胶州湾沉积物重金属形态不同浸取方法的比较与污染讯息指示作用初探

海洋沉积物中重金属的活性形态对于指示沉积物污染状况具有重要作用;为探寻简洁且能够有效提取重金属活性形态的浸提方法;实验研究了0.1 mol/L和1 mol/L盐酸的单级提取和欧共体标准局（European Community Bureau of Reference）提出的BCR分级提取法对胶州湾表层沉积物中重金属（Cr、Cu、Ni、Pb、Zn）和Al、Fe、Mn的浸取效果。结果显示;3种提取方法提取的金属含量呈显著正相关关系;两种浓度的稀盐酸对BCR方法中的酸可提取态和可还原态金属均具有较好浸提效果;但对可氧化态金属浸提能力相对较弱。不同提取方法的人为信号指数（ASI）计算结果表明;BCR浸取法提取结果的金属ASI值最大;表明其对沉积物中金属活性形态提取效率较高;1 mol/L HCl提取结果的金属ASI值最低;可能是较高浓度强酸使沉积物较大颗粒内层中“惰性”金属被浸取出来;“增加”了金属活性组分的污染讯息信号;对沉积物中Cu、Pb和Zn而言;0.1 mol/L HCl提取结果的ASI值与BCR方法接近。经过Al归一化后;0.1 mol/L HCl浸提的重金属含量的空间分布与胶州湾的实际污染状况相吻合;表明0.1 mol/L的HCl在一定程度上能够代替复杂的BCR浸取法;此方法可简化重金属活性形态的提取步骤;适合大范围沉积物重金属污染评价。     

Study on Longitudinal Deformation Profile of Rock Mass in a Subsea Tunnel

During tunnel excavation, the deformation of surrounding rock due to the unloading of rock mass will vary with time. However, the measured displacement of surrounding rock is only a part of the actual longitudinal deformation profile. There is a need to analyze the longitudinal deformation profile to identify the deformation state and evaluate the stability of surrounding rock mass. In the present article, the variation of pre-deformation of surrounding rock due to excavation was analyzed, and the release coefficient was obtained from the measured results. For the Qingdao subsea tunnel, the measured crown settlement of surrounding rock was analyzed using the regression analysis method, and the longitudinal deformation profile of rock mass was simulated using the numerical calculation method. Moreover, based on the conditions of the subsea tunnel, a solid-fluid coupling model test was carried out to check the reliability of the numerical calculation results. The results of the model test were consistent with the numerical calculation results.     

氮与磷的增加对海水无机碳体系影响的实验模拟研究

海洋碳循环是全球变化研究中的重要领域,它不仅在很大程度上决定了全球气温乃至全球气候的变化趋势,而且还是海洋生态系持续发展的基础,它决定着了海洋生态环境变化的走向。众所周知，碳(C)在海洋中以无机态和有机态的形式存在,在海气系统中,大于98%的C以溶解无机碳(DIC)形式存在于水体中(Zeebe et al,2001)其对海洋碳循环的影响至关重要。 氮(N)和磷(P)等营养盐对维持海洋生态系的正常运转起着至关重要的作用。但是，由于近年来人类生产、生活污水的排放以及滩涂和沿岸水域养殖区的长期施肥,它们也作为近岸海区的主要污染物而导致近海海洋生态环境的日益恶化,影响并改变了一些海域的生态结构。如在胶州湾,由于营养盐浓度及结构发生了变化导致该湾地区浮游植物数量和优势种组成的变化(沈志良,2002)近年来,在海洋沿岸带的河口、海湾等水体较浅的透光层内,以孔石莼等绿藻为主要代表的大型海藻开始泛滥,形成大型海藻的水华。海洋生态环境的改变,必然将导致海洋碳循环的变化,从长时间尺度来看也会影响到全球的气候和气温变化。目前,对营养盐与水生藻类之间的响应关系研究已有大量的报道(王勇等,2002；刘媛等，2004；张文俊等，2004)但对于营养盐与海水无机碳体系之间的耦合作用报道甚少。在海洋环境中、C N P作为主要的生源要素,其变化相互影响,并与海水中所存有的海洋生物密切相关。探讨海水中C-N-P的相互耦合关系对于研究海洋生态环境演变过程及效应,阐明海洋碳循环过程的深层次机理,揭示在过量N P作用富营养化条件下,C的迁移转化行为有重要的科学意义和实际价值。本文作者初步研究了模拟条件下C-N-P的相互关系。     

