Continental basalts in the accretionary complexes of the South-west Japan Arc: Constraints from geochemical and Sr and Nd isotopic data of metadiabase

Abstract The Ryoke Belt is one of the important terranes in the South‐west Japan Arc (SJA). It consists mainly of late Cretaceous granitoid rocks, meta‐sedimentary rocks (Jurassic accretionary complexes) and mafic rocks (gabbros, metadiabases; late Permian–early Jurassic). Initial ?_Sr (+ 25– + 59) and ?_Nd (? 2.1–?5.9) values of the metadiabases cannot be explained by crustal contamination but reflect the values of the source material. These values coincide with those of island arc basalt (IAB), active continental margin basalt (ACMB) and continental flood basalt (CFB). Spiderdiagrams and trace element chemistries of the metadiabases have CFB‐signature, rather than those of either IAB or ACMB. The Sr–Nd isotope data, trace element and rare earth element chemistries of the metadiabases indicate that they result from partial melting of continental‐type lithospheric mantle. Mafic granulite xenoliths in middle Miocene volcanic rocks distributed throughout the Ryoke Belt were probably derived from relatively deep crust. Their geochemical and Sr–Nd isotopic characteristics are similar to the metadiabases. This suggests that rocks, equivalent geochemically to the metadiabases, must be widely distributed at relatively deep crustal levels beneath a part of the Ryoke Belt. The geochemical and isotopic features of the metadiabases and mafic granulites from the Ryoke Belt are quite different from those of mafic rocks from other terranes in the SJA. These results imply that the Ryoke mafic rocks (metadiabase, mafic granulite) were not transported from other terranes by crustal movement but formed in situ. Sr–Nd isotopic features of late Cretaceous granitoid rocks occurring in the western part of the Japanese Islands are coincident with those of the Ryoke mafic rocks. Such an isotopic relation between these two rocks suggests that a continental‐type lithosphere is widely represented beneath the western part of the Japanese Islands.     

Deep-sea submersible survey in the Suruga, Sagami and Japan Trenches: preliminary results of the 1985 Kaiko cruise, Leg 2

Nine submersible dives were made in three trenches off central Japan, between 2990 and 5900 m of water depth. Our observations confirm the interpretation that Daiichi-Kashima Seamount is a Cretaceous guyot formed on the Pacific plate that has traveled into the Japan Trench. We also confirmed the previous interpretation of a large normal fault that splits the seamount in two halves, the lower one being now subducting beneath the Japan margin. Compressional deformation was identified within the lower part of the inner slope in front of the seamount. The pattern of deformation that affects Quaternary sediments is in agreement with the present kinematics of the convergence between the Pacific plate and Japan. Deep-water (5700 m) clam colonies are associated with advection of fluids, driven by the subduction-related overpressures. In the northern slope of the Boso Canyon, along the Sagami Trough system (Philippine Sea plate-Japan boundary), the deformation affecting a thick upper Miocene to lower Pliocene sequence indicates two directions of shortening: a N175°E direction which is consistent with the present relative motion along the Sagami Trough (N285–N300°E) and a N30°E direction which could be related to a more northerly direction of convergence that occured during the early Quaternary and earlier.     

