煤层气井产出剖面测试技术及应用

现有常规油气井产出剖面测试方法在煤层气井中适应性较差,测试范围和测量工艺等存在局限性,施工成功率低。因此,本文对煤层气井产出剖面测试技术进行了整体的系统化设计和研发。通过紧凑的结构设计、高度集成,研发了一套可同时进行温度、压力、磁性定位、热式流量、探针持气率、微波持气、涡轮流量和超声流量等多参数测量的煤层气井测井仪,并研制了一套一次下井可进行多种测试技术测量的煤层气井产出剖面测试技术。同时提高了测试仪器的精度和抗干扰能力,开发了多任务多窗口的便携地面系统操作,并研制新型偏心测试井口应用于煤层气井,实现修井作业时不间断连续测试。该技术在鄂尔多斯盆地石楼北区块3口煤层气井进行了现场试验,取得精确、连续的测试数据。测试结果显示,石楼北区块8^#+9^#煤层为主力产气、产水层。     

勘查植物地球化学在我国不同地球化学景观区的应用现状及展望

勘查植物地球化学是通过分析植物器官来获取成矿元素信息的地球化学方法。我国学者在干旱荒漠区、森林沼泽区、半干旱和湿润半湿润中低山景观区开展了系统的勘查植物地球化学试验,厘定了一批适用于勘查植物地球化学调查的植物,为该方法的推广及应用奠定了良好基础。今后应进一步加强对勘查植物地球化学异常产生的机理、勘查植物地球化学数据库及指南建立、勘查植物地球化学异常遥感应用等方面的研究,更好地利用勘查植物地球化学方法服务矿产勘查工作。     

Biostratigraphy,sedimentology and sequence stratigraphy of the Tournaisian–Viséan transitional strata in South China (Guangxi)

The biostratigraphy and sedimentological evolution of the Tournaisian–Viséan (T–V) transitional strata in South China (Guangxi) have been investigated. The sediments were deposited on a carbonate platform and in slope and basinal environments. In the T–V transitional strata, six foraminiferal associations have been distinguished which allow correlation between the shallow and deep water deposits. A careful examination of the evolutionary stages of the foraminifer Eoparastaffella provides a more accurate criterion for the definition of the T–V boundary, but does not significantly modify the historical one. The distinction of two morphotypes is based on the elevation of the last whorl and the peripheral outline. Tournaisian specimens of Eoparastaffella have a well rounded periphery (morphotype 1) contrasting with the subangular periphery of younger Viséan specimens (morphotype 2). A coefficient can be deduced from simple biometric measurements for more precisely defining the T–V boundary. The sequence stratigraphy of the T–V strata in South China has been reconstructed by combining biostratigraphical and sedimentological data. It allowed the correlation of the T–V transitional strata between the platform area and the slope and basinal locations. Late Tournaisian strata were deposited during a highstand systems tract. Near the end of the Tournaisian, a major drop in relative sea-level led to the development of an unconformity in the platform area. Lowstand deposits formed during latest Tournaisian time in the basin where a detailed biostratigraphic framework has been devised. Sediments deposited during the ensuing transgressive systems tract overlie the late Tournaisian highstand sediments in the platform area and the latest Tournaisian lowstand deposits in the basin. A major drop in relative sea-level near the end of the Tournaisian has been recognized worldwide. Therefore, the possibility of using the sequence stratigraphy of the T–V strata in South China for worldwide correlations should be investigated. © 1997 John Wiley & Sons, Ltd.     

以鲢、鳙养殖为主的长江中下游武山湖浮游植物群落结构特征

武山湖是紧邻长江的通江型富营养化湖泊,是国家级湿地公园.为切实了解该湖在以鲢、鳙养殖为主的情况下浮游植物结构特征,于2017年9月-2018年8月对其浮游植物群落结构特征及水质开展了监测.监测结果表明武山湖水质全年处于轻度富营养到重度富营养水平之间;12次共采集浮游植物7门100种（属）,浮游植物优势种共有23种,其中蓝藻门有9种,绿藻门有8种,硅藻门和隐藻门各有3种.夏季和秋季蓝藻门优势种最多且优势度高,冬季和春季绿藻门和硅藻门优势种多且优势度高.武山湖浮游植物每月优势度最大的种类主要有蓝藻门微囊藻和细小平裂藻、绿藻门小球藻以及硅藻门小环藻.浮游植物生物量峰值出现在6月,达34.77 mg/L;丰度峰值出现在7月,达341.46×10⁶ cells/L.冗余分析（RDA）和线性相关分析均表明浮游植物丰度和生物量与总磷、温度和pH均呈显著正相关,且蓝藻门生物量和丰度以及优势属与总磷和温度均呈显著正相关.研究结果表明武山湖浮游植物丰度和生物量在夏季均很高,发生蓝藻水华的风险较大.相对于氮,磷是更重要的限制浮游植物生长的营养元素.     

