Synthetic and natural chlorine-bearing apatite

Hydrothermal syntheses of chlor-hydroxyapatite have been carried out between 300 and 700° C at a constant pressure of 1000 bar. The substitution of OH for Cl varies as a function of the amount of added CaCl₂, temperature, and pH. In the main reaction the incorporation of Cl is negligible at 300° C but increases to over 40 mole percent Cl-apatite at 700° C. A simple X-ray method for determining the Cl/Cl+OH ratio has been developed and this is also extended to fluorine-bearing chlor-hydroxyapatites. A number of natural chlor-fluorhydroxyapatites are discussed in the light of the X-ray method and the result of the synthesis.     

Identification of Uranyl Minerals Using Oxygen K‐Edge X‐Ray Absorption Spectroscopy

Although most of the world's uranium exists as pitchblende or uraninite, this mineral can be weathered to a great variety of secondary uranium minerals, most containing the uranyl cation. Anthropogenic uranium compounds can also react in the environment, leading to spatial–chemical alterations that could be useful for nuclear forensics analyses. Soft X‐ray absorption spectroscopy (XAS) has the advantages of being non‐destructive, element‐specific and sensitive to electronic and physical structure. The soft X‐ray probe can also be focused to a spot size on the order of tens of nanometres, providing chemical information with high spatial resolution. However, before XAS can be applied at high spatial resolution, it is necessary to find spectroscopic signatures for a variety of uranium compounds in the soft X‐ray spectral region. To that end, we collected the near edge X‐ray absorption fine structure (NEXAFS) spectra of a variety of common uranyl‐bearing minerals, including uranyl carbonates, oxyhydroxides, phosphates and silicates. We find that uranyl compounds can be distinguished by class (carbonate, oxyhydroxide, phosphate or silicate) based on their oxygen K‐edge absorption spectra. This work establishes a database of reference spectra for future spatially resolved analyses. We proceed to show scanning X‐ray transmission microscopy (STXM) data from a schoepite particle in the presence of an unknown contaminant.     

Time to leave: an analysis of travel times during the approach and landfall of Hurricane Irma

Hurricane Irma caused widespread evacuation activity across Florida and some of its neighboring states in September of 2017. The researchers gathered estimated travel times from the Google Distance Matrix API over about a month to identify and analyze evacuation periods on roads in Florida, Georgia, and South Carolina during this time. Travel time data were mathematically adjusted to show more realistic estimations. Both sets of travel times were then graphed, with the assumption that elevated travel times prior to and during hurricane landfall were indicative of evacuation activity. The study generally corroborated the well-established daytime evacuation preference. However, not all evacuation periods followed the daytime travel preference, and at least one nighttime evacuation may have been caused by flooding. In another case, later elevated travel coincided with significant power loss. Finally, the Florida data suggest that most of the evacuation traffic departed before local jurisdictions’ recommended evacuation start times.

     

Temporal trends in abundance of fish in the tidal Delaware River

Water quality in the tidal Delaware River has improved dramatically over the last several decades. Areas near Philadelphia that were once anoxic and formed a pollution block to migratory fish passage now rarely experience dissolved oxygen concentrations less than 3 ppm. To assess whether these improvements in water quality led to increased abundance of juvenile fishes, data from a beach seine survey conducted annually since 1980 were examined. The number of species captured increased throughout the tidal river, but the increase was greatest in the areas downstream of Philadelphia, wheare water quality has improved the most. Abundance of juvenile striped bass and American shad, two important game species in the river whose migratory patterns make them susceptible to water quality problems, both increased more than, 1,000-fold during the last decade. Correlatations between the temporal abundance patterns of these species in the tidal Delaware River and in other East Coast systems were poor, suggesting that increases in their numbers were related more closely to improving conditions within the Delaware than to factors affecting coastal stocks.     

