以鲢、鳙养殖为主的长江中下游武山湖浮游植物群落结构特征

武山湖是紧邻长江的通江型富营养化湖泊,是国家级湿地公园.为切实了解该湖在以鲢、鳙养殖为主的情况下浮游植物结构特征,于2017年9月-2018年8月对其浮游植物群落结构特征及水质开展了监测.监测结果表明武山湖水质全年处于轻度富营养到重度富营养水平之间;12次共采集浮游植物7门100种（属）,浮游植物优势种共有23种,其中蓝藻门有9种,绿藻门有8种,硅藻门和隐藻门各有3种.夏季和秋季蓝藻门优势种最多且优势度高,冬季和春季绿藻门和硅藻门优势种多且优势度高.武山湖浮游植物每月优势度最大的种类主要有蓝藻门微囊藻和细小平裂藻、绿藻门小球藻以及硅藻门小环藻.浮游植物生物量峰值出现在6月,达34.77 mg/L;丰度峰值出现在7月,达341.46×10⁶ cells/L.冗余分析（RDA）和线性相关分析均表明浮游植物丰度和生物量与总磷、温度和pH均呈显著正相关,且蓝藻门生物量和丰度以及优势属与总磷和温度均呈显著正相关.研究结果表明武山湖浮游植物丰度和生物量在夏季均很高,发生蓝藻水华的风险较大.相对于氮,磷是更重要的限制浮游植物生长的营养元素.     

近50a洱海水环境演变特征及其主要驱动因素

基于1971 2020年近50年洱海湖区主要水质指标的监测数据,采用M-K检验和GAMs模型定量解析了洱海水质的年际变化趋势,采用多元回归法综合分析了洱海水环境演变的驱动因素。结果表明,近50年来,在流域发展与湖泊保护双轮驱动的作用下,洱海水质年际波动明显,主要水质指标浓度也呈现出多个显著变化的趋势过程。1980s初至1985年间水质指标浓度显著上升,主要与流域南部城镇化发展有关;1986 1980s末显著下降,与南部截污干渠(管)建设密切相关;1990s末至2003年间显著上升,主要与南部城镇工业发展、农业种植结构调整等重要发展策略有关;20042008年间显著下降,主要与中心城区截污治污、环洱海湖滨带修复等重要工程实施有关。在此期间洱海发生过两次较为严重的规模化藻华事件,1996年在水质优良的情况下洱海首次发生蓝藻水华,这与长期低水位运行、网箱养鱼和银鱼引种等导致湖泊生态系统严重受损密切相关;2003年在水质污染加重、生态系统尚未恢复情况下洱海再次发生蓝藻水华。2次藻华事件也改变了流域发展政策,对洱海的科学认识和保护治理力度不断加大,特别是2016年以来高强度的湖泊保护工作,促使洱...     

Peroxymonosulfate Improves the Activity and Stability of Manganese Oxide for Oxidation of Arsenite to Arsenate

Manganese oxide has been widely investigated for oxidation of arsenite (As(III)) to arsenate (As(V)) due to its high redox potential; however, it becomes extremely unstable after reuse. Here, As(III) oxidation activity and stability of manganese oxide in the presence of peroxymonosulfate (PMS) is investigated. Batch experimental results reveal that manganese oxide/PMS exhibits high catalytic activity for As(III) oxidation compared to manganese oxide or PMS alone. Addition of PMS to manganese oxide not only reveals long‐term stability for As(III) oxidation, but also shows high As(III) oxidation activity in the presence of coexisting ions such as As(V) and phosphate. Quenching tests reveal that As(III) oxidation in the manganese oxide/PMS system is attributed to activation of PMS by manganese oxide at different oxidation states (Mn(III) and Mn(IV)), and the generation of sulfate radicals that are responsible for As(III) oxidation.     