长江口沉积物对铅的吸附作用

模拟研究长江口悬浮沉积物对Pb的吸附作用,发现沉积物的吸附性能与其氧化铁和有机物等活性组份的含量密切相关,获得Langmuir型吸附等温线,测定饱和吸附容量和分配系数,结果表明,pH和盐度对吸附产生明显影响,吸附率与pH和盐度之间分别呈线性正相关和负相关关系。初步探讨吸附动力学特征,沉积物对Pb吸附化化学作用为主,与厦门港沉积物相似。     

南海夏季风暴发过程的低频特征

应用1979～1996年共18a的NOAA卫星OLR资料及NCEP/NCAR再分析850hPa风场资料,分析了夏季南海地区及南海季风暴发过程的某些低频特征。认为北半球夏季南海地区的低频活动较活跃,并且具有明显的年际变化,这种年际变化同南海季风的暴发时间有联系。南海地区的低频振荡在南海季风暴发后增强。通过对18a 及K*的时段叠加合成图的分析,发现南海夏季风的暴发同赤道印度洋低频振荡的东传及西太平洋低频扰动西传有密切联系,南海夏季风暴发期间南海地区将印度洋与西太平洋之间的低频活动联系在一起。     

基于Zemax外海观测光纤探针传感器探头结构的优化设计

光纤探针法是一种适合观测波浪破碎瞬间卷入微气泡羽流的方法,现有的观测探针探头多采用塑料、玻璃等材质,存在脆性大、损耗大、不耐低温、易腐蚀等缺点,拟设计一种蓝宝石光纤探针克服其局限性,提升探测性能.文章在介绍光纤探针传感器测量原理的基础上,采用光学仿真软件Zemax建立了光纤探针传感器探头的仿真模型,并利用模型对其每针的材质、形状、角度等结构设计关键因素进行了优化设计,由仿真结果确定了每针形状为圆锥形、传输材质为蓝宝石.该仿真结果将为后续光纤探针传感器系统的整体设计及光路优化奠定基础.     

Carbon pools and fluxes in the China Seas and adjacent oceans

The China Seas include the South China Sea, East China Sea, Yellow Sea, and Bohai Sea. Located off the Northwestern Pacific margin, covering 4700000 km~2 from tropical to northern temperate zones, and including a variety of continental margins/basins and depths, the China Seas provide typical cases for carbon budget studies. The South China Sea being a deep basin and part of the Western Pacific Warm Pool is characterized by oceanic features; the East China Sea with a wide continental shelf, enormous terrestrial discharges and open margins to the West Pacific, is featured by strong cross-shelf materials transport; the Yellow Sea is featured by the confluence of cold and warm waters; and the Bohai Sea is a shallow semiclosed gulf with strong impacts of human activities. Three large rivers, the Yangtze River, Yellow River, and Pearl River, flow into the East China Sea, the Bohai Sea, and the South China Sea, respectively. The Kuroshio Current at the outer margin of the Chinese continental shelf is one of the two major western boundary currents of the world oceans and its strength and position directly affect the regional climate of China. These characteristics make the China Seas a typical case of marginal seas to study carbon storage and fluxes. This paper systematically analyzes the literature data on the carbon pools and fluxes of the Bohai Sea,Yellow Sea, East China Sea, and South China Sea, including different interfaces(land-sea, sea-air, sediment-water, and marginal sea-open ocean) and different ecosystems(mangroves, wetland, seagrass beds, macroalgae mariculture, coral reefs, euphotic zones, and water column). Among the four seas, the Bohai Sea and South China Sea are acting as CO_2 sources, releasing about0.22 and 13.86–33.60 Tg C yr~(-1) into the atmosphere, respectively, whereas the Yellow Sea and East China Sea are acting as carbon sinks, absorbing about 1.15 and 6.92–23.30 Tg C yr~(-1) of atmospheric CO_2, respectively. Overall, if only the CO_2 exchange at the sea-air interface is considered, the Chinese marginal seas appear to be a source of atmospheric CO_2, with a net release of 6.01–9.33 Tg C yr~(-1), mainly from the inputs of rivers and adjacent oceans. The riverine dissolved inorganic carbon (DIC) input into the Bohai Sea and Yellow Sea, East China Sea, and South China Sea are 5.04, 14.60, and 40.14 Tg C yr~(-1),respectively. The DIC input from adjacent oceans is as high as 144.81 Tg C yr~(-1), significantly exceeding the carbon released from the seas to the atmosphere. In terms of output, the depositional fluxes of organic carbon in the Bohai Sea, Yellow Sea, East China Sea, and South China Sea are 2.00, 3.60, 7.40, and 5.92 Tg C yr~(-1), respectively. The fluxes of organic carbon from the East China Sea and South China Sea to the adjacent oceans are 15.25–36.70 and 43.93 Tg C yr~(-1), respectively. The annual carbon storage of mangroves, wetlands, and seagrass in Chinese coastal waters is 0.36–1.75 Tg C yr~(-1), with a dissolved organic carbon(DOC) output from seagrass beds of up to 0.59 Tg C yr~(-1). Removable organic carbon flux by Chinese macroalgae mariculture account for 0.68 Tg C yr~(-1) and the associated POC depositional and DOC releasing fluxes are 0.14 and 0.82 Tg C yr~(-1), respectively. Thus, in total, the annual output of organic carbon, which is mainly DOC, in the China Seas is 81.72–104.56 Tg C yr~(-1). The DOC efflux from the East China Sea to the adjacent oceans is 15.00–35.00 Tg C yr~(-1). The DOC efflux from the South China Sea is 31.39 Tg C yr~(-1). Although the marginal China Seas seem to be a source of atmospheric CO_2 based on the CO_2 flux at the sea-air interface, the combined effects of the riverine input in the area, oceanic input, depositional export,and microbial carbon pump(DOC conversion and output) indicate that the China Seas represent an important carbon storage area.     