Stresses at sites close to the Nojima Fault measured from core samples

Abstract The Nojima Fault in Awaji, Hyogo prefecture, Japan, was ruptured during the 1995 Hyogo-ken Nanbu earthquake ( M _JMA = 7.2). Toshima is located close to the fault segment, in which a large dislocation has been observed on the Earth's surface. Ikuha is near the southern end of the buried fault that extends from the surface rupture. Stresses are measured on core samples taken at depths of 310 m, 312 m and 415 m at Toshima and a depth of 351 m at Ikuha. The measured stresses show that both sites are in the field of a strike–slip regime, but compression dominates at Toshima. Defining the relative shear stress as the maximum shear stress divided by the normal stress on the maximum shear plane, the relative shear stress ranges from 0.42 to 0.54 at Toshima and is approximately 0.32 at Ikuha. While the value at Ikuha is moderate, those at Toshima are comparably large to those in areas close to the inferred fault of the 1984 Nagano-ken Seibu earthquake. Value amounts greater than 0.4 suggest that there are areas of large relative shear stress along faults, thus having the potential to generate earthquakes. Provided that the cores are correctly oriented, the largest horizontal stresses at shallow depths are in the direction from N113°E to N139°E at Toshima and N74°E at Ikuha, indicating that the fault does not orient optimally for the stress field at both sites. The slip is known to be predominant in the right-lateral strike–slip component. Although this slip may appear contradictory to the stress field at Toshima, the slip direction is found to be parallel to the measured stresses resolved on the fault plane for the first approximation. The ratio of shear stress to normal stress on the fault plane is roughly estimated to be greater than zero and smaller than 0.3 near Toshima.     

Structural design of buried pipelines for severe earthquakes

In order to realistically assess the seismic risk of a pipeline system, the accurate estimate of the pipe strains which depend upon structural details, pipe material, properties of the surrounding soil, the nature of the propagating wave, etc. is critical. Emphasis in this study, therefore has been placed on the analysis of a structural strain for several types of piping elements unique to the buried pipeline and also the provision of a simplified design formula which can be used practically. The purpose of this study is (a) to define the slippage factor in order to estimate the decrease in pipe strain resulting from the slippage effect, (b) to propose a simplified method to evaluate the plastic deformation of the pipeline for severe earthquakes, and (c) to derive a practical design formula for the structural strains of bent pipes.     

Chemical environment for red tides due toChattonella antiqua

In order to assess the roles of Fe and Cu in outbreaks ofChattonella antiqua red tide, concentrations of these metals in the surface seawater were monitored around the Ie-shima Islands in the Seto Inland Sea during the summers of 1986–1988. Bioassay of the surface seawater with respect to Fe and Cu was also conducted using a cultured strain ofC. antiqua.Concentrations of Fe and Cu in the filtered seawater (Fe^F and Cu^F) were in the range of 3.9–10.0 and 9.3–11.2 nM, respectively. The bioassay with respect to Fe revealed that Fe at the surface layer was usually insufficient to support the maximum growth rate ofC. antiqua, except whenC. antiqua was dominant in the field. However, correlations between Fe^F and the growth rate of the control cultures (Fe, EDTA=not enriched; N, P, B₁₂=enriched at optimum levels) were not apparent, probably because Fe^F did not reflect the concentration of available Fe.The bioassay with respect to Cu was coupled with the Cu^F values obtained. The results indicated that Cu at the surface layer was detoxified by complexation with natural organic ligand(s), and that pCu (=minus log of cupric ion activity) was 11.5–11.7, optimum for the growth ofC. antiqua, throughout the survey period. It is suggested that Fe, but not Cu, is a potentially important factor in regulating the natural populations ofC. antiqua in the Seto Inland Sea.     

Observations of the total lunar eclipse on March 24, 1978, at 3.4-mm wavelength

Observations of the total lunar eclipse were made at 3.4-mm wavelength (87.4 GHz) on March 24, 1978. Eclipsr cooling curves with the best S/N ratio among those published thus far were obtained for the three points (the mountain area near the crater of Hipparuchus, Sinus Medii, and Copernicus). Each of the curves can be decomposed into the three parts which apparently correspond to ingress, totality, and egress. The derived cooling rate and heating rate differ significantly at the three points.     

Production of bioplastics and hydrogen gas by photosynthetic microorganisms

Experiments on salimity tolerance of embryos and larvae of the southern bay scallopArgopecten irradians concentricus Say under controlled temperature of 28°C showed that although the eggs were fertilized and cleaved at salinity 18.1–37.4, they could further develop into normal D-shaped larvae only at salinity 23.4–36.1, while the trochophore larvae could develop into normal D—shaped larvae at salinity 22.1–39.9. For 72 hours, the larvae could tolerate salinity of 18.4–43.9, the salinity favoring growth was 19.8–42.4; the suitable range was 21–36, and the optimum at about 28. They metamorphosed at salinity 18.9–43.5, optimally at 24–32. Contribution No. 3301 from the Institute of Oceanology, Chinese Academy of Sciences. The research was supported by the National Climbing Project B(PDB6-3-2).     

