Synthesis, Characterization and Antibacterial Activity of New Ln（Ⅲ ） Complexes with an Unsymmetrical Schiff Base Ligand

1Introduction SomeSchiffbasecomplexesderivedfromaminoacidsareparticularlyactiveinbiologycatalysisandmaterial.Thestudyofthemisfocusofthestudyof coordinationchemistry.Recently,studiesofsuchmetalcomplexesofmono Schiffbaseshavebeenre ported(Fanetal.,2003a,b;L…     

北大巴山早古生代地幔交代作用与煌斑岩浆的起源和演化

产于陕西岚皋境内、赋存于碱质煌斑杂岩中的金云角 闪 辉石岩捕虏体是交 代地幔捕虏体。微量元素和SrNd同位素的对比研究表明,金云角闪辉石岩型交代地幔是寄 主煌斑岩的源区。金云角闪辉石岩捕虏体富含高Na、Ti的角闪石是本区寄主煌斑岩富Ti, 具 低K/Na值的根本原因。煌斑杂岩的同位素地球化学研究表明,早古生代地幔交代作用相对 于煌斑岩的侵位是一个相对近的时间间隔,大约发生于距今600～700 Ma。寄主煌斑岩 的 原生岩浆是金云角闪辉石岩型地幔经较大程度部分熔融而形成,原生岩浆为相似于橄榄金伯 利岩和橄辉玢岩的碱质超基性煌斑岩浆,其经初步分离结晶后形成两个不同的母岩浆,分别 相当于橄榄金伯利岩浆和橄辉玢岩岩浆,两个母岩浆各自具有不同的分离结晶系列,形成不 同的岩石类型。     

Geology and geochemistry of the Bingdaban ophiolitic mélange in the boundary fault zone on the northern Central Tianshan Belt,and its tectonic implications

The properties and tectonic significance of the fault bound zone on the northern margin of the Central Tianshan belt are key issues to understand the tectonic framework and evolutionary history of the Tianshan Orogenic Belt. Based on the geological and geochemical studies in the Tianshan orogenic belt, it is suggested that the ophiolitic slices found in the Bingdaban area represent the remaining oceanic crust of the Early Paleozoic ocean between the Hazakstan and Zhungaer blocks. Mainly composed of basalts, gabbros and diabases, the ophiolites were overthrust onto the boundary fault between the Northern Tianshan and Central Tianshan belts. The major element geochemistry is characterized by high TiO₂ (1.50%–2.25%) and MgO (6.64%–9.35%), low K₂O (0.06%–0.41%) and P₂O₅ (0.1%–0.2%), and Na₂O>K₂O as well. Low ΣREE and depletion in LREE indicate that the original magma was derived from a depleted mantle source. Compared with a primitive mantle, the geochemistry of the basalts from the Bingdaban area is featureded by depletion in Th, U, Nb, La, Ce and Pr, and unfractionated in HFS elements. The ratios of Zr/Nb, Nb/La, Hf/Ta, Th/Yb and Hf/Th are similar to those of the typical N-MORB. It can be interpreted that the basalts in the Bingdaban area were derived from a depleted mantle source, and formed in a matured mid-oceanic ridge setting during the matured evolutionary stage of the Northern Tianshan ocean. In comparison with the basalts, the diabases from the Bingdaban area show higher contents of Al₂O₃, ΣREE and HFS elements as well as unfractionated incompatible elements except Cs, Rb and Ba, and about 10 times the values of the primitive mantle. Thus, the diabases are thought to be derived from a primitive mantle and similar to the typical E-MORB. The diabases also have slight Nb depletion accompanying no apparent Th enrichment compared with N-MORB. From studies of the regional geology and all above evidence, it can be suggested that the diabases from the Bingdaban area were formed in the mid-oceanic ridge of the Northern Tianshan ocean during the initial spreading stage. Supported by the Major State Research Program of PRC (Grant No. 2001CB409801), the National Natural Science Foundation of China (Grant Nos. 40472115 and 40234041) and the State Research Program of China Geological Survey (Grant No. 2001130000-22)     

数字地质调查系统中空间数据库建库流程 关键技术的解决方案

空间数据库建库流程是数字地质调查系统总体技术流程的一个重要组成部分。针对地质人员实际工作量等方面的几个关键技术问题提出了详细的解决方案．并在数字地质调查系统的软件系统中以辅助建库工具、辅助检查工具、数据检索工具的形式加以实现。为建库提供了技术保障,保证了数据的质量,有效地提高了地质人员对地质调查系统的应用能力和建库的效率。     

