Scanning electron microscopy,cathodoluminescence, and Raman spectroscopy of experimentally shock‐metamorphosed quartzite

Abstract— We studied unshocked and experimentally (at 12, 25, and 28 GPa, with 25, 100, 450, and 750°C pre‐shock temperatures) shock‐metamorphosed Hospital Hill quartzite from South Africa using cathodoluminescence (CL) images and spectroscopy and Raman spectroscopy to document systematic pressure or temperature‐related effects that could be used in shock barometry. In general, CL images of all samples show CL‐bright luminescent patchy areas and bands in otherwise nonluminescent quartz, as well as CL‐dark irregular fractures. Fluid inclusions appear dominant in CL images of the 25 GPa sample shocked at 750°C and of the 28 GPa sample shocked at 450°C. Only the optical image of our 28 GPa sample shocked at 25°C exhibits distinct planar deformation features (PDFs). Cathodoluminescence spectra of unshocked and experimentally shocked samples show broad bands in the near‐ultraviolet range and the visible light range at all shock stages, indicating the presence of defect centers on, e.g., SiO₄ groups. No systematic change in the appearance of the CL images was obvious, but the CL spectra do show changes between the shock stages. The Raman spectra are characteristic for quartz in the unshocked and 12 GPa samples. In the 25 and 28 GPa samples, broad bands indicate the presence of glassy SiO₂, while high‐pressure polymorphs are not detected. Apparently, some of the CL and Raman spectral properties can be used in shock barometry.     

Center to limb variation of penumbral Stokes V profiles

We investigated the horizontal and the vertical component of the Evershed flow (EF). To this end, we computed average Stokes V profiles for various velocity classes in penumbrae at different heliocentric angles. Our results show that for blueshifted profiles an additional lobe with the same polarity as the spot is present in the blue side of the average Stokes V profile. The amplitude of the additional lobe grows with increasing blueshift and with increasing heliocentric angle. For small redshifts, the profiles show an additional lobe with the opposite polarity as the spot on the red side of the average Stokes V profile. Even at disk center, the original polarity of the average Stokes V profile is reversed for strong redshifts. The transition between the different types of Stokes V profiles is continuous and indicates that not only the vertical, but also the horizontal EF is a magnetized stream of plasma in a magnetic background field (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

On the occurrence and origin of anthropogenic radionuclides found in a fragment of the Chelyabinsk (LL5) meteorite

A piece of the 2013 Chelyabinsk meteorite was investigated for its content of anthropogenic radionuclides. In addition to traces of cesium‐137 that had been previously reported for this particular fragment, we found an unusually high amount of strontium‐90, which indicates that the source of this contamination was the Kyshtym accident (1957). A high Sr‐90/Cs‐137 activity ratio is characteristic for Kyshtym‐derived contaminations. Based on the cesium‐137 content in the soil from the finding site, it is estimated that the fragment was contaminated with soil particles in the milligram range upon impact. Investigation of the soil revealed very unusual ferromagnetic characteristics and an iron‐rich chemical composition. Mössbauer spectroscopy indicated the presence of steel components in this soil, suggesting that the investigated meteorite fragment was found in an industrial dumping site rather than natural soil.     

Die Eisverhältnisse des Winters 1952/53 an den deutschen Küsten zwischen Ems und Trave

Zusammenfassung Der Winter 1952/53 war an den deutschen Küsten ein mä\iger Eiswinter. Innerhalb der Winter von 1896/97 bis 1952/53 nimmt er nach seinem Eisausma\ gerade den Zentralwert ein. Während des Winters war die méridionale Luftzirkulation vorherrschend, aber auch der Anteil der zonalen Zirkulation war nicht gering. Unter den Gro\wetterlagen überwogen das abgeschlossene Hoch über Mitteleuropa und die Hochdruckbrücke über Mitteleuropa. Der Winter hatte vier Eisperioden, von denen die zweite nur andeutungsweise auftrat, während die letzte das meiste Eis brachte.

