Retrieval and tentative indentification of the 3 μm spectral feature in Titan's haze

Recently, an unidentified 3.3-3.4 μm feature found in the solar occultation spectra of the atmosphere of Titan observed by Cassini/VIMS was tentatively attributed to the C-H stretching mode of aliphatic hydrocarbon chains attached to large organic molecules, but without properly extracting the feature from adjacent influences of strong CH₄ and weak C₂H₆ absorptions (Bellucci et al., 2009). In this work, we retrieve the detailed spectral feature using a radiative transfer program including absorption and fluorescent emission of both molecules, as well as absorption and scattering by haze particles. The spectral features of the haze retrieved from the VIMS data at various altitudes are similar to each other, indicating relatively uniform spectral properties of the haze with altitude. However, slight deviations observed near 127 km and above 300 km suggest inhomogeneity at these altitudes. We find that the positions of the major spectral peaks occur at 3.33-3.37 μm, which are somewhat different from the typical 3.3 μm aromatic or 3.4 μm aliphatic C-H stretches usually seen in the spectra of dust particles of the interstellar medium and comets. The peaks, however, coincide with those of the solid state spectra of C₂H₆, CH₄, and CH₃CN; and a broad shoulder from 3.37 to 3.50 μm coincides with those of C₅H₁₂ and C₆H₁₂ as well as those of typical aliphatic C-H stretches. This result combined with high-altitude (∼1000 km) haze formation process recently reported by Waite et al. (2007) opens a new question on the chemical composition of the haze particles. We discuss the possibility that the 3 μm feature may be due to the solid state absorption bands of these molecules (or some other molecules) and we advocate additional laboratory measurements for the ices of hydrocarbon and nitrogen-bearing molecules present in Titan's atmosphere for the identification of this 3 μm feature.     

Direct measurements of cosmic-ray energy: The kinematical method revisited

At an energy scale of 10¹⁵-10¹⁶ eV, a direct measurement of the energy carried by charged cosmic radiation is a real challenge for balloon-borne and space based instruments. As a consequence of the very small fluxes, a large collecting power is required which is difficult to accommodate with weight-limited instruments equipped with calorimeters. A different approach has been proposed that might allow for a sizeable reduction of the instrument mass. It is based on a kinematical technique, whereby the energy of the cosmic-ray is estimated on the basis of the measured angular distribution of the secondaries resulting from its interaction in a target. In this paper, we review the basic principles of the method and study the properties of different energy estimators by means of a full simulation of the interaction of the incident particle in a conceptual instrument. We also discuss the intrinsic limitations of the method and investigate its possible application to direct measurements of the cosmic-ray spectrum in the region of the ‘knee’.     

Rainfall frequency analysis using a mixed GEV distribution: a case study for annual maximum rainfalls in South Korea

Extreme rainfalls in South Korea result mainly from convective storms and typhoon storms during the summer. A proper way for dealing with the extreme rainfalls in hydrologic design is to consider the statistical characteristics of the annual maximum rainfall from two different storms when determining design rainfalls. Therefore, this study introduced a mixed generalized extreme value (GEV) distribution to estimate the rainfall quantile for 57 gauge stations across South Korea and compared the rainfall quantiles with those from conventional rainfall frequency analysis using a single GEV distribution. Overall, these results show that the mixed GEV distribution allows probability behavior to be taken into account during rainfall frequency analysis through the process of parameter estimation. The resulting rainfall quantile estimates were found to be significantly smaller than those determined using a single GEV distribution. The difference of rainfall quantiles was found to be closely correlated with the occurrence probability of typhoon and the distribution parameters.     

Integration of air pollution data collected by mobile sensors and ground-based stations to derive a spatiotemporal air pollution profile of a city

ABSTRACT

Air pollution has become a serious environmental problem causing severe consequences in our ecology, climate, health, and urban development. Effective and efficient monitoring and mitigation of air pollution require a comprehensive understanding of the air pollution process through a reliable database carrying important information about the spatiotemporal variations of air pollutant concentrations at various spatial and temporal scales. Traditional analysis suffers from the severe insufficiency of data collected by only a few stations. In this study, we propose a rigorous framework for the integration of air pollutant concentration data coming from the ground-based stations, which are spatially sparse but temporally dense, and mobile sensors, which are spatially dense but temporally sparse. Based on the integrated database which is relatively dense in space and time, we then estimate air pollutant concentrations for given location and time by applying a two-step local regression model to the data. This study advances the frontier of basic research in air pollution monitoring via the integration of station and mobile sensors and sets up the stage for further research on other spatiotemporal problems involving multi-source and multi-scale information.     

Factors Influencing Water Consumption in Multifamily Housing in Tempe,Arizona

Central to the Smart Growth movement is that compact development reduces vehicle miles traveled, carbon emissions, and water use. Empirical efforts to evaluate compact development have examined residential densities but have not distinguished decreasing lot sizes from multifamily apartments as mechanisms for compact development. Efforts to link design features to water use have emphasized single-family at the expense of multifamily housing. This study isolates the determinants of water use in large (more than fifty units) apartment complexes in the city of Tempe, Arizona. In July 2007, per bedroom water use increased with pool area, dishwashers, and in-unit laundry facilities. We are able to explain nearly 50 percent of the variation in water demand with these variables. These results inform public policy for reducing water use in multifamily housing structures, suggesting strategies to construct and market “green” apartment units.     

