椒江河口沉积物As、Hg黄铁矿矿化程度及其生物有效性

本文利用取自浙江椒江河口3个未扰动柱状沉积物样,进行了孔隙水化学测试、固相沉积物的活性分量与黄铁矿分量的分级提取和测试,结果表明：Hg主要以黄铁矿态形式存在于沉积物中。As在有机碳较高的河口区潮上带和沉积速率较慢的潮下带主要以黄铁矿形态存在[DTMP（degree of trace metal pyritization,痕量元素黄铁矿矿化程度）〉50%）],而在中潮带As的黄铁矿矿化程度略低（DTMP均值为40.99%）,研究区DOP（Fe的黄铁矿矿化程度）值普遍较低（〈35%）,Mn-DTMP低于3.32%。从而揭示了浙江椒江河口沉积物在数厘米以下,毒性痕量元素Hg和As被高度黄铁矿矿化的规律性,并指出在遇有海事活动或风暴潮事件对海底沉积物进行扰动时,河口沉积物与充氧的海水反应,高度黄铁矿矿化的痕量元素会转变成活性态,从而导致近海生态系统的毒性事件。     

差分层析SAR技术研究现状分析

差分层析SAR是在层析SAR基础上发展起来的一种四维信息反演技术。它不仅实现了对雷达目标的三维分辨能力,同时可以获取目标的形变速率信息,可实现对目标方位-距离-高度-时间四维成像,这对实现城市基础设施动态形变监测、古建筑风险评估、重要工程安全监测等应用具有重要实际意义和价值。本文基于差分层析SAR成像原理,分析了成像处理过程中存在的问题,总结了差分层析SAR成像算法研究现状和特点;最后列举了差分层析SAR技术的主要应用领域,并对其技术发展趋势进行了展望。     

Distribution of ionospheric O<Superscript>+</Superscript> ion in synchronous altitude region

Based on satellite observation data, using dynamics equation, the ionospheric O⁺ ion’s distribution in the synchronous altitude region for different geomagnetic activity indexK _p is studied by theoretical modeling and numerical analyzing, and semi-empirical models for the O⁺ ion’s density and flux versus longitude in the synchronous altitude region for differentK _p are given. The main results show that in the synchronous altitude region: (i) The O⁺ ion’s density and flux in day-side are larger than those in nightside. (ii) With longitude changing, the higher the geomagnetic activity indexK _p is, the higher the O⁺ ion’s density and flux, and their variation amplitude will be. The O⁺ ion’s density and flux whenK _{p ≥} 6 will be about ten times as great as that whenK _p = 0. (iii) WhenK _p = 0 orK _{p ≥} 6, the O⁺ ion’s density reaches maximum at longitudes 120° and 240° respectively, and minimum in the magnetotail. WhenK _p = 3−5, the O⁺ ion’s density gets to maximum at longitude 0°, and minimum in the magnetotail. However, the O⁺ ion’s flux reaches maximum at longitude 120° and 240° respectively, and minimum in the magnetotail for anyK _p value.     

Distribution,sources and potential toxicological significance of polycyclic aromatic hydrocarbons (PAHs) in surface soils of the Yellow River Delta,China

PAH concentrations of 61 surface soil samples collected from the Yellow River Delta (YRD), China were measured to determine occurrence levels, sources, and potential toxicological significance of PAHs. The total concentrations of ∑PAHs ranged from 27 to 753 ng/g d.w., with a mean of 118 ± 132 ng/g. The highest concentrations was found in the mid-southern part of the YRD (753 ng/g), which was associated with the oil exploration. The ratios indicated that the PAHs throughout the YRD were mostly of pyrogenic origin; while various sites in mid-southern part in the region were derived mainly from the petrogenic sources. Multivariate statistical analyses supported that the PAHs in surface soils of the YRD were principally from the coal and biomass combustion, petroleum spills, and/or vehicular emissions. The toxic assessment suggested that the PAHs in soils were at low potential of ecotoxicological contamination level for the YRD.     