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Ice conditions on the German coasts between the rivers Ems and Trave during the winter 1952/53

Summary The winter 1952/53 on the German coasts was a moderate ice winter. Because of the extent of its ice formation it occupies the central value among the winters from 1896/97 up to 1952/53. During this winter, meridional atmospheric circulation predominated, though the part that fell to zonal circulation was not inconsiderable either. Among the large scale weather situations, the closed high pressure area and the ridge of high pressure over Central Europe were preponderant. There were four periods of ice formation of which the second period was but very insignificant, while the greatest ice production was observed during the last cold period.

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Rapport sur les conditions des glaces sur les cÔtes allemandes entre l'Ems et le Trave pendant l'hiver 1952/53

Résumé L'hiver 1952/53 sur les cÔtes allemandes montrait un caractère modéré. Parmi les hivers de la période de 1896/97 jusqu'à 1952/53 il occupe justement la valeur centrale à cause de la grandeur de sa production des glaces. Pendant cet hiver, la circulation atmosphérique méridionale prédominait, mais la part de la circulation zonale n'était pas petite non plus. Parmi les situations météorologiques générales, l'aire concentrée de haute pression et la dorsale de haute pression au dessus de l'Europe Central étaient prépondérantes. Il y avait quatre périodes des glaces pendant cet hiver; au cours da la seconde période la production des glaces était insignifiicante tandis que la dernière période était caractérisée par la plus forte formation des glaces.

     

Combined influence of PDO and ENSO on northern Andean glaciers: a case study on the Cotopaxi ice-covered volcano,Ecuador

This paper describes the application of remote sensing in monitoring the fluctuations in one of the mountain glaciers in the Ecuadorean Andes during the past few decades using ASTER, EO-1 ALI, Landsat MSS, TM and ETM + images. Satellite images were used to calculate the snow line altitudes (SLAs) during the period 1979–2013. Cotopaxi ice covered volcano was studied as representative of Ecuadorian glaciers in the eastern cordillera. Precipitation and air temperature data from various gauging stations within the range of 30 km from the study site and monthly discharge and water level data from a gauging station were also utilized in this study. Anomalies in precipitation and temperature were found to be slightly different in the Cotopaxi region compared to nearby Antizana in the same cordillera and Chimborazo region in the western cordillera. An attempt to correlate the El Niño—southern oscillation phenomenon with the glacier fluctuations in Ecuadorian Andes was done successfully. Cold and warm regimes of Pacific Decadal Oscillation is also considered. The calculated glacier fluctuations obtained were similar to that performed on the nearby Antizana 15 in the eastern cordillera during 1995–2002. Precipitation and temperature anomalies were similar with Antizana 15. It is evident from the research that SLAs were highly fluctuated between the period of occurrence of El Niño and La Niña events. It is also seen that the glacier fluctuations show a negative mass balance trend in during the warm regime of Pacific Decadal Oscillation during the past three decades. Glaciated areas were advanced during the La Nina events in the cold regime of PDO during 1998–2002.     

High-P granulites of the Songshugou area (Qinling Orogen,east-central China): Petrography,phase relations,and U/Pb zircon geochronology

High-pressure (HP) granulites provide telling records of mineral reactions at upper mantle to lower crustal levels and key information on the fate of material in subduction systems. The latter especially applies when they abut eclogite and mantle dunite because such rock associations are crucial for understanding the incompletely known processes at the interface of converging plates. A continental arc, active c. 520–395 Ma ago, formed an enigmatic example of such a rock association in the Songshugou area, Qinling Orogen. To unravel the juxtaposition of the distinct rocks, this study combines petrography, phase equilibria modelling, conventional thermobarometry, and zircon U–Th–Pb–Ti–REE analysis. Two mafic HP granulites, which contain the mineral assemblages garnet–clinopyroxene–plagioclase–rutile–mesoperthite–quartz and garnet–clinopyroxene–plagioclase–rutile, experienced peak metamorphic conditions of ≤1.4 GPa, 860°C and ~1.3 GPa, ≥910°C, respectively. During decompression and cooling, at 489 ± 4 Ma, amphibole lamellae unmixed from a clinopyroxene solid solution and orthopyroxene in part replaced garnet. A felsic HP granulite shows equilibration of garnet, perthite, antiperthite, kyanite, quartz, and rutile at 810–860°C, ~1.2 GPa, sillimanite growth during decompression, and upper amphibolite facies cooling at 510 ± 4 Ma. Though the thermobarometric data are just within the methodological errors, the U/Pb zircon ages imply the HP granulites did not evolve coherently. The HP granulites either represent foundered lower arc crust or originated from subduction erosion because their geochemistry is indistinguishable from that of the hanging-wall plate. Published and new pressure–temperature–time–deformation paths converge at ~710°C, ~0.9 GPa, and ≲470 Ma, implying exhumation tectonics juxtaposed the HP granulites with a mélange of eclogite and mantle dunite at lower crustal levels. This study highlights that lower arc crust can comprise material of diverse evolution.     