新一代天气雷达故障处理和故障标准化平台的研发与应用

新一代天气雷达是一个组成结构复杂的探测平台,各个组合之间比较分散。由于机械运转的持续性,且对运行环境要求严格,所以雷达系统易发故障。对不同类型的雷达故障进行归纳和简析,并进行归类,按照雷达故障产生的原因分类为:雷达部件故障、软件故障、灾害引起的雷达故障、虚假报警、雷达产品图像错误。天气雷达故障处理和故障标准化平台的开发将相应的成果应用于日常的气象探测设备的监控业务中,并集成到综合气象观测系统运行监控平台,以实现天气雷达故障的快速响应和维修。对2007年6月至2010年5月新一代天气雷达的运行能力进行了计算,并抽样其中2种型号的天气雷达,对故障案例进行分析研究,给出了故障的分系统分布情况。     

双流冬草莓低温冻害天气特征及防冻措施探讨

双流县作为我国最大的冬草莓生产基地,低温冻害是冬季生产关键期的主要气象灾害。本文对2005年初低温冻害进行了分析,归纳出了双流县冬草莓低温冻害的发生规律及冻害临界温度指标,并提出了具体的防冻措施。     

河北丰宁招兵沟铁磷矿床地质及综合利用前景

河北丰宁招兵沟铁磷矿床为赋存于太古宇绿岩带内低品位特大型矿床。含磷岩系具近似绿岩带下部火山岩群的特点。铁磷矿体呈层状,大的透镜状产出,还伴生Ti、V 等有益元素。矿石选矿回收性能良好。通过对该区当前内生低品位铁磷矿开采情况的调查,认为我国北方低品位铁磷矿综合利用前景乐观。     

东洞庭湖沉积物覆水后磷形态变化及其释放量

研究干燥覆水后低流速条件下东洞庭湖沉积物中磷的形态变化及释放量,可以为轻度富营养化湖泊中磷的生物地球化学循环提供基础数据,为季节性湖泊內源营养盐的迁移转化规律研究、內源营养盐的释放风险评价提供理论依据.本文采集处于干湿交替状态的东洞庭湖表层沉积物,利用室内模拟装置,研究风干沉积物低流速条件下覆水后沉积物及上覆水中磷的形态变化.结果表明,低流速覆水后东洞庭湖沉积物中的磷向上覆水及大气中迁移释放,上覆水中磷的释放量随覆水时长增大,释放速率随覆水时长减小,上覆水流速和磷释放量相关性显著.上覆水循环过程中释放到上覆水中的溶解态有机磷比溶解态活性磷更容易吸附于颗粒物而转化为颗粒态磷.覆水后沉积物中各形态有机磷、无机磷及磷的生物有效性均发生转变,覆水初期沉积物中无机磷向有机磷转化,磷的生物可利用性增大;上覆水循环过程中有机磷向无机磷转化,磷的生物可利用性减小;覆水后沉积物的无机磷的主要组分由铝磷转变为铁磷,有机磷的主要组分有从中活性有机磷向活性有机磷转变的趋势.     

Remarks on dynamical ellipticity at the Earth's

In this paper, two factors — the redistribution of the density and the variation in the angular velocity of the Earth rotation, that affect the adopted value of the flattening for equidensity surface within the Earth, are discussed. The computational results show that the contribution of the redistribution of the density in the Earth interior (especially in the core) on the change of the flattening at the core-mantle boundary (CMB) is marginal, and that the calculated value of the flattening at the CMB can be in good agreement with the VLBI observed value so long as the fact that the angular velocity of the Earth rotation has undergone the tidal evolution is taken into account. As a result, this paper presents a set of recommended values of the dynamical parameters of the Earth (see Table III) for computing Earth's forced nutation series.     

江汉平原沔城M1孔的沉积特征与古环境重建

通过对江汉平原沔城M₁孔湖泊沉积物进行沉积特征、粒度、14C年代、孢粉分析,重建了晚冰期以来该地区古环境、古气候演化的过程和序列:晚冰期后期有一扩张期,气候温湿并出现湖泊相沉积;晚冰期末期气候温凉偏干、河流环境;全新世初期(10-8.9kaBP),气候转向温湿;全新世大暖期(8.9-3.5kaBP),总体上气候温暖湿润,其中6.8-4.9kaBP是最宜期,4.9-4.8kaBP和4.4-4.2kaBP为两次降温事件,4.8kaBP积水湖盆开始形成,3.9-3.5kaBP为云梦泽鼎盛期;全新世晚期(3.5-1.7kaBP),气温较大暖期有所下降,其中3.5-2.5kaBP温凉偏湿,2.5-1.7kaBP较为温湿,湖泊较为稳定,1.7kaBP开始,云梦泽萎缩,钻孔所在位置出露水面。