The effect of geometry and tidal forcing on hydrodynamics and net sediment transport in semi-enclosed tidal basins

A new depth-averaged exploratory model has been developed to investigate the hydrodynamics and the tidally averaged sediment transport in a semi-enclosed tidal basin. This model comprises the two-dimensional (2DH) dynamics in a tidal basin that consists of a channel of arbitrary length, flanked by tidal flats, in which the water motion is being driven by an asymmetric tidal forcing at the seaward side. The equations are discretized in space by means of the finite element method and solved in the frequency domain. In this study, the lateral variations of the tidal asymmetry and the tidally averaged sediment transport are analyzed, as well as their sensitivity to changes in basin geometry and external overtides. The Coriolis force is taken into account. It is found that the length of the tidal basin and, to a lesser extent, the tidal flat area and the convergence length determine the behaviour of the tidally averaged velocity and the overtides and consequently control the strength and the direction of the tidally averaged sediment transport. Furthermore, the externally prescribed overtides can have a major influence on tidal asymmetry in the basin, depending on their amplitude and phase. Finally, for sufficiently wide tidal basins, the Coriolis force generates significant lateral dynamics.     

A proposal for a new scenario framework to support research and assessment in different climate research communities

In this paper, we propose a scenario framework that could provide a scenario “thread” through the different climate research communities (climate change – vulnerability, impact, and adaptation - and mitigation) in order to support assessment of mitigation and adaptation strategies and climate impacts. The scenario framework is organized around a matrix with two main axes: radiative forcing levels and socio-economic conditions. The radiative forcing levels (and the associated climate signal) are described by the new Representative Concentration Pathways. The second axis, socio-economic developments comprises elements that affect the capacity for mitigation and adaptation, as well as the exposure to climate impacts. The proposed scenarios derived from this framework are limited in number, allow for comparison across various mitigation and adaptation levels, address a range of vulnerability characteristics, provide information across climate forcing and vulnerability states and span a full century time scale. Assessments based on the proposed scenario framework would strengthen cooperation between integrated-assessment modelers, climate modelers and vulnerability, impact and adaptation researchers, and most importantly, facilitate the development of more consistent and comparable research within and across these research communities.     

Wake Response to an Ocean-Feedback Mechanism: Madeira Island Case Study

We focus on an island wake episode that occurred in the Madeira Archipelago region of the north-east Atlantic at $32.5^{\circ }\mathrm{N}, 17^{\circ }\mathrm{W}$ . The Weather Research and Forecasting numerical model was used in a (one-way) downscaling mode, considering initial and boundary conditions from the European Centre for Medium-range Weather Forecasts system. The current literature emphasizes adiabatic effects on the dynamical aspects of atmospheric wakes. Changes in mountain height and consequently its relation to the atmospheric inversion layer should explain the shift in wake regimes, from a ‘strong-wake’ to ‘weak-wake’ scenario. Nevertheless, changes in sea-surface temperature variability in the lee of an island can induce similar regime shifts because of exposure to stronger solar radiation. Increase in evaporation contributes to the enhancement of convection and thus to the uplift of the stratified atmospheric layer above the critical height, with subsequent internal gravity wave activity.     

On using mixed-layer transport parameterizations with radiometric surface temperature for computing regional scale sensible heat flux

Recent mixed-layer formulations for computing large-scale surface energy fluxes under daytime convective conditions do not require the estimation of surface-layer parameters, such as the roughness lengths for momentum and heat. This greatly simplifies approaches using operational satellite measurements of surface temperature for computing the surface energy balance at regional scales because the surface roughness parameters are not well known for many landscapes. The utility of such mixed-layer formulations is tested using data from several recent multidisciplinary field experiments (HAPEX-MOBILHY, FIFE and Monsoon 90). The results indicate that specific mixed-layer formulations adequately simulate surface sensible heat fluxes in the grassland and shrubland sites. However, use of the original values of proposed empirical coefficients for the forested site yield poor results. This is probably due to the fact that the forested site has significantly different surface geometry and associated distribution of temperature among the surface components (especially the relative importance of soil background temperatures) compared to the other sites. Therefore, the relationship between aerodynamic and radiometric surface temperature may have greatly differed between the forested site and the other locations. However, differences in aerodynamic roughness between the experimental sites were not correlated with changes required in the values of the coefficients. Instead, a two-source model which makes the distinction between aerodynamic and radiative temperature is proposed, as a means to determine which surface properties significantly affect the magnitude of the mixed-layer coefficients.