Vacuum testing of the permeability of the excavation damaged zone

Summary The vacuum permeability method provides a new approach to assessment of permeability in the near-field of rock excavations. The method, which resembles leak testing of vacuum lines, is based on the measurement and interpretation of the pneumatic response to evacuation of a rock mass. As the induced drainage area is in order of meters, the method is particularly suitable on the scale of the excavation damaged zone. The data can be evaluated either analytically or numerically. The evaluation is similar to the approach used in the analysis of drill stem tests in gas wells. Experiments on large scale laboratory models corroborated the validity of the method and the evaluation procedure. Field tests were conducted at a wide range of geomechanical conditions. The collected data indicate that there are three characteristic types of permeability distribution in the excavation damaged zone.     

Tectonic significance of Triassic mafic rocks in the June Complex,Sanandaj–Sirjan zone,Iran

This study concentrates on the petrological and geochemical investigation of mafic rocks embedded within the voluminous Triassic June Complex of the central Sanandaj–Sirjan zone (Iran), which are crucial to reconstruct the geodynamics of the Neotethyan passive margin. The Triassic mafic rocks are alkaline to sub-alkaline basalts, containing 43.36–49.09 wt% SiO₂, 5.19–20.61 wt% MgO and 0.66–4.59 wt% total alkalis. Based on MgO concentrations, the mafic rocks fall into two groups: cumulates (Mg# = 51.61–58.94) and isotropic basaltic liquids (Mg# = 24.54–42.66). In all samples, the chondrite-normalized REE patterns show enrichment of light REEs with variable (La/Yb)_N ratios ranging from 2.48 to 9.00, which confirm their amalgamated OIB-like and E-MORB-like signatures. Enrichment in large-ion lithophile elements and depletion in high field strength elements (HFSE) relative to the primitive mantle further support this interpretation. No samples point to crustal contamination, all having undergone fractionation of olivine + clinopyroxene + plagioclase. Nevertheless, elemental data suggest that the substantial variations in (La/Sm)_PM and Zr/Nb ratios can be explained by variable degrees of partial melting rather than fractional crystallization from a common parental magma. The high (Nb/Yb)_PM ratio in the alkaline mafic rocks points to the mixing of magmas from enriched and depleted mantle sources. Abundant OIB alkaline basalts and rare E-MORB appear to be linked to the drifting stage on the northern passive margin of the Neotethys Ocean.     

Geomagnetic control of polar mesosphere summer echoes

Using observations with the ALOMAR SOUSY radar near Andenes (69.3°N, 16.0°E) from 1994 until 1997 polar mesosphere summer echoes (PMSE) have been investigated in dependence on geomagnetic K indices derived at the Auroral Observatory Tromsø (69.66°N, 18.94°E). During night-time and morning hours a significant correlation between the signal-to-noise ratio (SNR) of the radar results and the geomagnetic K indices could be detected with a maximum correlation near midnight. The correlation becomes markedly smaller in the afternoon and early evening hours with a minimum near 17 UT. This diurnal variation is in reasonable agreement with riometer absorption at Ivalo (68.55°N, 27.28°E) and can be explained by the diurnal variation of ionization due to precipitating high energetic particles. Therefore, a part of the diurnal PMSE variation is caused by this particle precipitation. The variability of the solar EUV variation, however, has no significant influence on the PMSE during the observation period.