珠江流域降水集中度时空变化特征及成因分析

基于珠江流域内43个常规气象站点1960~2012年的逐日降水资料,计算了流域内各站点长期降水集中度(LCI)和逐年降水集中度(ACI);采用Mann-Kendall趋势检验法和Sen’s坡度检验法检测ACI时间上的变化趋势;同时采用反距离权重插值法(IDW)对LCI的区域特征和ACI的变化趋势进行空间插值以分析降水集中度的时空分布规律;采用随机森林(RF)算法对降水集中度的影响因子进行重要度分析。结果表明:(1)珠江流域逐年降水集中度ACI的年际变化不明显,东南部呈上升趋势,西北部呈下降趋势;(2)珠江流域西北部长期降水集中度LCI值偏小,即降水分布较平均;东南部长期降水集中度LCI值偏大,即降水较集中,表明该地区降水极值情况发生的几率相对较高,该空间分布趋势可能是受距离海洋的远近及海拔的影响;(3)众多气候影响因子中,东亚夏季季风(EASMI)对珠江流域的降水集中度影响最明显。     

日本囊对虾Marsupenaeus japonicus)组织蛋白酶D基因克隆及表达分析

组织蛋白酶D是溶酶体天冬氨酸蛋白酶家族的主要成员,广泛参与动物机体细胞内蛋白质的降解过程,对维持细胞稳态和正常代谢具有重要的作用。为研究组织蛋白酶D在甲壳动物非特异性免疫和幼体发育过程中的作用,本研究采用RACE技术首次克隆得到日本囊对虾组织蛋白酶D基因cDNA序列,命名为MjCatD,其中开放阅读框长为1161 bp,编码386个氨基酸残基。序列分析和同源建模显示该基因编码的蛋白含有保守的N-糖基化位点、天冬氨酸蛋白酶签名序列、酶活化位点和非消化性组织蛋白酶D的特征序列,并且呈保守的双叶形结构。同源性比较和系统进化分析发现,MjCatD与斑节对虾、美洲螯龙虾和脊尾白虾相似性较高,并且与它们紧密聚为一支。实时荧光定量PCR结果显示,MjCatD基因在日本囊对虾多个组织中均有表达,其中肝胰腺中表达量最高。在白斑综合征病毒(white spot syndrome virus, WSSV)感染后3～24 h日本囊对虾肝胰腺中MjCatD的表达量逐渐下降,而在48 h急剧上调至最高表达量并且与对照组差异极显著(P<0.01)。此外,MjCatD基因在幼体发育不同阶段中也表现出明显的变化趋势。以上研究表明,MjCatD基因可能参与日本囊对虾先天免疫反应和幼体发育过程。     

温度、盐度和光照对浒苔生长和光合作用的影响

Intensive Pyropia aquaculture in the coast of southwestern Yellow Sea and its subsequent waste, including disposed Ulva prolifera, was speculated to be one of the major sources for the large-scale green tide proceeding in the Yellow Sea since 2007. It was, however, unclear how the detached U. prolifera responded and resumed growing after they detached from its original habitat. In this study, we investigated the growth and photosynthetic response of the detached U. prolifera to various temperature, salinity and irradiance in the laboratory. The photosynthetic rate of the detached U. prolifera was significantly higher at moderate temperature levels(14–27°C)and high salinity(26–32), with optimum at 23°C and 32. Both low(14°C) and highest temperature(40°C), as well as low salinity(8) had adverse effects on the photosynthesis. Compared with the other Ulva species, U. prolifera showed higher saturated irradiance and no significant photoinhibition at high irradiance, indicating the great tolerance of U. prolifera to the high irradiance. The dense branch and complex structure of floating mats could help protect the thalli and reduce photoinhibition in field. Furthermore, temperature exerted a stronger influence on the growth rate of the detached U. prolifera compared to salinity. Overall, the high growth rate of this detached U. prolifera(10.6%–16.7% d~(–1)) at a wide range of temperature(5–32°C) and salinity(14–32) implied its blooming tendency with fluctuated salinity and temperature during floating. The environmental parameters in the southwestern Yellow Sea at the beginning of green tide were coincident with the optimal conditions for the detached U. prolifera.     

