Study on the isotherms of the interaction between suspended particles and Cu (II) in the Huanghe River

The isotherms of the interaction between the suspended particles and Cu²⁺, and the effects of lysine and asparaginic acid on the isotherms in the Huanghe (Yellow) River were studied by applying the theory and method of interfacial stepwise ion/coordination particle exchange. We obtained a new stepped river isotherm, formed by two curves joined together with a “plateau” in the middle. The adsorption equilibrium constantsK ₁ andK ₂ were calculated by using the isothermal equation of surface stepwise ion exchange. Amino acid in small amount promotes exchange adsorption of the suspended particles with Cu²⁺. The degree of promotive action relates to the isoelectric point of amino acid. The promotive effect of lysine is bigger than that of asparaginic acid. Project 29361001 supported by NSFC.     

Total lipid and fatty acid composition of eight strains of marine diatoms

Fatty acid composition and total lipid content of 8 strains of marine diatoms (Nitzschia frustrula, Nitzschia closterium, Nitzschia incerta, Navicula pelliculosa, Phaeodactylum tricornutum, Synedra fragilaroides) were examined. The microalgae were grown under defined conditions and harvested at the late exponential phase. The major fatty acids in most strains were 14∶0 (1.0%–6.3%), 16∶0 (13.5–26.4%), 16∶1n−7 (21.1%–46.3%) and 20∶5n−3 (6.5%–19.5%). The polyunsaturated fatty acids 16∶2n−4, 16∶3n−4, 16∶4n−1 and 20∶4n−6 also comprised a significant proportion of the total fatty acids in some strains. The characteristic fatty acid composition of diatoms is readily distinguishable from those of other microalgal groups. Significant concentration of the polyunsaturated fatty acid 20∶5n−3 (eicosapentaenoic acid) was present in each strain, with the highest proportion in B222 (19.5%). Project supported by the Hi-Tech “863” Programs of the China Ministry of Science and Technology (863-819-02-01).     

库岸边坡倾角及水位变化对红土型库岸稳定性影响研究

水库库岸失稳对水库安全运行有重大影响。采用土工试验和干湿循环试验,结合数值计算及理论分析,研究红土型库岸边坡倾角和库水位升降与库岸稳定性的关系。结果表明:(1)在一定初始干密度条件下,红土抗剪强度随水位升降循环次数增加而非线性减小,且在水位升降循环约10次时趋于稳定。(2)在一定水位升降速率、升降幅度和升降循环次数条件下,红土型库岸稳定安全系数随库岸边坡倾角的增加总体上呈减小的趋势,且在边坡倾角为50°左右存在稳定安全系数极小值。(3)在一定水位升降循环次数条件下,水位上升到坡高的60%左右为上升阶段的相对危险区域,且水位上升速率对库岸稳定安全系数影响很小;水位下降至坡高的70%左右为库水位下降阶段的相对危险区域,且水位下降速率越大,库岸稳定安全系数越小。(4)针对一定初始干密度,库岸稳定安全系数先随水位升降循环次数的增加而减小,但在水位升降循环次数约10次后逐渐趋于稳定。库岸岩土体性质及库岸边坡倾角、水位变化都会对库岸稳定产生影响。     

Solubilities,Densities,Refractive Indices of Aqueous Ternary Systems PEG400-NaCl/KCl-H2O at 298 K

Phase equilibria for the NaCl/KCl-PEG400-H_2 O aqueous ternary systems at 298 K were studied using an isothermal dissolution method. In addition,the densities and refractive indices were determined. The corresponding phase diagrams,as well as the density vs. composition and refractive index vs.composition diagrams,were plotted. Results revealed that over the entire PEG400 composition range studied at 298 K only 1 liquid phase was obtained,without the formation of a biphase region. The phase diagrams of these 2 systems consist of 1 homogeneous area with unsaturated liquid( L) and an equilibrium area containing the solid phase of NaCl/KCl and the saturated liquid phase( S + L). The solubility of NaCl/KCl decreases with the addition of PEG400 at 298 K.     

北斗三号组网卫星数据质量分析及单系统定轨精度初步评估

选取2018-01-23起10 d内16个iGMAS测站观测数据,对北斗三号卫星的观测数据质量及BDS单系统精密定轨精度进行评估。初步结果表明,老信号B1I、B3I北斗三号卫星的信噪比略强于二号卫星,噪声与多路径基本相当,均在0.1 m量级,新卫星不存在星内多路径偏差。新信号B1C/L1/E1频点GPS信噪比最强,Galileo和BDS卫星相当,B2a/L5/E5a和B2b/E5b各系统基本相当;噪声及多路径方面,B1C/L1/E1频点GPS优于BDS、Galileo卫星0.1 m量级,B2a/L5/E5a和B2b/E5b各系统基本相当,均在0.1 m量级,新信号中北斗三号卫星星内多路径偏差基本消失。单系统精密定轨试验中,分别进行有/无GEO卫星策略、太阳光压模型ECOM 五/九参数策略的比较,并使用卫星激光测距数据进行独立检核。初步结果表明,有GEO卫星、ECOM五参数光压模型的定轨精度最好,C19号卫星7个重叠弧段的平均定轨精度在沿迹向、法向、径向的精度分别为32 cm、16 cm、8 cm,与试验卫星的定轨精度基本相当。     

Spatial Distribution Assessment and Source Apportionment of Land-Based Pollutant Yield from Qingdao,China

