱位错和内层空气柱发生形变三种缺陷形态对光子带隙型光子晶体光纤(PBG-PCF)色散特性的影响.发现一方面缺陷的出现会使色散曲线趋于平坦,另一方面点缺陷和位错缺陷的出现会使零色散点向长波移动,内层空气柱的形变使零色散点向短波长移动.这对PBG-PCF的实际生产实践会有指导意义.     

Effect of slow-solvent-vapour treatment on performance of polymer photovoltaic devices

In this work, enhanced poly(3-hexylthiophene):[6,6]-phenyl-C61-butyric acid methyl ester (P3HT:PCBM) bulk-heterojunction photovoltaic devices are achieved via slow-solvent-vapour treatment. The correlations between the morphology of the active layer and the photovoltaic performance of polymer-based solar cell are investigated. The active layers are characterized by atomic force microscopy and optical absorption. The results show that slow-solvent-vapour treatment can induce P3HT self-organization into an ordered structure, leading to the enhanced absorption and efficient charge transport.     

Improvement of photorefractive properties in Hf:Fe:LiNbO3 crystals with various [Li]/[Nb] ratios

Photorefractive properties of Hf:Fe:LiNbO₃ crystals with various [Li]/[Nb] ratios have been investigated at 488 nm wavelength based on the two-wave coupling experiment. High diffraction efficiency and large recording sensitivity are observed and explained. The decrease in Li vacancies is suggested to be the main contributor to the increase in the photoconductivity and subsequently to the induction of the improvement of recording sensitivity. The saturation diffraction efficiency is measured up to 80.2%, and simultaneously the recording sensitivity of 0.91 cm/J is achieved to in the Hf:Fe:LiNbO₃ crystal grown from the melt with the [Li]/[Nb] ratio of 1.20, which is significantly enhanced as compared with those of the Hf:Fe:LiNbO₃ crystal with the [Li]/[Nb] ratio of 0.94 in melt under the same experimental conditions. Experimental results definitely show that increasing the [Li]/[Nb] ratio in crystal is an effective method for Hf:Fe:LiNbO₃ crystal to improve its photorefractive properties.     

Accurate ab initio study of low-lying electronic states of phosphorus nitride radical

This paper employs the highly accurate valence internally contracted multireference configuration interaction method to investigate the potential energy curves (PECs) for the ground state (X¹Σ⁺) and two low-lying excited states (A¹Π and D¹Δ of phosphorus nitride (PN) radical with the correlation-consistent basis set, aug-cc-pV6Z, in the valence range. Relativistic effects are considered in these calculations. The spectroscopic constants of the X¹Σ⁺ and A¹Π states are calculated based on the PECs, and the results are in good accord with the available experimental data. The first 30 vibrational states for the A¹Π state and the first 40 vibrational states for the A¹Π state are determined when J=0. For each vibrational state, molecular constants G(υ), B(υ) and D(υ) are also attained.     

3D Step-by-step inversion strategy for audio magnetotellurics data based on unstructured mesh

A three-dimensional (3D) step-by-step inversion strategy for audio magnetotellurics(AMT) is investigated in this study.The objective function is minimized by it...     

中国城际公路零担专线网络空间结构特征

基于社会网络分析方法,利用国家交通运输物流公共信息平台2018年全国地级及以上城市的公路零担专线数据,从城市节点、城际联系、子网络3个层面对中国城市网络结构特征进行识别,结果表明：1）上海、天津、郑州、广州、杭州在网络中处于主导性地位,根据货流组织系数,可将城市节点划分为强中心、次强中心、弱中心、从属型4种类型。2）在首位联系总量排名前十的城市中,输出型城市和输入型城市的比例为4∶1,反映货流流向的不均衡性。由公路零担专线数据刻画的网络空间呈现显著的距离衰减规律,集中在500 km的专线数量占比为41.9%。3）公路零担专线网络形成东北―冀鲁蒙社区、中原社区、关中社区、江淮社区、泛珠三角―长三角社区、长株潭社区6个具有显著地域特征的城市社区,社区结构表现出明显的空间集聚和跨行政区特征。最后,提出以下建议：增强成渝城市群公路零担专线服务能力,发挥核心城市产业集聚和带动作用;优化边缘城市产业结构,加强交通与产业融合;积极引导无车承运人平台发挥网络规模化效应,提高公路货运组织效率。     