五硼酸铷溶液的物化性质及物种分布

碳酸铷、硼酸化学计量比混合,蒸发溶液,直至五硼酸铷RbB5O8·4H2O晶体析出。经粉末X射线衍射（XRD）、拉曼光谱（Raman spectroscopy）、热重/微商热重/差示扫描量热（TG/DTG/DSC）、原子吸收光谱等实验方法,确定其化学组成及结构。298.15、333.15K时测量溶液的物理化学性质（密度、电导、pH）,并与经验方程进行拟合,研究五硼酸铷溶液的物化性质随浓度、温度的变化规律。根据文献报道的平衡常数,实验测量的pH数据,采用牛顿迭代法进一步研究五硼酸铷溶液中主要存在的硼酸根离子对类型、含量以及物种的形成。     

榆树林油田扶杨油层沉积岩地球化学特征及地质意义

三肇凹陷榆树林油田扶杨油层中泥岩、粉砂岩和砂岩样品主量元素和微量元素地球化学分析表明,多数主量元素含量中等,与全球平均大陆上地壳(UCC)相比,Fe_2O_3、MgO、CaO、Na_2O含量较低,而TiO_2、Al_2O_3、K_2O、MnO含量均略高;样品中的相容元素(V、Cr、Co、Ni等)含量均低于澳大利亚后太古宙页岩(PAAS)和UCC;稀土元素总量为102×10~(-6)~276×10~(-6),平均为188×10~(-6),与PAAS表现出相似的球粒陨石标准化曲线,显示了相似的物源和构造背景。元素间的相关性分析显示大部分元素与SiO_2负相关而与Al_2O_3正相关,说明大部分元素受到黏土矿物吸附作用的影响,石英与长石矿物对这些元素表现出一定的稀释效应。根据主元素物源判别方程图和Th-Hf-Co图投影及La/Hf、(Gd/Yb)N值,扶杨油层物源主要来自后太古宙长英质火山岩,可能卷入了部分再循环沉积岩。通过一系列的构造背景判别图解分析,表明扶杨油层沉积时以大陆岛弧环境为主。在对油层组进行了纵向古气候分析后,认为FI油层组沉积时处于一个构造活动强、干旱的环境中,所形成的沉积岩储层物性更好,是油气勘探开发的重点层位。     

塔里木陆块西北缘萨热克砂岩型铜矿床构造-流体演化对成矿的制约

塔里木陆块西北缘萨热克砂岩型铜矿床构造演化、流体演化与成矿之间具有密切关系,处于一个统一系统中。矿床成岩期方解石中包裹体水的δD值为-65.3‰~-99.2‰,改造成矿期石英包裹体水的δD值为-77.7‰~-96.3‰,成岩成矿期成矿流体δ~(18)OH_2O变化范围为-3.22‰~1.84‰,改造成矿期成矿流体δ~(18)OH_2O变化范围为-4.26‰~5.14‰,指示萨热克铜矿成岩期、改造期成矿流体主要为中生代大气降水及其经水岩作用而成的盆地卤水。矿石中辉铜矿δ~(34)S值为-24.7‰~-15.4‰,指示硫主要源自硫酸盐细菌与有机质还原,部分源于有机硫。构造与成矿流体演化对砂岩铜矿成矿起关键制约作用。盆地发展早期强烈的抬升运动使盆地周缘基底与古生界剥蚀,为富铜矿源层的形成提供了丰富物源,至晚侏罗世盆地发展晚期,长期演化积聚的巨量含矿流体在库孜贡苏组砾岩胶结物及裂隙中富集,在萨热克巴依盆地内形成具有经济意义的砂岩型铜矿床。     

