阿尔泰晚古生代早期长英质火山岩的地球化学特征及构造背景

新疆北部哈巴河一带出露的一套晚古生代早期长英质火山岩主要由英安质—流纹质火山岩组成。其Rb-Sr等时线年龄为405±57Ma,为早泥盆世。地球化学特征显示它们具有Ti含量低,Mg#含量中等—富集(42.2~88.7),Th/Ta为8.6~16.4,低—中等Ti/Zr值(介于4.9~53.46);稀土配分型式为LREE富集,无Eu或中等的负Eu异常;且在蜘蛛网图上显示LILE富集,Nb和Ta亏损的特征。Y-Nb和Rb-(Y+Nb)构造判别图解显示这些长英质火山岩形成于岛弧环境。结合前人的研究成果,认为新疆北部哈巴河晚古生代早期长英质火山岩是在古亚洲洋北侧岛弧构造环境下形成的,是作为古亚洲洋从SW至NE方向朝西伯利亚古板块俯冲的产物。     

中亚成矿域斑岩大规模成矿特征：大地构造背景、流体作用与成矿深部动力学机制

中亚成矿域夹持于西伯利亚、东欧和塔里木-华北克拉通之间,展布范围与全球显生宙大陆地壳生长最典型的增生型造山带——中亚造山带相当,并产出一系列大型—超大型斑岩铜(-金)、斑岩钼及斑岩铜(-钼)矿床。斑岩成矿作用自西向东存在明显差异,可高度概括为具‘西铜东钼、早铜晚钼’特征。基于前寒武纪基底性质、成矿大地构造背景以及斑岩成矿特征方面的系统综合研究,以重要构造线为界,将成矿域进一步划分为三个成矿省:哈萨克斯坦斑岩Cu(-Au-Mo)、蒙古斑岩Cu(-Au)和中国东北斑岩Mo(-Cu)成矿省。哈萨克斯坦成矿省具新太古—古元古代结晶基底;四个大型斑岩Cu矿床形成于早古生代增生造山过程(481~440Ma),而绝大多数矿床为晚石炭世(330~295Ma)集中爆发成矿的产物。古亚洲洋西段,沿我国中天山—伊犁南缘—吉尔吉斯北天山—中哈萨克斯坦—科克切塔夫至成吉思线性展布的古生代岩浆弧与哈萨克斯坦山弯构造共同制约了斑岩成矿作用;增生造山向山弯构造的转换阶段为斑岩集中成矿期。蒙古斑岩成矿省亦具新太古代—早古元古代结晶基底;斑岩成矿作用主要发生在泥盆纪(~370Ma)和三叠纪(~240Ma)两个时期,为图瓦-蒙古山弯构造演化过程中两个局部时段的突发成矿;早期成矿事件与古亚洲洋体系向南戈壁微地块下的俯冲增生造山有关,晚期成矿可能是蒙古—鄂霍茨克洋俯冲作用的结果。中国东北斑岩成矿省广泛发育新元古代结晶基底和泛非事件岩石学记录;奥陶纪(482~440Ma)斑岩成矿受控于古亚洲洋早古生代时期俯冲增生作用;而中生代斑岩钼集中爆发成矿则分别受控于古亚洲洋体系后碰撞(~250Ma)、蒙古—鄂霍茨克洋体系同俯冲(248~204Ma)、古太平洋体系同俯冲(195~145Ma)及中国东部岩石圈减薄事件(145~106Ma)不同地球动力学体制。成矿流体方面总体而论,中亚斑岩型矿床热液蚀变遵循经典Lowell and Guibert模式,高氧化性岩浆流体有效出溶造就了大型-超大型斑岩矿床。中亚成矿域斑岩铜矿的成矿斑岩岩石类型与环太平洋域成矿斑岩类似,以钙碱性和高钾钙碱性成分为主,最常见的是石英二长闪长岩、二长花岗岩、花岗闪长岩和花岗岩。成钼矿斑岩比成铜(-金-钼)斑岩更偏酸性,具更高SiO2含量。部分斑岩具埃达克质岩微量元素地球化学特征,另一部分斑岩却有类似正常弧火山岩的特征。虽然现有弧环境斑岩岩浆产生的‘MASH’和‘板片熔融’模型以及‘后碰撞拆沉与新生基性下地壳熔融’模型能够解释中亚成矿域部分斑岩铜矿床成矿的深部机制,但本文新提出‘残余洋中脊俯冲+预富集基性下地壳熔融’模型解释哈萨克斯坦成矿省巴尔喀什—西准噶尔成矿带斑岩铜大规模成矿的深部机制。中亚域斑岩钼成矿与古老地壳或古老岩石圈地幔的熔融无关,而与新生地壳熔融产生长英质岩浆的深部事件存在直接成因联系。西段哈萨克斯坦省新生地壳由古生代古亚洲洋演化过程中弧增生事件形成,而东段中国东北成矿省新生地壳则是新元古代与Rodinia超大陆相关聚合和裂解事件造就的。"新生下地壳部分熔融成钼"模型突破了钼成矿与古老地壳熔融有关的传统认识,能很好地解释全球最大的中国东北钼成矿省的成矿深部动力学机制。     