Electrical conductivities of pyrolitic mantle and MORB materials up to the lowermost mantle conditions

The electrical conductivities of natural pyrolitic mantle and MORB materials were measured at high pressure and temperature covering the entire lower mantle conditions up to 133 GPa and 2650 K. In contrast to the previous laboratory-based models, our data demonstrate that the conductivity of pyrolite does not increase monotonically but varies dramatically with depth in the lower mantle; it drops due to high-spin to low-spin transition of iron in both perovskite and ferropericlase in the mid-lower mantle and increases sharply across the perovskite to post-perovskite phase transition at the D″ layer. We also found that the MORB exhibits much higher conductivity than pyrolite. The depth–conductivity profile measured for pyrolite does not match the geomagnetic field data below about 1500-km depth, possibly suggesting the existence of large quantities of subducted MORB crust in the deep lower mantle. The observations of geomagnetic jerks suggest that the electrical conductivity may be laterally heterogeneous in the lowermost mantle with high anomaly underneath Africa and the Pacific, the same regions as large low shear-wave velocity provinces. Such conductivity and shear-wave speed anomalies are also possibly caused by the deep subduction and accumulation of dense MORB crust above the core–mantle boundary.     

Estrogen equivalent concentration of individual isomer-specific 4-nonylphenol in Ariake sea water, Japan

Concentrations of 4-nonylphenol (NP) were determined by isomer-specific quantification of individual NP isomers based on relative response factor (RRF) quantification with GC–MS in combination with steam distillation extraction. Concentrations of NP in the Ariake Sea decreased with distance from the river mouth (St.A; 49 ng NP/l) to offshore areas (St.C; 11 ng NP/l). Even the least concentration in water from St.C in Ariake Sea was sufficient to have adverse effects on barnacles. The isomers, NP1–NP14 were separated by GC–PFC and identified structurally with NMR. The isomers varied in estrogenic activity with NP7 exhibiting the greatest estrogenic activity with a potency that was approximately 1.9 × 10⁻³ that of 17β-estradiol (E2) in recombinant yeast screen system. The coefficient of variation (CV) of NP isomer’s concentrations among three samples at St.A, B and C were 4–75%. This suggests that NP isomers might be independently degraded in aquatic environmental samples. The predicted estrogenic activity of measured concentrations of NP in Ariake Sea was 2.7–3.0-fold greater than the measured estrogen agonist activity.     

High-pressure transformations of ilmenite to perovskite, and lithium niobate to perovskite in zinc germanate

In-situ X-ray powder diffraction measurements conducted under high pressure confirmed the existence of an unquenchable orthorhombic perovskite in ZnGeO₃. ZnGeO₃ ilmenite transformed into perovskite at 30.0 GPa and 1300±150 K in a laser-heated diamond anvil cell. After releasing the pressure, the lithium niobate phase was recovered as a quenched product. The perovskite was also obtained by recompression of the lithium niobate phase at room temperature under a lower pressure than the equilibrium phase boundary of the ilmenite–perovskite transition. Bulk moduli of ilmenite, lithium niobate, and perovskite phases were calculated on the basis of the refined X-ray diffraction data. The structural relations among these phases are considered in terms of the rotation of GeO₆ octahedra. A slight rotation of the octahedra plays an important role for the transition from lithium niobate to perovskite at ambient temperature. On the other hand, high temperature is needed to rearrange GeO₆ octahedra in the ilmenite–perovskite transition. The correlation of quenchability with rotation angle of GeO₆ octahedra for other germanate perovskites is also discussed.