Correlation analysis between drought indices and terrestrial water storage from 2002 to 2015 in China

Drought monitoring is a key topic in environmental monitoring and assessment although there is still a need to determine the correlation between drought monitoring indices and remote sensing products. We analyzed the correlation between the self-calibrating Palmer Drought Severity Index (sc_PDSI), the Standardized Precipitation Index and the Standardized Precipitation Evapotranspiration Index (SPEI) and terrestrial water storage monitored through the Gravity Recovery and Climate Experiment (GRACE) on a monthly timescale from 2002 to 2015 in China. As a consequence of anomalies in the soil water budget, the highly significant correlation between the sc_PDSI and the GRACE satellite-observed terrestrial water storage suggested that these two datasets are the most suitable for use in monitoring droughts. In comparing the three drought indices, the sc_PDSI was introduced as a means of drought monitoring in the Yangtze, Pearl, Huaihe, Southeast and Songhua River Basins, whereas the SPEI was found to be more applicable to other major river basins, such as the Inland River Basin. These diverse spatial behaviors are caused by the differences between the hydrological droughts characterized by these three drought indices.     

Spatial and temporal variations of suspended solid concentrations from 2000 to 2013 in Poyang Lake,China

Concentrations of suspended solids in lakes can affect the latter’s primary productivity and reflect changes in sediment deposition. Determining the temporal and spatial distribution of suspended solid concentrations has important significance in lake water environmental management; this is particularly urgent for Poyang Lake, the largest freshwater lake in China. In this study, suspended solid concentration inversion models for Poyang Lake were created using a semi-empirical method with regression analysis between continuously measured suspended solid concentration data and multi-band moderate-resolution imaging spectroradiometer images for spring, summer, autumn, and winter from 2009 to 2012. The coefficient of determination (R²) is from 0.6 to 0.9 and the average relative error for the accuracy verification was between 10 and 30%. The seasonal distributions of suspended solid concentrations in Poyang Lake from 2000 to 2013 were then obtained using optimal reversal models. The results showed that the seasonal variation in suspended solid concentrations had a “W” shape in which high spring and autumn and low summer and winter values. The suspended solid concentrations increased annually from 2000 to 2013 and were mainly distributed in the northern and central portions of the lake, with lower values along the shorelines. Further analysis indicated that the large difference in water level between the wet and dry seasons is an important factor in explaining these seasonal variations. Moreover, the suspended solid concentrations were poorly correlated with water temperature and chlorophyll-a concentration but more highly correlated with the deferred chlorophyll-a concentration.     

川北地区寒武系筇竹寺组钙质结核裂缝充填物特征及指示意义

川北地区寒武系筇竹寺组钙质结核泥页岩中早成岩期钙质结核较发育,结核裂缝中见多期次矿物充填。为揭示钙质结核裂缝形成机理,本次结合岩石学特征及地球化学特征等开展系统研究。川北筇竹寺组钙质结核裂缝中见三~四期矿物充填。第一期微晶方解石表面较脏,阴极发光暗淡,δ13C_(PDB)、δ18O_(PDB)平均值分别为-4.26‰及-7.69‰;第二期为细—中晶粒状方解石充填,阴极发光为橘黄色,流体包裹体均一温度为平均值为86.4℃,δ13C_(PDB)、δ18O_(PDB)平均值分别为-3.15‰及-7.41‰;第三期为粗晶方解石充填阴极发光暗淡,流体包裹体均一温度平均值为96.6℃,δ~(13)C_(_(PDB))、δ~(18)O_(_(PDB))平均值分别为-1.73‰及-10.28‰;第四期为重晶石充填。结合区域构造史—热演化史分析表明,钙质结核裂缝中四期充填物分别指示早期脱水、烃源岩早成熟期生烃、加里东构造运动抬升释压及深埋藏期硫酸盐热还原作用事件。