溶剂萃取原子吸收光谱法测定高纯石英砂中痕量铁

高纯石英砂用HF等溶剂溶解并蒸干后,在微酸性介质中用抗坏血酸还原Fe^3＋为Fe^2＋,与1,10-二氮杂菲形成Fe2＋3络合物,加入适量ClO4^-阴离子与之形成离子缔合物,用硝基苯萃取,原子吸收测定有机相,本法检出限1.1μg/g,样品分析结果的RSD%为：4.52～10.3.     

Facies-controlled volcanic reservoirs of northern Songliao Basin, NE China

Volcanic rocks of the late Mesozoic are very important reservoirs for the commercial natural gases including hydrocarbon, carbon dioxide and rare gases in the northern Songliao Basin. The reservoir volcanic rocks include rhyolite, andesite, trachyte, basalt and tuff. Facies of the volcanic rocks can be classified into 5 categories and 15 special types. Porosity and permeability of the volcanic reservoirs are facies-controlled. Commercial reservoirs were commonly found among the following volcanic subfacies: volcanic neck (I1) , underground-explosive breccia (I3), pyroclastic-bearing lava flow (II3), upper effusive (III3) and inner extrusive ones (IV1). The best volcanic reservoirs are generally evolved in the interbedded explosive and effusive volcanics. Rhyolites show in general better reservoir features than other types of rocks do.     

利用Sentinel-3A OLCI可见光通道反演台湾岛气溶胶光学厚度

OLCI（Ocean Land Colour Instrument）作为MERIS（Medium Resolution Imaging Spectrometer）的后继升级版传感器,在气溶胶反演中存在潜在优势,但是目前利用OLCI数据进行气溶胶监测的研究较少。因此,本文针对OLCI多通道反射特征开发了OLCI云检测算法,并对传统查找表构建方法进行改进,根据观测几何特征提出动态查找表法,并通过光谱卷积方式等效转换MODIS和OLCI红蓝通道地表反射率并获取OLCI红蓝通道地表反射率固定关系,进而实现台湾岛550 nm处的AOD反演。与550 nm处AERONET level 2.0 AOD验证结果首先表明不同季节、不同站点的精度表现存在一定差异,其次相对于同期MOD04_3K AOD产品,本文反演结果与全球气溶胶自动观测网（AERONET）站点实测值之间表现出更显著 的相关性（R²=0.8199）,均方根误差（RMSE）从0.175下降到0.113,相对平均误差（RME）从33.6%下降到26.7%,且67.5%的OLCI AOD落在预测误差（EE）区间内,明显大于MOD04_3K AOD落在预测误差区间的百分比（55.7%）。此外,误差分析表明,当实际AOD值较低时,红蓝通道地表反射率之间关系的误判会导致较为明显的AOD反演相对误差。     

上海―长沙―张家界旅游互动关系研究

上海、长沙、张家界是长江经济带上三个重要的旅游城市,且旅游业发展具有较强的互补性。在分析三地旅游互动的基础、现状以及存在问题与障碍的基础上,提出三地旅游互动机制构建的基本思路,主要包括确立合理的旅游分工体系、打造旅游互动的要素基础、创新旅游互动发展机制、建立多元化的协调机制等,以期为促进以制度整合导向为主要引擎的三地旅游深度合作与联动发展,同时也为我国非相邻区域大尺度空间范围内城市型旅游目的地互动关系的构建提供一个基础性架构和可资借鉴的理论范式。     

贵州土地石漠化类型时空演变过程及其评价

构建了贵州20世纪80年代、90年代和21世纪初等3期历史石漠化数据,利用其空间变换和数学模型详细探讨和评价了石漠化的时空演变过程,研究发现:(1)研究时段内贵州省石漠化总面积变化不明显,但石漠化内部类型之间的相互演变非常显著,各类型之间的演变具有转移、多变、"此消彼长"的特点.(2)石漠化的时空演变过程可分为单变方式、层变方式、返变方式等3种基本类型,其中以层变方式为主.单变方式为辅.返变方式较少.(3)石漠化正向演变与逆向演变并存,治理速度赶不上恶化速度,两者的比值为82.29%,局部治理,整体恶化.(4)各石漠化类型总的演变速率是398.31 km2·a-1,石漠化等级越高,演变速率越慢.(5)石漠化演变频率最快的是中度石漠化和潜在石漠化.轻度石漠化的演变频率明显低于中度石漠化.对石漠化的空间演变区域特征和影响因子做了宏观的定性分析、并根据石漠化演变特点对综合治理提出了相应的建议.     