Early Carboniferous High Ba‐Sr Granitoid in Southern Langshan of Northeastern Alxa: Implications for Accretionary Tectonics along the Southern Central Asian Orogenic Belt

Voluminous granitoids are widely distributed in the Langshan region, northeast of the Alxa block, and record the evolutionary processes of the southern Central Asian Orogenic Belt. The Dabashan pluton was emplaced into the Paleoproterozoic Diebusige complex. Early Carboniferous zircon LA-ICP MS U-Pb ages were from 327 Ma to 346 Ma. The Dabashan pluton can be classified as monzogranite and syenogranite, and exhibits high K2O contents and K2O/Na2O ratios, which reveal a high-K calc-alkaline nature. The samples display strongly fractionated REE patterns, and are enriched in large ion lithophile elements (LILE) relative to high field strength elements (HFSE). The Dabashan plutons display unusually high Ba (823–2817 ppm) and Sr (166–520 ppm) contents and K/Rb ratios (315–627), but low Rb/Ba ratios (0.02–0.14), and exhibit fertile zircon Hf isotopic compositions [εHf(t)=?14 to ?20], which are comparable to those of typical high Ba–Sr granitoids. Based on the geochemical compositions of the samples, we suggest that subducted sediments and ancient crustal materials both played important roles in their generation. Basaltic melts were derived from partial melting of subcontinental lithophile mantle metasomatized by subducted sediment-related melts with residual garnet in the source, which caused partial melting of ancient lower crust. Magmas derived from underplating ascended and emplaced in the middle–upper crust at different depths. The resultant magmas experienced some degree of fractional crystallization during their ascent. Given these geochemical characteristics, together with regional tectonic, magmatic, and structure analysis data, an active continental margin environment is proposed for the generation of these rocks.     

新疆东天山秋格明塔什——黄山韧性剪切带^40Ar／^39Ar年代学研究

秋格明塔什—黄山巨型韧性剪切带产出在东天山北部,其活动时期的系统厘定对东天山大地构造演化极为关键,因而对揭示中亚造山带南部晚期的历史有着重要意义。系统的Ar-Ar同位素年代学研究表明,该剪切带的活动在时间上具有多期性:剪切带早期为挤压推覆剪切作用,发生于300Ma之后,至少延续到了283.7Ma,但在280.2Ma时已经终止;晚期为右行走滑剪切变形作用,主活动期的时代为262.9～242.8Ma,历时近20Ma。在右行走滑剪切变形阶段,秋格明塔什—黄山韧性剪切带出现差异抬升现象,导致剪切带不同区段糜棱岩的同位素年龄有较大差别:剪切带中—西段(康古尔地区)走滑剪切变形作用产生的糜棱岩的时代为262.9～256.1Ma,快速抬升发生在262.9～261.5Ma,冷却速率>100℃/Ma。剪切带东段(土屋—延东地区)走滑剪切变形作用产生的糜棱岩的时代为247.1～242.8Ma,快速抬升发生在247.1～246.9Ma期间,冷却速率>200℃/Ma。结合区域地质资料,笔者认为早期的挤压推覆剪切作用可能与东天山晚古生代板块俯冲—碰撞过程有关,而晚期的走滑剪切变形则可能反映了东天山北部地区碰撞后陆内变形特征。     