Seasonal changes in camera-based indices from an open canopy black spruce forest in Alaska,and comparison with indices from a closed canopy evergreen coniferous forest in Japan

Evaluation of the carbon, water, and energy balances in evergreen coniferous forests requires accurate in situ and satellite data regarding their spatio-temporal dynamics. Daily digital camera images can be used to determine the relationships among phenology, gross primary productivity (GPP), and meteorological parameters, and to ground-truth satellite observations. In this study, we examine the relationship between seasonal variations in camera-based canopy surface indices and eddy-covariance-based GPP derived from field studies in an Alaskan open canopy black spruce forest and in a Japanese closed canopy cedar forest. The ratio of the green digital number to the total digital number, hue, and GPP showed a bell-shaped seasonal profile at both sites. Canopy surface images for the black spruce forest and cedar forest mainly detected seasonal changes in vegetation on the floor of the forest and in the tree canopy, respectively. In contrast, the seasonal cycles of the ratios of the red and blue digital numbers to the total digital numbers differed between the two sites, possibly due to differences in forest structure and leaf color. These results suggest that forest structural characteristics, such as canopy openness and seasonal forest-floor changes, should be considered during continuous observations of phenology in evergreen coniferous forests.     

Characteristics of evapotranspiration from a permafrost black spruce forest in interior Alaska

Here, the year 2011 characteristics of evapotranspiration and the energy budget of a black spruce forest underlain by permafrost in interior Alaska were explored. Energy balance was nearly closed during summer, and the mean value of the daily energy balance ratio (the ratio of turbulent energy fluxes to available energy) from June to August was 1.00, though a large energy balance deficit was observed in the spring. Such a deficit was explained partly by the energy consumed by snowmelt. Ground heat flux played an important role in the energy balance, explaining 26.5% of net radiation during summer. The mean daily evapotranspiration of this forest during summer was 1.37 mm day^?1 – considered typical for boreal forests. The annual evapotranspiration and sublimation yielded 207.3 mm year^?1, a value much smaller than the annual precipitation. Sublimation accounted for 8.8% (18.2 mm year^?1) of the annual evapotranspiration and sublimation; thus, the sublimation is not negligible in the annual water balance in boreal forests. The daytime average decoupling coefficient was very small, and the mean value was 0.05 during summer. Thus, evapotranspiration from this forest was mostly explained by the component from the dryness of the air, resulting from the aerodynamically rough surface of this forest.     

A comparison between a Monte Carlo implementation of retrospective optimal interpolation and an ensemble Kalman filter in nonlinear dynamics

To more correctly estimate the error covariance of an evolved state of a nonlinear dynamical system, the second and higher-order moments of the prior error need to be known. Retrospective optimal interpolation (ROI) may require relatively less information on the higher-order moments of the prior errors than an ensemble Kalman filter (EnKF) because it uses the initial conditions as the background states instead of forecasts. Analogous to the extension of a Kalman filter into an EnKF, an ensemble retrospective optimal interpolation (EnROI) technique was derived using the Monte Carlo method from ROI. In contrast to the deterministic version of ROI, the background error covariance is represented by a background ensemble in EnROI. By sequentially applying EnROI to a moving limited analysis window and exploiting the forecast from the average of the background ensemble of EnROI as a guess field, the computation costs for EnROI can be reduced. In the numerical experiment using a Lorenz-96 model and a Model-III of Lorenz with a perfect-model assumption, the cost-effectiveness of the suboptimal version of EnROI is demonstrated to be superior to that of EnKF using perturbed observations.     

Tectonometamorphic evolution of the Permo-Triassic Songrim (Indosinian) orogeny: evidence from the late Paleozoic Pyeongan Supergroup in the northeastern Taebaeksan Basin,South Korea

The deformed and metamorphosed middle Pennsylvanian to Early Triassic (?) rocks of the Pyeongan Supergroup, occurring in northeastern flank of the Paleozoic Taebaeksan Basin, east central South Korea, record the impact of the Late Permian–Triassic Songrim (Indosinian) collisional orogeny in the eastern Eurasia margin. Analysis of meso- and microstructures and their relationship with porphyroblast growth has revealed that these metasedimentary rocks were affected by four deformation events (D₁–D₄). During the polyphase deformations, successive foliations with alternately steep (S₁ and S₃) and flat-lying (S₂ and S₄) orientations were produced with growth of chloritoid, andalusite and kyanite porphyroblasts during D₁ and D₂, and growth of garnet, staurolite and andalusite porphyroblasts during D₃ and D₄. SHRIMP U–Pb detrital zircon ages (330–310 Ma) from metapelites in the oldest unit of the Pyeongan Supergroup in the study area, combined with the previous data on sandstone compositions, indicate magmatic activity that was contemporaneous with the initial deposition of the Pyeongan Supergroup. This also suggests that the Pyeongan Supergroup was deposited in an arc-related foreland basin at an active continental margin during the Late Carboniferous and Permian time. Two contractional deformation events (D₁ and D₃) and two events related to gravitational flattening (D₂ and D₄), along with Barrovian-type medium-pressure regional metamorphism, may have resulted from the Late Permian–Triassic Songrim orogeny, related to collision between the North and South China blocks and/or collision between the Eastern Eurasia margin and the proto-Japan terrane.