淮河上游暴雨事件评估模型

暴雨灾害是我国面临的主要气象灾害之一,对其进行评估具有重要的理论和现实意义。该文以气象降水数据为基础建立数据集,采用统计分析的方法建立暴雨事件评估模型,对淮河流域上游的暴雨事件进行评估。该模型选取了4项描述暴雨事件的指标:区域平均日降水量、区域最大日降水量、覆盖范围和持续时间,通过对淮河上游16个站1961—2007年逐日降水量资料的统计分析,按概率分布划分出这4项指标的各等级标准,从而建立暴雨事件等级标准评估矩阵,而需要评估的暴雨事件等级则通过计算该暴雨事件各指标所组成的向量与等级标准评估矩阵中各等级所组成的列向量之间的欧式距离来确定。通过对历史资料及2008年4月—2010年7月发生的暴雨事件实况资料进行评估,发现评估结果与其所造成的实际影响对应较好,说明该模型对暴雨事件等级的划分较为合理。     

山西高温天气的环流特征及流型配置研究

利用1958年-2008年高低空气象观测资料以及山西省气象信息中心归档的109站1958年-2008年的原始气象记录月报表及其信息化产品资料,分别以最高气温≥35℃、≥37℃、≥40℃为指标,研究山西高温日的时空分布、变化趋势及环流特征。结果表明：a）山西高温日最早出现在4月中旬,最晚出现在9月中旬,≥35℃、≥37℃和≥40℃的高温日6月下旬最多;b）高温日数有随纬度、随海拔的升高而减少,有西部多于东部、南部多于北部、盆地多于山区的空间分布特征。≥40℃的高温区域主要集中在运城和临汾地区;C）1984年-2008年,35℃以上的高温日数整体呈上升趋势;1979年-2008年,30年间高温站次以153站次,10a的趋势增多。20世纪90年代以后,不仅高温日数增多,而且高温持续时间、强度、范围都有增强趋势;d）影响山西高温的500hPa环流形势主要有副高纬向性、副高经向型以及大陆高压（脊）控制型3类。在特定的流型配置下,T850≥25℃、T700≥13℃,T850≥26℃、T700≥14℃,T850≥28℃、T700≥15℃,T850≥32℃、T700≥16℃是山西省不同区域、不同风向影响时,≥35℃、≥37℃、≥40℃高温天气预报的临界值。     

危险化工企业的雷电灾害风险评估探讨

近几年来,随着焦作市城市的快速发展和经济增长,危险化工企业数量不断增加.同时,雷电对危险化工企业造成的损失也逐渐凸显出来.由于危险化工企业自身的特殊性,雷电灾害可能给其带来巨大的经济损失和人员伤亡,甚至会引起社会问题.对危险化工企业开展雷电灾害风险评估工作,可以更加全面地掌握雷电灾害相关数据,为安全、合理、经济地选择雷...     

气象综合信息电子屏在新农村建设中的应用及思考

通过对气象综合信息电子屏应用情况进行分析和探讨,得出一些应用初步结论和思考,以期抛砖引玉,使该项工作能在新农村建设中加快应用步伐,为真正解决农村信息覆盖"最后一公里"的瓶颈提供参考.     

Long-term simulations of the sulfur concentrations over the China, Japan and Korea: A model comparison study

Three comprehensive acid deposition models were used to simulate the sulfur concentrations over northeast Asia over the period covering entire year of 2002, and discussed the aggregated uncertainties and discrepancies of the three models. The participating models are from the countries participating in the project of Longrange Transboundary Air Pollutants in Northeast Asia (LTP): China, Japan and Korea. The Eulerian Model-3/CMAQ (by China), Regional Air Quality Model (RAQM, by Japan), and Comprehensive Acid Deposition Model (CADM, by Korea) were employed by each country with common emissions data established by the administrative agencies of China, Japan and Korea. The episodic simulation results between 1 to 15, March 2002 are also presented, during which aircraft measurements were carried out over the Yellow sea. The episodic results show both a wide short-term variability in simulations against measurements, and maximum concentration differences of 3～5 times among the three models, requiring that further attention before confidence among the three models can be claimed for short-term simulations. However, the year-long cumulative simulations showed almost the same general features, with lower aggregated uncertainties between the three models, produced by the long term integration over northeast Asia.     

