Nb–Ta fractionation induced by fluid‐rock interaction in subduction‐zones: constraints from UHP eclogite‐ and vein‐hosted rutile from the Dabie orogen,Central‐Eastern China

Niobium and Ta concentrations in ultrahigh‐pressure (UHP) eclogites and rutile from these eclogites and associated high pressure (HP) veins were used to study the behaviour of Nb–Ta during dehydration and fluid‐rock interaction. Samples were collected through a ～2 km profile at the Bixiling complex in the Dabie orogenic belt, Central‐Eastern China. All but one eclogite away from veins (EAVs) display nearly constant Nb/Ta ratios ranging from 16.1 to 19.2, with an average of 16.9 ± 0.8 (2 SE), similar to that of their gabbroic protolith from the Yangtze Block. Nb/Ta ratios of rutile from the EAVs range from 12.7 to 25.3 among different individual grains, with the average values close to those of the corresponding bulk rocks. These observations show that Nb and Ta were not significantly fractionated by prograde metamorphism up to eclogite facies when no significant fluid‐rock interaction occurs. In contrast, Nb/Ta ratios of rutile from eclogites close to veins (ECVs) are highly variable from 17.8 to 49.8, which are systematically higher (by up to 17) than those of rutile from the veins. These observations demonstrate that Nb and Ta were mobilized and fractionated during localized fluid flow and intensive fluid‐rock interaction. This is strongly supported by Nb/Ta zoning patterns in single rutile grains revealed by in situ LA‐ICP‐MS analysis. Ratios of Nb/Ta in the ECV‐hosted rutile decrease gradually from cores towards rims, whereas those in the EAV‐hosted rutile are nearly invariable. Furthermore, the vein rutile shows Nb/Ta zoning patterns that are complementary to those in rutile from their immediate hosts (ECVs), suggesting an internal origin for the vein‐forming fluids. The Nb/Ta ratios of such fluids evolved from low values at the early stage of subduction to higher values at later supercritical conditions with increased temperature and pressure. Quantitative modelling was conducted to constrain the compositional evolution of metamorphic fluids during dehydration and fluid‐rock interaction focusing on Nb–Ta distribution. The modelling results based on our proposed multistage fluid phase evolution path can essentially reproduce the natural observations reported in the present study.     

南极长城站Pi2地磁脉动特征

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中国晚前寒武纪 Pseudogymnosolenidae

<正> 1974年在我国上前寒武系蓟县层型剖面蓟县系雾迷山组下部首次报道了一个新的叠层石群Pseudogymnosolen Liang et Tsao,近数年来在我国许多地区陆续发现该群分子。与此同时,又发现大量的形态上与Pseudogymnosolen具有一定相似性但又有明显区别的新的叠层石群。作者认为原假裸枝叠层石群(相当属)资料十分丰富,已有足够条件提升为超群Pseudogymnosolenidae(相当科)。此超群的叠层石具有固定的柱体形态(表1图2),局部柱体本身是由一系列紧密相连的假柱组成,故它们的分类位置应归于柱-层叠层石大类。但因叠层体微小(柱体直径一般小于1厘米),具较频繁的平行和微散开分叉,它们可以与柱-层叠层石大类的其他叠层石明显区分。     

北祁连铜厂沟金矿含金黄铁矿热电性分析与找矿标志研究

根据铜厂沟金矿的矿区地质特征、含金黄铁矿热电性与微量元素分析等的研究,认为铜厂沟矿区自东向西黄铁矿热电性主要为N型电子导型,且有高负值→低正值→低负值→高负值变化趋势,提出Ag、As、Sb元素高浓度特征是金矿富集的有利部位,高硫黄铁矿与低硫黄铁矿混生或P、N导型黄铁矿混生是金矿富集的标志,含黄铁矿硫化物石英脉是有利的找矿标志.     

复合土钉支护结构中土钉设置的合理型式

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山东半岛地下水库建设与研究进展

合理建设和管理地下水库是我国北方缺水地区增加水资源可利用量的有效途径.为了有效利用暴雨洪水资源,同时阻止海水沿河道下游入侵地下水含水层,自上世纪80年代以来,山东半岛陆续兴建了多座地下水库.介绍了山东半岛地下水库建设成就、地下水库建设的潜力、采取的技术措施和主要研究进展.指出地下水库环境保护是亟待引起重视的问题.     

内蒙古乌达地区地球物理场特征与地下煤火分布

以2004年内蒙古乌达地区1:5000大比例尺的直升机航空电磁、磁综合测量资料为基础,结合地面煤田地质、物探、遥感等资料,对内蒙古乌达地区的航空磁场特征、航空电磁场特征与地下煤火分布的关系进行了分析与研究,在综合分析的基础上,建立了该区的地下煤火划分标志,并对该区的地下煤火分布和燃烧状况进行了分析和圈定.     

宗教教义中的环保思想评析

古人对于环保问题十分重视，这在宗教方面表现为，宗教教义及宗教思想中有不少相关的论述：《圣经》中有着朦胧的环境保护意识；道教经典《太平经》中有具有拟人化特征的环保思想；佛教对于人与自然的关系也具有一定深度的认识。宗教环保思想的历史渊源可以上溯至宗教的起始阶段——原始宗教时期，早在原始宗教中就已经存在自然崇拜、动植物崇拜。通过对于宗教的四要素中的核心要素——宗教教义要素所赖以产生的现实基础的剖析可以看出，这些环保思想和崇拜行为是与当时的社会生产力发展水平、科学发展水平、人类的认识能力，尤其是人类生存和发展对于自然物的依赖等因素有密切关系。     

Origin of gray-green sandstone in ore bed of sandstone type uranium deposit in north Ordos Basin

Dongsheng sandstone-type uranium deposit is located in the northern part of Ordos Basin, occurring in the transitional zones between gray-green and gray sandstones of Jurassic Zhiluo Formation. Sandstones in oxidized zone of the ore bed look gray-green, being of unique signature and different from one of ordinary inter-layered oxidation zone of sandstone-type uranium deposits. The character and origin of gray-green sandstones are systematically studied through their petrology, mineralogy and geochemistry. It is pointed out that this color of sandstones is originated from secondary oil-gas reduction processes after paleo-oxidation, being due to acicular-leaf chlorite covering surfaces of the sandstone grains. To find out the origin of gray-green sandstone and recognize paleo-oxidation zones in the ore bed are of not only theoretical significance for understanding metallogenesis of this kind of sandstone-type uranium deposit, but also very importantly practical significance for prospecting for similar kind of sandstone-type uranium deposit.     

经纬仪i角检定中的符号问题

通过对经纬仪横轴与竖轴垂直度的测试分析，就检定规程JJG414-94中所得供的计算公式的符号问题，提出了更正意见。