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411.
412.
The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields. 相似文献
413.
A remarkable invariance in the ratio of 1,3-dimethylcarbazole (DMC) to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate. 相似文献
414.
土地利用总体规划实施评价与修编的研究 总被引:4,自引:0,他引:4
本文在客观评价上一轮土地利用总体规划的基础上,结合新一轮土地利用总体规划修编的背景和国家宏观调控下的土地政策变化趋势,提出了当前福建省土地利用总体规划修编和今后实施的有关建议,以更好地指导新一轮土地利用总体规划的修编工作。 相似文献
415.
庙岛群岛旅游资源丰富。本文运用特尔斐法(Delphi)及层次分析法(AHP)构建庙岛群岛旅游资源开发价值评估模型,定性与定量相结合,对10个条件适宜的岛屿进行评估。进而提出优化庙岛群岛旅游资源空间结构,实现可持续利用的若干对策。 相似文献
416.
云南东北部拱王山末次冰期 总被引:1,自引:0,他引:1
1 Introduction The Gongwang mountains constitute one of the few high m ountains of irrefutable late Pleistocene glaciation in eastern China. This area is one of the m ost extensively studied Quaternary geologicallocationsin eastern China and the interpret… 相似文献
417.
Wenzhi Zhao Shuichang Zhang Feiyu Wang Jianping Chen Zhongyao Xiao Fuqing Song 《Organic Geochemistry》2005,36(12):1602-1616
Oil and gas exploration in eastern Tarim Basin, NW China has been successful in recent years, with several commercial gas accumulations being discovered in a thermally mature to over-mature region. The Yingnan2 (YN2) gas field, situated in the Yingnan structure of the Yingjisu Depression, produces gases that are relatively enriched in nitrogen and C2+ alkanes. The δ13C1 (−38.6‰ to −36.2‰) and δ13C2 values (−30.9‰ to −34.7‰) of these gases are characteristic of marine sourced gases with relatively high maturity levels. The distributions of biomarkers in the associated condensates suggest close affinities with the Cambrian–Lower Ordovician source rocks which, in the Yingjisu Sag, are currently over-mature (with 3–4%Ro). Burial and thermal maturity modeling results indicate that paleo-temperatures of the Cambrian–Lower Ordovician source rocks had increased from 90 to 210 °C during the late Caledonian orogeny (458–438 Ma), due to rapid subsidence and sediment loading. By the end of Ordovician, hydrocarbon potential in these source rocks had been largely exhausted. The homogenization temperatures of hydrocarbon fluid inclusions identified from the Jurassic reservoirs of the YN2 gas field suggest a hydrocarbon emplacement time as recent as about 10 Ma, when the maturity levels of Middle–Lower Jurassic source rocks in the study area were too low (<0.7%Ro) to form a large quantity of oil and gas. The presence of abundant diamondoid hydrocarbons in the associated condensates and the relatively heavy isotopic values of the oils indicate that the gases were derived from thermal cracking of early-formed oils. Estimation from the stable carbon isotope ratios of gaseous alkanes suggests that the gases may have been formed at temperatures well above 190 °C. Thus, the oil and gas accumulation history in the study area can be reconstructed as follows: (1) during the late Caledonian orogeny, the Cambrian–Lower Ordovician marine source rocks had gone through the peak oil, wet gas and dry gas generation stages, with the generated oil and gas migrating upwards along faults and fractures to form early oil and gas accumulations in the Middle–Upper Ordovician and Silurian sandstone reservoirs; (2) since the late Yanshanian orogeny, the early oil accumulations have been buried deeper and oil has undergone thermal cracking to form gas; (3) during the late Himalayan orogeny, the seals for the deep reservoirs were breached; and the gas and condensates migrated upward and eventually accumulating in the relatively shallow Jurassic reservoirs. 相似文献
418.
文章列数了《中国地层典》5个方面的重要失误:不是中国地层名称全览性的工具书,急于采用处于争议中的术语,大量地层单位名称的出处因考证不到位而形成张冠李戴,采用的历史优先律不是国际共识,在编撰过程中建立新名称。文章用选出的泰山杂岩、滹沱系、秦岭片岩和仑山石灰岩4个名称为例说明《中国地层典》对其出处的考证不到位,进而论证《中国地层典》的诸多解释可信度低。文章严肃地指出“历史优先律”给中国地层学造成的不良后果:它破坏了地层命名法的标准性,颠倒了中国地层命名史,干扰了中国地层名称的管理。 相似文献
419.
420.
Analysis of the environmental sensitivities of a typical dynamic epikarst system at the Nongla monitoring site, Guangxi, China 总被引:6,自引:0,他引:6
Nongla, a typical karst dynamic system (KDS) monitoring site, is located at Nongla Village, Mashan County, Guangxi, China. The data from a Greenspan CTDP300 multichannel data logger indicates that the KDS is highly sensitive to environmental changes. Multi-day and diurnal physico-chemical composition of epikarst spring water is quite different under different climatic conditions. During a day with no rainfall, water temperature and air temperature have similar variations. Electrical conductivity (EC) has good positive correlation with pH value and water temperature. During rainstorms, the physico-chemical composition of the spring water is initially strongly effected by dilution, pH and EC drop rapidly. However, half to one hour later, EC returns to normal and the CO2 effects will be the dominant physical effect. This is due to the high fissure rates and high permeability in the epikarst zone. Dilution effects were observed during the entire rainstorm event,whereas, it only acts during the earliest period of light rain. Therefore, it is necessary to examine the water–rock–CO2 combination as a whole system to explain the hydrochemical behavior of epikarst processes. 相似文献