库车坳陷克拉2气田异常流体压力演化史

根据克拉2气田现今实测地层压力分析了异常高压发育的特征,并通过流体包裹体测试求取包裹体形成时期的古压力。计算结果表明:下白垩统和古近系库姆格列木群砂岩储层在距今8～6Ma(康村组沉积期末)时,古压力系数大致为1.09～1.18,发育过剩压力为4.6～9.6MPa的异常高压。在此基础上,以古、今压力数据为约束条件,利用数值模拟技术定量恢复出下白垩统与侏罗系异常流体压力的演化历史。研究发现:下白垩统储层流体压力经历了沉积型异常流体压力形成发展(白垩纪-库车组沉积期末)和沉积型异常流体压力萎缩—构造挤压型异常流体压力孕育(库车组沉积期末至今)两个阶段。康村组沉积早期沉积型超压开始出现,库车组沉积期末达到顶峰,过剩压力达40～50MPa;此后,在沉积型超压萎缩—构造挤压型超压孕育过程的耦合下,过剩压力曾降至25～30MPa,更新世起超压略有升高。侏罗系流体压力演化较为简单,吉迪克组沉积期开始出现超压,至库车组沉积期末达到高峰,此后异常高压逐渐萎缩。在克拉2气田的主要成藏时期(距今3～1Ma),烃源岩较储层具有更高的异常压力,源—储压力差为10～30MPa。     

Spatial variation and driving mechanism of soil organic carbon components in the alluvial/sedimentary zone of the Yellow River

Alluviation and sedimentation of the Yellow River are important factors influencing the surface soil structure and organic carbon content in its lower reaches. Selecting Kaifeng and Zhoukou as typical cases of the Yellow River flooding area, the field survey, soil sample collection, laboratory experiment and Geographic Information System(GIS) spatial analysis methods were applied to study the spatial distribution characteristics and change mechanism of organic carbon components at different soil depths. The results revealed that the soil total organic carbon(TOC), active organic carbon(AOC) and nonactive organic carbon(NOC) contents ranged from 0.05–30.03 g/kg, 0.01–8.86 g/kg and 0.02–23.36 g/kg, respectively. The TOC, AOC and NOC contents in the surface soil layer were obviously higher than those in the lower soil layer, and the sequence of the content and change range within a single layer was TOCNOCAOC. Geostatistical analysis indicated that the TOC, AOC and NOC contents were commonly influenced by structural and random factors, and the influence magnitudes of these two factors were similar. The overall spatial trends of TOC, AOC and NOC remained relatively consistent from the 0–20 cm layer to the 20–100 cm layer, and the transition between high-and low-value areas was obvious, while the spatial variance was high. The AOC and NOC contents and spatial distribution better reflected TOC spatial variation and carbon accumulation areas. The distribution and depth of the sediment, agricultural land-use type, cropping system, fertilization method, tillage process and cultivation history were the main factors impacting the spatial variation in the soil organic carbon(SOC) components. Therefore, increasing the organic matter content, straw return, applying organic manure, adding exogenous particulate matter and conservation tillage are effective measures to improve the soil quality and attain sustainable agricultural development in the alluvial/sedimentary zone of the Yellow River.     

武山地震台观测热水成因的研究

武山地震台为国家级基准台,但由于各种原因反应地震的效果不明显,因此需要从多方面研究,采取改进措施,提高其预报效能。     

对铀矿水文地球化学找矿工作中某些问题的探讨

本文在总结铀矿水分散体规模的基础上,对铀矿水文地球化学代矿工作的网度要求进行了讨论,提出区调阶段的工作比例尺为1:20万—1:10万,普查阶段为1:5万—1:2.5万,详查阶段为1:1万—1:5000;在阐明各工作阶段所圈定的水文地球化学场的地质含义的基础上,讨论了中、小比例尺水文地球化学调查工作的原理、效果及技术要求。提出了在潮湿多雨地区开展水分散流找矿的合理性和优越性。指出了水分散流找矿的关键是分析方法的灵敏度和精度。在水文地球化学调查中要注意通用找矿标志和矿化度(电导)的取样分析工作。