阿尔泰喀纳斯早泥盆纪钾质富镁英安岩:俯冲沉积物熔体交代

阿尔泰造山带喀纳斯地区出露一套钾质富镁英安岩,锆石U-Pb定年显示其形成于早泥盆世(411±4 Ma)。该套英安岩富SiO_2(64.71～67.77 wt%),MgO(3.28～3.53 wt%)和K_2O(2.12～2.75 wt%),贫Na_2O(1.70～1.85wt%),K_2O/Na_2O比值介于(1.20～1.53),具较高的Al_2O_3(14.12～15.33 wt%)和较低的CaO(1.12～1.28 wt%),ASI指数1.8,显示过铝质钙碱性岩浆系列特征,明显不同于初始的高镁安山质岩浆。样品具有中等的Cr(134×10~(-6)～153×10~(-6))、Co(17.47×10~(-6)～18.65×10~(-6))、Ni(71.64×10~(-6)～80.76×10~(-6))含量,富集大离子亲石元素Rb、K和高场强元素U、Th、Pb及LREE,发育Sr、Ba及"TNT"(Ta、Nb、Ti)负异常,显示俯冲带岩浆岩地球化学特征。其高的Mg~#(51.71～52.47)和低的ε_(Nd)(t)值(-4.6～-4.2)说明该套火山岩可能来自遭受强烈交代作用的地幔楔部分熔融。样品具有较高的Ba/La、Pb/La比值和较低的Th/Yb、Nb/Y比值,显示地幔交代作用以俯冲沉积物熔体的交代作用为主。以上地球化学特征说明,喀纳斯钾质富镁英安岩可能主要是受俯冲沉积物熔体交代的上覆地幔橄榄岩部分熔融的产物,阿尔泰泥盆纪处于俯冲作用相关的活动大陆边缘构造环境。此外,该套火山岩的形成时代制约了其下覆的哈巴河群沉积上限,显示哈巴河群沉积于早泥盆世之前。     

Nature and timing of the Solonker suture of the Central Asian Orogenic Belt: insights from geochronology and geochemistry of basic intrusions in the Xilin Gol Complex,Inner Mongolia,China

The Solonker suture zone of the Central Asian Orogenic Belt (CAOB) records the final closure of the Paleo-Asian Ocean. The nature and timing of final collision along the Solonker suture has long been controversial, partly because of an incomplete record of isotopic ages and differing interpretations of the geological environments of key tectonic units. The Xilin Gol Complex, consisting of strongly deformed gneisses, schists and amphibolites, is such a key tectonic unit within the CAOB. Lenticular or quasi-lamellar amphibolites are dispersed throughout the complex, intercalated with biotite–plagioclase gneiss. Both rock types experienced amphibolite-facies metamorphism. The protolith of the amphibolite is a basic rock that intruded into the biotite–plagioclase gneiss at 319 ± 4 Ma based on LA-ICPMS zircon U–Pb dating. The basic intrusion was sourced from a modified magma that experienced crystal fractionation and was admixed with slab-derived fluids. The slab-derived fluids, which formed during Early Paleozoic oceanic subduction along the north-dipping Sonidzuoqi–Xilinhot subduction zone, mixed with the magma source and produced subduction-related geochemical signatures superimposed on volcanic arc chemistry. After Early Paleozoic oceanic subduction and arc-continent collision, a transient stage of extension occurred between 313 and 280 Ma in the Sonidzuoqi–Xilinhot area. Deformation and recrystallization during the switch from compression to extension and reheating by the later magmatic intrusions reset the isotope systems of minerals in the Xilin Gol Complex, recorded by a 312.2 ± 1.5 Ma biotite ⁴⁰Ar/³⁹Ar age from biotite–plagioclase gneiss, a 309 ± 12 Ma zircon intercept age and a 307.5 ± 3.5 Ma hornblende ⁴⁰Ar/³⁹Ar age from amphibolites in the complex. There was an arc/forearc-related marine basin at the southern margin of the Xilin Gol Complex during the Permian. The closure of the oceanic basin led to Late Paleozoic–Middle Triassic north-dipping subduction beneath the Xilin Gol Complex and induced the amphibolite-facies metamorphism of the complex. The final suturing of the Solonker zone occurred from 269 to 231 Ma. This latest amphibolite-facies metamorphism with pressures of 0.31–0.39 GPa and temperatures of 620–660 °C was recorded at 263.4 ± 1.4 Ma to the Xilin Gol Complex, as indicated by the hornblende ⁴⁰Ar/³⁹Ar age from the amphibolites, as well as several zircon ages of 260 ± 3–231 ± 3 Ma. The Xilin Gol Complex documented the progressive accretion of a single, long-lived subduction system at the southern margin of the south Mongolian microcontinent from the Early Paleozoic (~452 Ma) to Middle Triassic (~231 Ma). The CAOB shows protracted collision prior to final suturing.     