Trace metals in porewater of surface sediments and their bioavailability in Jiaozhou Bay,Qingdao, China

Samples of porewater and the edible tissue of mottled clams, Ruditapes variegatus, were collected simultaneously at each of 12 stations from Jiaozhou Bay near Qingdao, China, in June of 2003. Chemical analysis focused on trace metals and major elements. Porewater concentrations of Cd, Cr, Pb, and Zn were distributed in a bimodal fashion among the 12 stations, with mean concentrations at six of the stations being 8–32 times mean values at the other six stations. The concentrations of the same metals in clams were remarkably similar among stations, the coefficients of variation being only 12–37%. Calculations performed with the computer program PHREEQC indicated that Pb and Cr in porewater were present only in the +2 and +3 states, respectively, and because dissolved Cd and Zn exist only in the +2 state, the bimodal distribution of these four metals likely reflects secondary effects associated with their scavenging by Fe and/or Mn under oxidizing conditions and subsequent dissolution in the reducing environment of the porewaters. Consistent with this hypothesis is the fact that the distribution of high and low metal concentrations was closely correlated with the granularity of the sediment, with lower metal concentrations associated with relatively coarse sediment. Comparison of published biological concentration factors with the ratios of metal concentrations in the clams to porewater metal concentrations indicated that the porewaters were not the primary sources of the metals in the clams. Mixing processes in the bay likely account for the rather uniform concentrations of metals in clam tissue.     

滨海湿地咸水冲淡驱动机理

海陆界面水体相互作用研究是当代国际海岸带生态水文学的热点.滨海湿地的生态水文环境脆弱,浅层地下水及盐度梯度变化对其生长和发育起着控制作用.咸水冲淡驱动力主要是地下水动力作用、盐度驱动下的水化学运动作用和海洋潮汐作用的叠加效应.通过国内外学者近30年的研究成果分析了滨海湿地咸水冲淡研究程度及进展情况,认为掌握咸水冲淡驱动...     

华南后汛期降雨量的振动和分布

对１９５９至１９８８年华南后汛期（７－９月）降雨量距平百分率的大尺度变化特征进行了分析,并与前汛期（４－６月）降雨量的情况进行了比较,同时探讨了后汛期降雨量异常的成因。结果表明,华南后汛期雨量存在明显的年际变化,且地区差异显著;后汛期降雨量的异常与热带西太平洋的海水温度、南海地区大气的对流活动及登陆我国东南沿海地区的热带气旋的频数有关。     

湖北省休闲农业示范点空间格局及影响因素研究

运用GIS空间分析方法,对湖北省休闲农业示范点的空间分布特征及影响因素进行了研究。结果表明:湖北省休闲农业示范点为集聚型分布态势,空间差异明显;总体呈"散点状与组团状"分布特征,集中于鄂东和鄂中地区,且主要沿公路、铁路等交通干道及城市周边分布;其空间分布密度具有多中心集群分布趋势,表现出"大分散、小集聚"的分布格局;其空间分布具有显著的自相关性,规模相似地区在空间上趋于集聚,热点区与冷点区呈现出"面状"分布特征,其中,热点区主要分布在荆门、孝感等鄂中地区和武汉,冷点区主要分布在宜昌、恩施、神农架等鄂西地区和鄂东北地区。相关分析得出,农业水平、人口规模、交通设施和资源禀赋是影响湖北省休闲农业示范点空间分布的主要因素。     

南沙海面的夏季风和海—气通量分析

本文分析1984—1988年夏季南沙考察资料。结果表明:南沙海面夏季风来自南路和西路及本区的季风气流。季风潮的出现主要是南路气流加强或季风与热带气旋环流的相互作用。夏季风期间的天气形势、气象特征和海—气通量随季节和天气过程变化显著。