军队参与国际重大自然灾害救援行动工作机制建设的思考

向遭受严重自然灾害的国家或地区提供人道主义紧急支援,是各国军队在和平时期的重要使命。目前中国军队还没有成建制地出国参加过重大自然灾害的国际救援。本文介绍了联合国重大自然灾害国际救援行动协调工作机制、联合国框架下的军队资源参与灾害救援的工作机制。结合印尼地震海啸、海地地震等灾害中各国军队救援的情况,对我国军队将来参与国际重大自然灾害救援,在法律、预案和工作机制准备方面进行了分析,并提出了建议。     

龙门山断裂带上“破裂空段”的发震概率研究

本文采用分层粘弹性介质模型计算了汶川地震对芦山震中产生的库仑应力加载的影响,进而结合Dieterich(1994)提出的速率状态摩擦定律给出芦山附近区域6级地震累积发震概率随时间的变化。结果显示,2013年芦山7.0级地震时其累积发震概率达18%,说明汶川地震产生的应力扰动加速了芦山地震的发生。本文还计算了汶川、芦山2次地震对其间"破裂空段"处产生的累积库仑应力扰动的影响,结合背景地震发生率,给出了"破裂空段"处6级地震累积发震概率变化。虽然计算结果可能受到大邑地震、介质模型参数的选取和背景地震发生概率等因素影响而存在一定误差,但"破裂空段"在2次强震应力加载下累积发震概率是不断增大的,因此我们认为"破裂空段"处发生中强地震的紧迫性不断增强。     

Analysis of elastic anisotropy of tight sandstone and the influential factors

Tight sandstone has a certain anisotropy. Using ultrasonic measurements of samples in three different directions and related matched experiments, this study systematically analyzes the pore structure and anisotropy of tight sandstone samples obtained from oil fields and compares results with those of shale. Results firstly show that the anisotropy of tight sandstone is mainly related to the compositional layering and thin interbedding which occur in different sedimentary environments. Tight sandstone has typical transverse isotropic medium characteristics, Young’s modulus increases in different directions with increasing confining pressure, Poisson’s ratio change is not obvious, anisotropic coefficients decrease with increasing effective pressure, and a certain linear relationship exists between ε, γ, and δ. This article finally summarizes anisotropy in different areas, thereby providing a foundation for the use of suitable appraisal models in different regions. This research can be used as an experimental reference for logging evaluation, seismic data interpretation, and fracturing develop of tight sandstones.