Geochemistry and petrogenesis of the Yishak Volcanic Sequence,Kudi ophiolite,West Kunlun (NW China): implications for the magmatic evolution in a subduction zone environment

The Yishak Volcanic Series (YVS) is part of the Late Cambrian Kudi ophiolite in the western Kunlun Mountains, NW China, which marks the oldest suture zone in the Tibetan Plateau. The YVS is a well-preserved sequence comprising five conformable units (A to E) of basalts to andesites, with mafic dykes in Units A to D. These rocks are sequentially characterized upward by geochemical features of N-MORB (Unit A), E-MORB (Unit B), island-arc basalt (Unit C), BABB (Unit D and mafic dykes) and boninite series rocks (Unit E), reflecting complex interactions among various source components. The evolution of magma compositions from MORB-dominated to boninite series rocks clearly indicates temporally increasing subduction signatures, which, in combination with the extensional tectonic background, suggests that the Kudi ophiolite most likely formed in a spontaneous nucleation of subduction zone.     

农业物候动态对地表生物物理过程及气候的反馈研究进展

地表过程对全球变化的响应和反馈是地球系统科学研究的核心课题之一,目前的研究多关注全球变化对地表过程的影响,而地表动态过程对地表生物物理过程及气候的反馈研究较少。系统认识地表物候动态对生物物理过程及气候的反馈对深化地球系统科学研究有着重要的意义。本文从农业物候动态的事实、农业物候动态在陆面过程模型中的参数化表达、农业物候动态对地表生物物理过程及气候的反馈等方面进行综述,发现在气候变化和管理措施影响下,以种植期和灌浆期为代表的农业物候期发生了显著的规律性变化;耦合农业物候动态,改善了模型对地表动态过程、生物物理过程和大气过程的数字化表达;农业物候变化对地表净辐射、潜热、感热、反照率和气温、降水、环流等过程产生了影响,并表现出以地表能量分配为主的气候反馈机理。针对农业物候动态对地表生物物理过程及气候效应的时空重要性,需要继续开展以下方面的工作：① 加强全球变化对地表物候动态的影响及其反馈的综合研究;② 不同光谱波段地表反射率与农业物候动态的关系研究;③ 农业物候动态引起的作物生理学特征变化在地表生物物理过程中的贡献;④ 重视不同气候区物候动态对气候反馈效应的差异。     

深圳福田白骨壤红树林Cu,Pb,Zn,Cd的累积及分布

于1994年3月，采用样方法分析、探讨深圳福田自然保护区车公庙林区白骨壤红树林重金属Cu，Ph，Zn，Cd元素的累积及分布。结果表明：该林地表层土壤（0—3cm深），Cu，Ph，Zn，Cd的含量分别为383．28．7，1140，0136×10－6，储量分别为5285.40，3960.60,15732.00,18.77mg／m2、植物体各部位Cu，Pb,Zn，Cd含量范围分别为1.81-13.8，0.402－3．51，3．42－69.5，0.013－0295×10-6对表层土壤加权平均富集系数为Cd＞Zn＞Cu＞Pb.该群落Cu，Pb，Zn，Cd现存累积量分别为53．70,19．27，187.89,0.72mg／m2；年净存留累积量分别为4063.91，1318.14，16358.62，60．21μg／m2；林地残留物相应元素的储量分别为2091.18，1958.66,5046.60,19.30μg／m2。该林区不同群落叶层Cu，Pb,Zn，Cd现存累积量为白骨壤林＞桐花树林＞秋茄林。