Experimental petrology constraints on the recycling of mafic cumulate: a focus on Cr-spinel from the Rum Eastern Layered Intrusion,Scotland

The ¹⁷⁶Lu–¹⁷⁶Hf and ¹⁴⁷Sm–¹⁴³Nd decay systems are routinely used to determine garnet (Grt)–whole-rock (WR) ages; however, the ¹⁷⁶Lu–¹⁷⁶Hf age of garnet is typically older than the ¹⁴⁷Sm–¹⁴³Nd age determined from the same aliquots. Here we present experimental data for Lu³⁺ and Hf⁴⁺ diffusion in garnet as functions of temperature, pressure and oxygen fugacity and show that the diffusivity of Hf⁴⁺ in almandine/spessartine garnet is significantly slower than that of Lu³⁺. The diffusive closure temperature (T _C) of Hf⁴⁺ is significantly higher than that of Nd³⁺, and although this property is partly responsible for the observed ¹⁷⁶Lu–¹⁷⁶Hf and ¹⁴⁷Sm–¹⁴³Nd Grt–WR age discrepancies, the difference between the T _C-s of Lu³⁺ and Hf⁴⁺ could lead to apparent Grt–WR ¹⁷⁶Lu–¹⁷⁶Hf ages that are skewed from the age of Hf⁴⁺ closure in garnet. In addition, the slow diffusivity of Hf⁴⁺ indicates that the bulk of metamorphic garnets retain a substantial fraction of prograde radiogenic ¹⁷⁶Hf throughout peak metamorphic conditions, a phenomenon that further complicates the interpretation of ¹⁷⁶Lu–¹⁷⁶Hf garnet ages and invalidates the use of analytical T _C expressions. We argue that the diffusion of trivalent rare earth elements in garnet becomes much faster when their concentration level falls below a few hundred ppm, as in the experiments of Tirone et al. (Geochim Cosmochim Acta 69: 2385–2398, 2005), and further argue that this low-concentration mechanism is appropriate for modeling the susceptibility of ¹⁴⁷Sm–¹⁴³Nd garnet ages to diffusive resetting.     

Preliminary Analysis of Photometric Variations of the Central Star of the Planetary Nebula Sh 2-71

We confirm the presence of regular UBV(RI)_C light variations of the object in the center of the planetary nebula Sh 2-71, with an improved period of P = 68.132 ± 0.005 days. The shapes and amplitudes of light curves, in particular colours, are briefly discussed.     

Transient brightenings of interconnecting loops

We study sudden brightenings of coronal loops that interconnect active regions. Such brightenings often occur within one or two days after the birth of a new interconnecting loop, as well as in some old interconnections. The brightenings of young loops are obviously associated with the emergence of new magnetic flux near their footpoints, whereas some enhancements of old loops may be triggered by slowly moving disturbances propagating from other centers of activity. A few loop brightenings are associated with flares, but the loop does not brighten in consequence of energy supply from the flare. Both the flare and the loop brightening are independent consequences of one common agent, presumably newly emerging flux.Temperatures in brightened loops are between 3 and 4 × 10⁶ K and densities are < 2 × 10⁹ cm^–3, probably < 5 × 10⁸ cm^–3 in some old loops. The top part of a loop is the site of the most intense brightening in the initial phase of a loop enhancement. The most frequent lifetime of these brightenings is 6 to 7 hr.Hale Observatories are operated jointly by the Carnegie Institution of Washington and the California Institute of Technology.     

Vibrational stability of double-star Roche model

The aim of the present paper will be to extend the methods of our previous investigations (Kopal, 1980, 1987) by employing the Clairaut coordinates (in which the radial component is identified with the total potential) to analyze the nature of small oscillations about the equilibrium form of Roche double-star model (identical, in fact, with zero-velocity surfaces of the restricted problem of three bodies).Linearized equations of this problem have been set up in Clairaut coordinates, and solved in a closed form. This solution turns out to be closely analogous to that obtained already for the rotating single-star Roche model, and discloses that (like in the preceding case) the terms secular in time appear already in the linear approximation. However, whether or not a retention of nonlinear terms in the equations of motion can regain secular stability of the respective configurations remains yet to be clarified by future investigations.     

Mapping Disastrous Natural Hazards Using Global Datasets

The increased interest for categorising countries at risk calls for an improved methodology allowing comparison of natural hazard impacts at a global level. A disaster is the intersection between a hazardous event, the elements at risk (population, infrastructures) and their vulnerability. In order to associate reported impacts with affected elements and socio-economic or geophysical contextual parameters, geographical location and extent of hazards is needed. The scope of this paper is to present improved automated procedures for a rapid mapping of large disastrous hazard events (floods, earthquakes, cyclones and volcanoes) using Geographical Information Systems (GIS) and available global datasets. Up to 82% of the events and 88% of the reported victims could be geo-referenced and the results highlight both the potentialities and limitations of the methods applied.     

Volatile Organic Compounds in the Po Basin. Part B: Biogenic VOCs

Measurements of volatile organic compounds (VOCs) were performed in the Po Basin, northern Italy in early summer 1998, summer 2002, and autumn 2003. During the three campaigns, trace gases and meteorological parameters were measured at a semi-rural station, around 35 km north of the city center of Milan. Bimodal diurnal cycles of isoprene with highest concentrations in the morning and evening were found and could be explained by the interaction of emissions, chemical reactions, and vertical mixing. The diurnal cycle could be qualitatively reproduced by a three-dimensional Eulerian model. The nighttime decay of isoprene could be attributed mostly to reactions with NO₃, while the decay of the isoprene oxidation products could not be explained with the considered chemical reactions. Methanol reached very high mixing ratios, up to 150 ppb. High concentrations with considerable variability occurred during nights with high relative humidities and low wind speeds. The origin of these nighttime methanol concentrations is most likely local and biogenic but the specific source could not be identified.     

Second Tesseral Harmonic Torque Due to the DynamicS of the Oceanic Surface Layer as Detected by TOPEX/POSEIDON Altimetry 1993-2000

Estimates of the second tesseral torque due to the variations in the radial space position of the mean ocean surface as monitored by TOPEX/POSEIDON altimeter system are derived. The magnitude of the studied torque may be compared to the tidal torque and to the tesseral torque caused by deformations due to the Earths rotation. However, such torque estimates strongly depend on the thickness of the ocean surface layer adopted in the spherical model of which the dynamics is believed to be responsible for the derived torque. The dependence on the thickness is discussed.