Timing of multiple hydrothermal events in the iron oxide–copper–gold deposits of the Southern Copper Belt,Carajás Province,Brazil

The Southern Copper Belt, Carajás Province, Brazil, hosts several iron oxide–copper–gold (IOCG) deposits, including Sossego, Cristalino, Alvo 118, Bacuri, Bacaba, Castanha, and Visconde. Mapping and U–Pb sensitive high-resolution ion microprobe (SHRIMP) IIe zircon geochronology allowed the characterization of the host rocks, situated within regional WNW–ESE shear zones. They encompass Mesoarchean (3.08–2.85 Ga) TTG orthogneiss, granites, and remains of greenstone belts, Neoarchean (ca. 2.74 Ga) granite, shallow-emplaced porphyries, and granophyric granite coeval with gabbro, and Paleoproterozoic (1.88 Ga) porphyry dykes. Extensive hydrothermal zones include albite–scapolite, biotite–scapolite–tourmaline–magnetite alteration, and proximal potassium feldspar, chlorite–epidote and chalcopyrite formation. U–Pb laser ablation multicollector inductively coupled mass spectrometry (LA-MC-ICP-MS) analysis of ore-related monazite and Re–Os NTIMS analysis of molybdenite suggest multiple Neoarchean (2.76 and 2.72–2.68 Ga) and Paleoproterozoic (2.06 Ga) hydrothermal events at the Bacaba and Bacuri deposits. These results, combined with available geochronological data from the literature, indicate recurrence of hydrothermal systems in the Southern Copper Belt, including 1.90–1.88-Ga ore formation in the Sossego–Curral ore bodies and the Alvo 118 deposit. Although early hydrothermal evolution at 2.76 Ga points to fluid migration coeval with the Carajás Basin formation, the main episode of IOCG genesis (2.72–2.68 Ga) is related to basin inversion coupled with Neoarchean (ca. 2.7 Ga) felsic magmatism. The data suggest that the IOCG deposits in the Southern Copper Belt and those in the Northern Copper Belt (2.57-Ga Salobo and Igarapé Bahia–Alemão deposits) do not share a common metallogenic evolution. Therefore, the association of all IOCG deposits of the Carajás Province with a single extensive hydrothermal system is precluded.     

Uniform fragility spectra for the performance‐based seismic design of structures considering variabilities in structural properties

This paper presents a new methodology based on structural performance to determine uniform fragility design spectra, i.e., spectra with the same probability of exceedance of a performance level for a given seismic intensity. The design spectra calculated with this methodology provide directly the lateral strength, in terms of yield‐ pseudo‐accelerations, associated with the rate of exceedance of a specific ductility characterizing the performance level for which the structures will be designed. This procedure involves the assessment of the seismic hazard using a large enough number of seismic records of several magnitudes; these records are simulated with an improved empirical Green function method. The statistics of the performance of a single degree of freedom system are obtained using Monte Carlo simulation considering the seismic demand, the fundamental period, and the strength of the structure as uncertain variables. With these results, the conditional probability that a structure exceeds a specific performance level is obtained. The authors consider that the proposed procedure is a significant improvement to others considered in the literature and a useful research tool for the further development of uniform fragility spectra that can be used for the performance‐based seismic design and retrofit of structures.     

Spectral classification of water masses under the influence of the Amazon River plume

The large amount of dissolved and particulate material discharged by the Amazon River into the Equatorial Atlantic Ocean cause distinct spectral response of its waters as compared to the nearby ocean waters. This paper shows the application of K-means clustering algorithm for classifying water masses in the region under the Amazon River plume influence according to their spectral behavior. Salinity and temperature data from 67 oceanographic stations were related to Sea-viewing Wide Field-of-view Sensor (SeaWiFS) remote sensing reflectances values and the following bio-optical products:(i) chlorophyll-a concentration, (ii) water attenuation coefficient and (iii) absorption coefficient for dissolved and detrital material. Four different water masses were identified such as:(1) oceanic water, (2) intermediate oceanic water, (3) intermediate river plume water and (4) Amazon River plume water. The spectral behavior of these water masses allowed concluding that the main active optical component of the waters in the region is the colored dissolved organic matter originated mostly from the Amazon River.     

Microphysical and chemical characteristics of cloud droplet residuals and interstitial particles in continental stratocumulus clouds

During June and July 2003 the Sources and Origins of Atmospheric Cloud Droplets experiment (SOACED) was carried out on a mountain-top site in central Sweden. The main objective of the experiment was to characterise the microphysical and chemical properties of cloud droplet residuals and interstitial aerosol particles in continental clouds and to understand the processes controlling cloud properties at this location.Interstitial and residual aerosol size distributions, cloud liquid water content and species- and size-resolved aerosol mass concentrations are the main variables employed to address questions pertaining to the cloud droplet number concentration and scavenging efficiency during a stratocumulus cloud event observed on July 28, 2003. In this cloud event, about 56% of the aerosol mass was associated with organic species, whilst SO₄ accounted for 23% and NH₄ for 14%. NO₃ and Cl made up about 7% of the total mass.The partitioning of the aerosol particles between cloud droplets and interstitial air has been studied in terms of their microphysical properties. The scavenging efficiency, defined as the fraction of particles activated into cloud elements compared to the total amount of particles, was investigated as a function of size. The scavenging efficiency curves displayed different shapes during the cloud event, from an S-shaped curve, with low scavenging efficiency in the Aitken mode and larger scavenging efficiency in the accumulation mode, to more unusual shapes where Aitken-mode particles were either solely activated or activated in addition to accumulation-mode particles.This study suggests that alterations of the aerosol chemical composition occurred during the measurement period, changing the hygroscopic nature of the CCN and decreasing their activation diameter. It is also hypothesized that entrainment of drier air aloft may have introduced inhomogeneities in the supersaturation field and modified the S-shaped scavenging curves.     

The effects of sample scheduling and sample numbers on estimates of the annual fluxes of suspended sediment in fluvial systems

Since the 1970s, there has been both continuing and growing interest in developing accurate estimates of the annual fluvial transport (fluxes and loads) of suspended sediment and sediment‐associated chemical constituents. This study provides an evaluation of the effects of manual sample numbers (from 4 to 12 year^?1) and sample scheduling (random‐based, calendar‐based and hydrology‐based) on the precision, bias and accuracy of annual suspended sediment flux estimates. The evaluation is based on data from selected US Geological Survey daily suspended sediment stations in the USA and covers basins ranging in area from just over 900 km² to nearly 2 million km² and annual suspended sediment fluxes ranging from about 4 Kt year^?1 to about 200 Mt year^?1. The results appear to indicate that there is a scale effect for random‐based and calendar‐based sampling schemes, with larger sample numbers required as basin size decreases. All the sampling schemes evaluated display some level of positive (overestimates) or negative (underestimates) bias. The study further indicates that hydrology‐based sampling schemes are likely to generate the most accurate annual suspended sediment flux estimates with the fewest number of samples, regardless of basin size. This type of scheme seems most appropriate when the determination of suspended sediment concentrations, sediment‐associated chemical concentrations, annual suspended sediment and annual suspended sediment‐associated chemical fluxes only represent a few of the parameters of interest in multidisciplinary, multiparameter monitoring programmes. The results are just as applicable to the calibration of autosamplers/suspended sediment surrogates currently used to measure/estimate suspended sediment concentrations and ultimately, annual suspended sediment fluxes, because manual samples are required to adjust the sample data/measurements generated by these techniques so that they provide depth‐integrated and cross‐sectionally representative data. Published 2014. This article is a U.S. Government work and is in the public domain in the USA.