王水溶样-电感耦合等离子体发射光谱法同时测定铁铜铅锌硫化物矿石中8个元素

建立了王水溶样-电感耦合等离子体发射光谱法同时测定铁、铜、铅、锌硫化物矿中Cu、Pb、Zn、As、Ag、Cd、Hg和Mo等8个元素的分析方法。确定了方法的溶矿及测定条件,用国家一级标准物质GBW07162(多金属贫矿石)和GBW07164(多金属矿石)进行精密度实验,除个别元素外,大多数的元素精密度(RSD,n=11)小于5%,准确度(RE)小于10%。通过一系列硫化物矿石标准物质进行方法验证,检测结果基本都在标准值的误差范围内,符合地质矿产开发的要求。方法简单,同时测定元素较多,线性范围宽,检出限低,尤其有利于硫化物矿石中的亲硫元素As、Ag、Hg的分析,实用性强。     

中国钼矿主要矿集区及其资源潜力探讨

钼矿是中国的优势矿种之一,在全国范围内均有分布。矿床成因类型以斑岩型、矽卡岩型和热液脉型为主,成矿时代以中生代和新生代为主。新世纪,随着科技进步,钼的应用领域逐渐扩大,带动了中国钼矿的勘探和开采工作,取得了一系列找矿新突破,特别是在非传统的钼矿产区发现了许多大型和超大型钼矿,使中国钼矿资源量有了大的突破,基本上改变了过去"南钨北钼"的原有格局。本文在广泛搜集资料的基础上,总结了中国钼矿资源特点,并综合考虑岩浆、构造、地层、流体、成矿时代等因素,初步将中国钼矿划分为17个大的矿床集中区(矿集区),简单介绍了矿集区的基本地质特征和成矿特征,给出了几个最重要矿集区的区域成矿模式,同时根据已有资料和找矿新进展,对主要钼矿矿集区进行了资源潜力分析,并对中国钼矿找矿工作提出了建议。     

Re–Os and U–Pb Geochronology of the Erlihe Pb–Zn Deposit, Qinling Orogenic Belt, Central China, and Constraints on Its Deposit Genesis

The Erlihe Pb–Zn deposit is an important mine of the Pb–Zn metallogenic zone in the South Qinling Orogen. It has been considered a sedimentary exhalative deposit in previous investigations because the ore body occurs concordantly at the transitional location of an upright fold. Re and Os isotopic analyses for paragenetic pyrites with sphalerite and galena from the ore body have been used to determine the timing of mineralization and to trace the source of metallogenic materials. The Re–Os isotopic data of four pyrite samples construct an isochron, yielding a weighted average age of 226±17 Ma (mean square weighted deviation=1.7), which is considered the main mineralization age. A dioritic porphyrite vein sample, showing weaker mineralization, was also dated using the SHRIMP zircon U–Pb isotopic method to constrain the youngest metallogenic age of the ore deposit, because it distributes along a group of tensional joints cutting not only the upright fold in the deposit field, but also the main ore bodies. The dioritic porphyrite sample yields a weighted mean 206Pb/238U age of 221±3 Ma, which is slightly younger than the Re–Os isotopic isochron age of the pyrites, considered as the upper age limit of the mineralization, namely the ending age of the mineralization. The Os isotopic compositions of sulfide minerals distribute within a range between Os isotopic compositions of the crust and the mantle, indicating that the ore deposit can be derived from magma-related fluid, and the metallogenic materials are most likely derived from the mixing source of the crust and the mantle. The Erlihe Pb–Zn deposit and associated dioritic porphyrite vein, important records of Qinling tectonic–magmatism–mineralization activities, were formed during the Triassic collisional orogeny processes.     