Groundwater System Division and Description of Asia

Based on landform, climate, river system, geological structure and hydrogeological structure and from the perspective of systematology, the groundwater system of Asia can be divided into 36 secondary groundwater systems under 11 primary ones by the intercontinental scale. This forms part of the work of the groundwater series map of Asia, which is compiled according to groundwater system division and evaluation of the total amount and types of aquifer, reflecting the large-scale features of groundwater resources in Asia. Systematic profiling of groundwater in this way provides a scientific basis for groundwater exploitation planning and management in Asia, and avoiding disputes over groundwater resources and the environment among Asian countries.     

盐碱化湿地稻-鱼复合生态系统微生物特征

为揭示盐碱化湿地稻-鱼复合生态系统微生物群落结构特征,1994-1995年,对松嫩平原苏打盐碱化湿地稻-鱼复合生态系统水体与土壤中的微生物数量及种群组成进行了初步研究。结果表明,稻-鱼湿地水体中异养细菌数量显著高于稻田湿地(P<0.05),季节变化特点为秋季>夏季>春季。异养细菌的数量分布与鱼产量有显著相关关系(r=0.879)。稻-鱼湿地系统的土壤微生物数量明显高于稻田湿地(P<0.01)。稻-鱼湿地和稻田湿地分别检测出10个和11个属的异养细菌。稻-鱼湿地系统1个生长期细菌的平均生物量为0.973g/m3,生产量为307.5 kg/hm2,所提供的鱼产力为7.0 kg/hm2。     

上海市PM2.5浓度变化特征及其气象因子分析

对上海市2012-2016年PM_2.5质量浓度、气象因素数据资料进行整理统计,通过定性分析与定量计算相结合的方法,揭示近年来上海市PM_2.5浓度的变化特征及其污染状况;采用相关性分析,从温度、气压、相对湿度、风向、风速和降水量等方面探讨了PM_2.5浓度与气象因素之间的关联性。结果表明：上海市近5 a空气质量主要为优和良,污染天数所占全年比例在减少。PM_2.5浓度呈现出夏季低,冬季高的季节特征,而且8月PM_2.5浓度最低,处于16~36 μg·m^-3;PM_2.5的日变化呈现出双峰双谷结构,浓度峰值出现于8~9时和19~20时,且后者浓度更高。气温、气压、相对湿度的阈值分别出现在9.8℃、1 021.6 hPa、83%,最大PM_2.5在阈值处出现显著变化;最大PM_2.5浓度与累积风速和降水量呈现出对数关系,并且东北风和东南风的累积风速达到350 m·s^-1以上时,PM_2.5浓度基本减少至35 μg·m^-3;降水量越大,PM_2.5浓度越低。     

Neumann stochastic finite element method for calculating temperature field of frozen soil based on random field theory

To study the effect of uncertain factors on the temperature field of frozen soil, we propose a method to calculate the spatial average variance from just the point variance based on the local average theory of random fields. We model the heat transfer coefficient and specific heat capacity as spatially random fields instead of traditional random variables. An analysis for calculating the random temperature field of seasonal frozen soil is suggested by the Neumann stochastic finite element method, and here we provide the computational formulae of mathematical expectation, variance and variable coefficient. As shown in the calculation flow chart, the stochastic finite element calculation program for solving the random temperature field, as compiled by Matrix Laboratory (MATLAB) software, can directly output the statistical results of the temperature field of frozen soil. An example is presented to demonstrate the random effects from random field parameters, and the feasibility of the proposed approach is proven by comparing these results with the results derived when the random parameters are only modeled as random variables. The results show that the Neumann stochastic finite element method can efficiently solve the problem of random temperature fields of frozen soil based on random field theory, and it can reduce the variability of calculation results when the random parameters are modeled as spatially random fields.     

中国湿地生态系统的外来入侵种研究

湿地是地球上各种生命形式高度聚集的生态体系之一,被称为“物种基因库”。湿地良好的环境条件不仅有利于本地种的生存,也利于外来物种的入侵。据现有资料统计,目前中国湿地生态系统中有外来入侵植物10种,隶属7个科;外来入侵动物53种,涉及哺乳类、鸟类、爬行类、两栖类、甲壳类、软体动物、鱼类和昆虫类。论述了这些入侵种的主要入侵途径,包括作为饲料、观赏、净化水质等目的人为有意引种,以及由非人为因素引起的入侵;同时还讨论了这些外来入侵种给湿地生态系统造成的不良影响,即导致物种多样性丧失、降低社会经济价值、破坏原有的生态系统和景观。