水华和赤潮的毒素及其检测与分析

本文介绍了水华和赤潮藻类各种毒素的类型及特点,对近年来毒素检测分析方法进行了综述,重点介绍微囊藻毒素（Microcystin,MCYST,MC）和麻痹性贝毒（Paralytic shellfish poisoning,PSP）的提取、检测方法。     

无定河流域不同水土流失区底栖动物生物完整性指数构建与健康评价

无定河流域位于黄土高原与毛乌素沙地过渡带,水土流失严重,生态环境具有脆弱性和波动性。于2021年春季(4月)和秋季(10月)对无定河流域上、中、下游及其6条支流和流域内的3个淤地坝开展水生态系统调查,旨在厘清无定河流域底栖动物群落特征,构建底栖动物生物完整性指数并开展健康评价。无定河流域春季共采集到底栖动物105种,平均密度为181 ind./m²,平均生物量为0.760 g/m²,秋季共采集到底栖动物67种,平均密度为94 ind./m²,平均生物量为0.454 g/m²。通过对两季度研究区域内底栖动物27个生物参数开展分布范围检验、判别能力分析和相关性分析,构建无定河流域底栖动物生物完整性指数,对全流域40个样点(6个参照点和34个受损点)进行B-IBI健康评价。评价结果表明,总体上无定河流域底栖动物生物完整性较好,40个样点中春季有19个处于健康或亚健康状态,秋季有23个处于健康或亚健康状态,其中无定河上、中游干支流大都以健康和亚健康为主,无定河下游干支流以及3个淤地坝水体健康状况较差。在不同水土流失类型区域,底栖动物群落特征和生物完整性评价具有显著性差异。本研究结果可为无定河流域河流健康评估提供科学依据。     

Effect of Ca(OH)2, NaCl,and Na2SO4 on the corrosion and electrochemical behavior of rebar

The corrosion of rebar in reinforced concrete in marine environments causes significant damage to structures built in ocean environments. Studies on the process and mechanism of corrosion of rebar in the presence of multiple ions may help to control damage and predict the service life of reinforced concrete structures in such environments. The effect of interactions between sulfate and chloride ions and calcium hydroxide on the electrochemical behavior of rebar are also important for evaluation of structure durability. In this work, electrochemical impedance spectroscopy(EIS) plots of rebar in Ca(OH)_2 solution and cement grout, including NaCl and Na_2SO_4 as aggressive salts, were measured for different immersion times. The results show that corrosion of rebar was controlled by the rate of charge transfer as the rebar was exposed to chloride solution. In the presence of high concentrations of sulfate ions in the electrolyte, generation and dissolution of the passive film proceeded simultaneously and corrosion was mainly controlled by the diffusion rate. When Na_2SO_4 and NaCl were added to Ca(OH)_2 solution, the instantaneous corrosion rate decreased by a factor of 10 to 20 as a result of the higher p H of the corroding solution.     

Effects of varying densities on serum reproductive parameters in pen-reared juvenile female rainbow trout <Emphasis Type="Italic">Oncorhynchus mykiss</Emphasis> farms

The primary goal of this study was to assess the effect of varying densities on serum reproductive parameters of immature rainbow trout Oncorhynchus mykiss. Experimental trout were maintained in intensive, pen-reared farms for 300 days in fresh water reservoirs. Initial densities were 4.6, 6.6, and 8.6 kg/m³ (40, 60, 80 ind./m³), indicated as SD1, SD2, SD3, and final densities were 31.1, 40.6, 49.3 kg/m³, respectively. A summary of the ovarian stages were observed by histological examination. Serum E₂ (estradiol), T (testosterone) were evaluated by radioimmunoassay and FSH (follicle-stimulating-hormone), LH (luteinizing-hormone), vitellogenin, 17α,20β-P (17α,20βdihydroxy4-pregnen-3-one) were measured by enzyme-linked immunosorbent assay. Our findings demonstrated that ovarian development were retarded (from stage III to stage IV) at highest rearing density (SD3) after 180 days of intensive culture (over 40.6 kg/m³). In addition, we observed an inverse relationship between serum reproductive parameters and rearing density. Furthermore, compared to serum reproductive parameters of SD1, E₂, T, FSH, vitellogenin, 17α,20β-P, GSI and LH of two higher density groups decreased firstly and significantly at 60 (over 15.9 kg/m 3 ), 180 (over 31.7 kg/m 3 ), 180 (over 40.6 kg/m³), 240 (over 36 kg/m³), 240 (over 36 kg/m³), 240 (over 45 kg/m³) and 300 (over 49.3 kg/m³) days, respectively. Comparing serum reproductive parameters within the same ovarian development stage of rainbow trout from varying densities revealed that higher population density also led to significantly lower overall serum reproductive parameters. Overall, this study presents the reproductive, endocrinological parameters of juvenile female rainbow trout at high rearing densities and indicates the need for rainbow trout (114.44±5.21 g, 19.69±0.31 cm) that are initially stocked at 6.6 or 8.6 kg/m³ should be classified and subdivided into lower density after 180 days of farming (not over 31.7 kg/m³).     