Geological, geochemical characteristics and isotope systematics of the Longqiao iron deposit in the Lu-Zong volcano-sedimentary basin, Middle-Lower Yangtze (Changjiang) River Valley, Eastern China

The Middle-Lower Yangtze (Changjiang) River Valley metallogenic belt is located on the northern margin of the Yangtze Craton of eastern China. Most polymetallic deposits in the Changjiang metallogenic belt are clustered in seven districts where magmatism of Mesozoic age (Yanshanian tectono-thermal event) is particularly extensive. From west to east these districts are: E-dong, Jiu-Rui, Anqing-Guichi, Lu-Zong, Tong-Ling, Ning-Wu and Ning-Zhen. World-class iron ore deposits occur in the Lu-Zong and Ning-Wu ore clusters, which are mainly located in continental fault-bound volcanic-sedimentary basins. One of these deposits is the Longqiao iron deposit, discovered in the northern part of the Lu-Zong Basin in 1985. This deposit consists of a single stratabound and stratiform orebody, hosted in sedimentary carbonate rocks of the Triassic Dongma'anshan Formation. A syenite pluton (Longqiao intrusion) is situated below the deposit. The iron ore is massive and disseminated and the ore minerals are mainly magnetite and minor pyrite. Wall rock alteration mostly consists of skarn minerals, such as diopside, garnet, potassic feldspar, quartz, chlorite, phlogopite and anhydrite. Thin sedimentary siderite beds of Triassic age occur as relict laminated ore at the top and the margin of the magnetite orebody. These sideritic laminae are part of Triassic evaporite-bearing carbonate deposits (Dongma'anshan Formation).Sulfur isotopic compositions show that the sulfur in the deposit was derived from a mixture of magmatic hydrothermal fluids and carbonate–evaporite host rocks. Similarly, the C and O isotopic compositions of limestones from the Dongma'anshan Formation indicate that these rocks interacted with magmatic hydrothermal fluids. The O isotopic compositions of the syenitic rocks and minerals from the deposit show that the hydrothermal magnetite and skarn minerals were formed from magmatic fluids. The Pb isotopic compositions of sulfides are similar to those of the Longqiao syenite. Phlogopite coexisting with magnetite in the magnetite ores yielded a plateau age of 130.5 ± 1.1 Ma (2σ), whereas the LA-ICP MS age of the syenite intrusion is 131.1 ± 1.5 Ma, which is slightly older than the age of phlogopite.The Longqiao syenite intrusion may have crystallized from a parental alkaline magma, generated by partial melting of lithospheric mantle, during extensional tectonics. The ore fluids were probably first derived from magma at depth, later emplaced in the sedimentary rocks of the Dongma'anshan Formation, where it interacted with siderite and evaporite-bearing carbonate strata, resulting in the formation of magnetite and skarn minerals. The Longqiao iron deposit is a skarn-type stratabound and stratiform mineral system, genetically and temporally related to the Longqiao syenite intrusion. The Longqiao syenite is part of the widespread Mesozoic intracontinental magmatism (Yanshanian event) in eastern China, which has been linked to lithospheric delamination and asthenospheric upwelling.     

不同氧化锰矿物对光催化降解苯酚的影响

合成层状结构的酸性和碱性水钠锰矿以及隧道结构的锰钾矿和钙锰矿,将其用于苯酚的光催化降解研究。分别采用X射线衍射(XRD)、原子吸收光谱(AAS)、扫描电镜(SEM)、BET氮气吸附法和紫外可见漫反射光谱(UV-Vis DRS)对供试锰氧化物的晶体结构、化学组成、微观形貌、比表面积以及光吸收性能等进行了表征。研究表明,暗反应条件锰氧化物对苯酚的降解作用较弱,而UV-Vis光照能显著促进锰氧化物对苯酚的降解。光照反应12 h后,锰钾矿、酸性水钠锰矿、钙锰矿以及碱性水钠锰矿的苯酚降解率分别为92.1%、77.3%、57.4%和45.8%;对应的TOC去除率分别由暗反应时的6.3%、11.2%、2.0%和4.6%提高至62.1%、43.1%、25.4%和22.5%。4种供试锰氧化物均具有光催化活性,其大小顺序为:锰钾矿>酸性水钠锰矿>钙锰矿>碱性水钠锰矿。UV-Vis光照下氧化锰矿物光化学降解苯酚主要存在3种降解机制———苯酚的直接光解,锰氧化物的化学氧化和锰氧化物的光化学催化,其中光催化降解起主导作用。