The spatial distribution of chemical oxygen demand(COD) and total nitrogen(TN) yield from Qingdao are studied by comparing pollutant yield amount, densities and spatial aggregation(Getis-Ord indexes) among the land-based pollutant source regions(PSRs) entering the three sub-seas(i.e. the Jiaozhou Bay(JZB), other coastal area in the Yellow Sea(OCAYS) and Laizhou Bay(LZB), respectively). Industrial composition of the loads are also studied by comparing pollutant yield among the sources of agriculture, rural domesticity, industry, urban domesticity and service, and calculation of Gini coefficient. Results show that spatial distribution of COD and TN yield from Qingdao are extremely unbalanced. The JZB, with less than 3% of the total coastal sea area of Qingdao, received 62% COD load and 65% TN yield from Qingdao, while the OCAYS, with more than 97% area, only received 23% COD and 20% TN, which consist with the much worsen water quality of JZB than that of OCAYS. On the other hand, the source apportionment of COD and TN loads in the PSRs entering JZB and the OCAYS was similar. The agricultural and domestic sources with high pollution intensity account for more than 80%, while the industrial and service sources with low pollution intensity account for less than 20%. While Gini coefficients, COD 0.81 and TN 0.84 which are much higher than the ‘imbalance' threshold of 0.4, show the uneven industrial structure of Qingdao. These results may be useful in the determination of land-based pollution total amount control at the PSR level.     

近六百年来长江三角洲地区城镇空间与城镇体系格局演变分析

基于历史文献、古地图和现代遥感数据,引入历史学古代城镇形态复原方法,复原（提取）明代以来长江三角洲地区113座城镇7个时间断面（1461年、1820年、1930年、1970年、1980年、2000年和2010年）下的城镇边界,采用扩张速率、扩张效率、首位度指数和位序-规模法则,分析了近六百年来区域城镇空间与城镇体系等级规模演变格局。取得以下研究结果：\mathrm{①}研究时段内,区内城镇用地总规模由205.98 km²增加到6442.19 km²,扩大了31.27倍;城镇扩张经历了萌芽阶段（明清时期）、起步阶段（民国至改革开放前夕）、成长阶段（改革开放至2000年）和加速阶段（2000—2010年）,城镇扩张速率不断加快,但扩张效率有待提升;\mathrm{②}在城镇等级规模空间格局上,明清时期南京与苏州为区内的一级城镇,民国后,上海逐渐取代其地位,从五级城镇发展成为区域核心城镇,四级以上城镇主要集中在长江干流沿岸和太湖流域,五级以下城镇大多集中在安徽;城镇体系呈首位型分布,城镇首位度较高,且改革开放后的城镇首位度较明清与民国时期要高,不同等级规模城镇之间差距扩大,大城镇优势较强。近30年,长江沿岸城镇发展加速,苏锡常都市圈、南京都市圈等逐渐形成并快速发展。     

新时代的国土空间规划体系重建与制度环境改革

在全面推进生态文明建设背景下,急需建立适合中国国情的国土空间开发保护制度和国土空间规划体系,这是新时期建立空间治理体系的重要任务。在国务院新一轮的机构改革背景下,空间类规划的编制职能向自然资源部集中,急需探索和建立全国国土空间规划体系的总体框架和制度环境改革的推进路径。研究表明：国家国土空间规划体系的重建取决于三个方面,一是依赖于部门的职能整合,二是国土空间规划体系的整合与重构,三是依赖于制度环境改革。因此,在机构改革逐步完成的形势下,需要从国土空间规划体系重建与制度环境改革两个路径着手,从国家、省域、市县等层面阐述了中国国土空间规划体系的重建思路,构建五级四类、上下衔接、分级管理的国土空间规划体系。从确定国土空间开发保护制度、专业人才培养、规划资质管理、推进立法等几个方面推进制度环境改革。最后从推进国土空间规划立法、审批程序前置和推进相关法律法规修改完善等方面提出具体举措,以确立国土空间规划的法定地位与统领作用。结合新时期国土空间规划编制,提出了尽快出台国土空间规划编制办法和技术规程、重新调整中国国土空间规划编制的时序安排、加强技术队伍建设等若干建议。     

知识产权贸易下的全球地缘科技格局及其演化

中国崛起,关键在于科技崛起。在当前技术针对与封锁的国际环境中,探讨建构以中国为核心的全球创新网络和科学制定中国未来科技战略是当前创新地理学和地缘政治学交叉之下研究的重点课题,而明晰全球地缘科技格局及其演变过程则是基础所在。本文基于2001—2015年全球国家（地区）间的知识产权进出口数据,在研究全球知识产权贸易格局和网络结构的基础上,探讨了全球地缘科技体系的时空演化特征,得出以下结论：① 全球知识产权贸易网络两极分化显著,是一典型的小世界网络,以美国为核心的金字塔结构不断夯实;② 基于敏感性和脆弱性模型阐释的全球知识产权贸易的非对称依赖性进一步验证了美国是全球地缘科技格局的核心,且其核心地位不断巩固和加强。     

“行政区划本身也是一种重要资源”的理论创新与应用

行政区划是国家治理体系和组织结构的基本形式,也是中央政府统治和管理全国各地的有效手段,是事关国家政治、经济和社会发展全局的重大战略问题。就“行政区划本身也是一种重要资源”的论断进行多视角的分析,提出“行政区划资源论”这一全新的理论解读。分别从空间、权力、行政和政策角度探讨行政区划的资源属性,并从行政资源的空间配置、生产要素的优化配置、权力资源的空间整合、空间资源的优化重组和政策资源的空间载体等多个角度剖析行政区划的资源效应,最后提出应当将“行政区划资源论”这一新论断积极应用至主体功能区规划、空间规划、空间治理体系建设等实践领域,完善目前行政区划设置和调整的思路与要求,建立健全与国家发展战略及综合配套改革相适应的行政区划体系和管理框架。