基于Monte Carlo模拟的三维剖面地质界线不确定性分析

三维剖面地质界线是构建三维地质结构模型的重要基础数据,其不确定性会影响三维模型的几何形态和属性分布。以单一分布为假设前提的统计学不确定性分析方法掩盖了其他概率分布特征对模型的影响。突破单一误差分布条件的假设前提,本文使用Monte Carlo方法模拟了不同概率分布情况下地质剖面数据中地质界线的抽样采集,以及地质界线空间分布的不确定性;依托地质界线空间位置与地质属性的耦合关系,提出了用地质属性概率分布实现地质界线空间不确定性的定量可视化,并结合实际地质剖面探讨了多种概率分布条件下地质界线的空间不确定性。实例研究表明,基于Monte Carlo模拟的不确定性分析方法可以突破单一误差分布假设条件,结合地质属性概率可充分揭示出建模数据的内在不确定性与模型外在要素形态之间的耦合关系。     

Effect of bedding planes on wave velocity and AE characteristics of the Longmaxi shale in China

The experimental work described in this paper was carried out in order to discover more about the effects of bedding planes on wave velocity and acoustic emission (AE) characteristics of shale. Two groups of specimens, which were collected from the Longmaxi shale outcrop in Chongqing, China and cored perpendicular and parallel to the bedding planes, were tested under uniaxial compression, and the wave velocity and AE were monitored. There were obvious differences in the acoustic characteristics of shale with different bedding plane orientations. The experimental results show that (1) the average increasing rates of P- and S-wave velocities were 39.86 and 54.41%, respectively, for the specimen with a load perpendicular to the bedding planes (Y-0). The P-wave velocity and axial strain of specimen show a marked logarithmic relationship. However, the average increasing rates of P- and S-wave velocities were 5.44 and 10.54%, respectively, for the specimen with a load parallel to the bedding planes (Y-90). The good linear relationship between P-wave velocity and axial strain before failure of specimen has been built. Generally, S-wave velocity was more sensitive to axial strain than P-wave velocity. (2) AE characteristics for Y-0 showed that a few signals → quiet period → stable increase → steep increase; for Y-90: quiet period → stable increase → sudden increase → sharp increase. The AE energy for two groups of specimens was concentrated on low and middle of amplitudes (45-80 dB), but the proportion of amplitudes (80–100 dB) and the total counts of AE for Y-0 was 1.95, 2.2 times as much as that for Y-90, respectively. The results preliminarily revealed the effect of bedding orientation on the wave velocity and AE properties of shale and may provide guidance for the improvement of acoustic logging and microseismic monitoring in the field.     

DFT study of the carbonation on mineral aerosol surface models of olivine: effect of water

Mineral aerosols play a significant role in gas–solid interfacial and atmospheric chemistry. Carbonation of olivine aerosol, which takes place in a multiphase reaction processes, can be an effective means to reduce the concentration of atmospheric carbon dioxide. Due to the presence of a huge reserve of silicate minerals in nature, olivine aerosol could be an ideal potential raw material for mineral carbonation for its higher reactivity with H₂O and CO₂. However, quantitative information about the carbonation process on the surface of natural olivine aerosol is not available. In this paper, calculations on the carbonation reaction processes with and without a H₂O molecule using a periodic olivine model has been carried out via the density functional theory. The pathways and their corresponding energies and structures in the carbonation reactions have been established, and the effect of water as means to reduce the energy barriers and stabilize the carbonated structures by forming hydrogen bonds has been confirmed.