近50a洱海水环境演变特征及其主要驱动因素

基于1971 2020年近50年洱海湖区主要水质指标的监测数据,采用M-K检验和GAMs模型定量解析了洱海水质的年际变化趋势,采用多元回归法综合分析了洱海水环境演变的驱动因素。结果表明,近50年来,在流域发展与湖泊保护双轮驱动的作用下,洱海水质年际波动明显,主要水质指标浓度也呈现出多个显著变化的趋势过程。1980s初至1985年间水质指标浓度显著上升,主要与流域南部城镇化发展有关;1986 1980s末显著下降,与南部截污干渠(管)建设密切相关;1990s末至2003年间显著上升,主要与南部城镇工业发展、农业种植结构调整等重要发展策略有关;20042008年间显著下降,主要与中心城区截污治污、环洱海湖滨带修复等重要工程实施有关。在此期间洱海发生过两次较为严重的规模化藻华事件,1996年在水质优良的情况下洱海首次发生蓝藻水华,这与长期低水位运行、网箱养鱼和银鱼引种等导致湖泊生态系统严重受损密切相关;2003年在水质污染加重、生态系统尚未恢复情况下洱海再次发生蓝藻水华。2次藻华事件也改变了流域发展政策,对洱海的科学认识和保护治理力度不断加大,特别是2016年以来高强度的湖泊保护工作,促使洱...     

Peroxymonosulfate Improves the Activity and Stability of Manganese Oxide for Oxidation of Arsenite to Arsenate

Manganese oxide has been widely investigated for oxidation of arsenite (As(III)) to arsenate (As(V)) due to its high redox potential; however, it becomes extremely unstable after reuse. Here, As(III) oxidation activity and stability of manganese oxide in the presence of peroxymonosulfate (PMS) is investigated. Batch experimental results reveal that manganese oxide/PMS exhibits high catalytic activity for As(III) oxidation compared to manganese oxide or PMS alone. Addition of PMS to manganese oxide not only reveals long‐term stability for As(III) oxidation, but also shows high As(III) oxidation activity in the presence of coexisting ions such as As(V) and phosphate. Quenching tests reveal that As(III) oxidation in the manganese oxide/PMS system is attributed to activation of PMS by manganese oxide at different oxidation states (Mn(III) and Mn(IV)), and the generation of sulfate radicals that are responsible for As(III) oxidation.     

水华和赤潮的毒素及其检测与分析

本文介绍了水华和赤潮藻类各种毒素的类型及特点,对近年来毒素检测分析方法进行了综述,重点介绍微囊藻毒素（Microcystin,MCYST,MC）和麻痹性贝毒（Paralytic shellfish poisoning,PSP）的提取、检测方法。     

无定河流域不同水土流失区底栖动物生物完整性指数构建与健康评价

无定河流域位于黄土高原与毛乌素沙地过渡带,水土流失严重,生态环境具有脆弱性和波动性。于2021年春季(4月)和秋季(10月)对无定河流域上、中、下游及其6条支流和流域内的3个淤地坝开展水生态系统调查,旨在厘清无定河流域底栖动物群落特征,构建底栖动物生物完整性指数并开展健康评价。无定河流域春季共采集到底栖动物105种,平均密度为181 ind./m²,平均生物量为0.760 g/m²,秋季共采集到底栖动物67种,平均密度为94 ind./m²,平均生物量为0.454 g/m²。通过对两季度研究区域内底栖动物27个生物参数开展分布范围检验、判别能力分析和相关性分析,构建无定河流域底栖动物生物完整性指数,对全流域40个样点(6个参照点和34个受损点)进行B-IBI健康评价。评价结果表明,总体上无定河流域底栖动物生物完整性较好,40个样点中春季有19个处于健康或亚健康状态,秋季有23个处于健康或亚健康状态,其中无定河上、中游干支流大都以健康和亚健康为主,无定河下游干支流以及3个淤地坝水体健康状况较差。在不同水土流失类型区域,底栖动物群落特征和生物完整性评价具有显著性差异。本研究结果可为无定河流域河流健康评估提供科学依据。     

提高地面气象测报质量的思考

地面气象测报工作是地面气象观测站的基本工作之一,地面气象测报数据质量直接影响着天气预报的准确性。地面气象测报人员必须严肃、认真、负责地做好这项工作。     

Effect of Ca(OH)2, NaCl,and Na2SO4 on the corrosion and electrochemical behavior of rebar

The corrosion of rebar in reinforced concrete in marine environments causes significant damage to structures built in ocean environments. Studies on the process and mechanism of corrosion of rebar in the presence of multiple ions may help to control damage and predict the service life of reinforced concrete structures in such environments. The effect of interactions between sulfate and chloride ions and calcium hydroxide on the electrochemical behavior of rebar are also important for evaluation of structure durability. In this work, electrochemical impedance spectroscopy(EIS) plots of rebar in Ca(OH)_2 solution and cement grout, including NaCl and Na_2SO_4 as aggressive salts, were measured for different immersion times. The results show that corrosion of rebar was controlled by the rate of charge transfer as the rebar was exposed to chloride solution. In the presence of high concentrations of sulfate ions in the electrolyte, generation and dissolution of the passive film proceeded simultaneously and corrosion was mainly controlled by the diffusion rate. When Na_2SO_4 and NaCl were added to Ca(OH)_2 solution, the instantaneous corrosion rate decreased by a factor of 10 to 20 as a result of the higher p H of the corroding solution.