Combining CLUE-S and SWAT models to forecast land use change and non-point source pollution impact at a watershed scale in Liaoning Province,China

Non-point source （NPS） pollution has become a major source of water pollution. A combination of models would provide the necessary direction and approaches designed to control NPS pollution through land use planning. In this study, NPS pollution load was simulated in urban planning, historic trends and ecological protection land use scenarios based on the Conversion of Land Use and its Effect at Small regional extent （CLUE-S） and Soil and Water Assessment Tool （SWAT） models applied to Hunhe-Taizi River Watershed, Liaoning Province, China. Total nitrogen （TN） and total phosphorus （TP） were chosen as NPS pollution indices. The results of models validation showed that CLUE-S and SWAT models were suitable in the study area. NPS pollution mainly came from dry farmland, paddy, rural and urban areas. The spatial distribution of TN and TP exhibited the same trend in 57 sub-catchments. The TN and TP had the highest NPS pollution load in the western and central plains, which concentrated the urban area and farm land. The NPS pollution load would increase in the urban planning and historic trends scenarios, and would be even higher in the urban planning scenario. How- ever, the NPS pollution load decreased in the ecological protection scenario. The differences observed in the three scenarios indicated that land use had a degree of impact on NPS pollution, which showed that scientific and ecologically sound construction could effec- tively reduce the NPS pollution load in a watershed. This study provides a scientific method for conducting NPS pollution research at the watershed scale, a scientific basis for non-point source pollution control, and a reference for related policy making.     

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The Interdecadal Changes of South Pacific Sea Surface Temperature in the Mid-1990s and Their Connections with ENSO简

The characteristic changes of South Pacific sea surface temperature anomalies （SSTAs） for the period January 1979 to December 2011, during which the 1990s Pacific pan-decadal variability （PDV） interdecadal regime shifts occurred, were examined. Empirical Orthogonal Function （EOF） analysis was applied to the monthly mean SSTA for two sub-periods： January 1979 to December 1994 （P 1） and January 1996 to December 2011 （P2）. Both the spatial and temporal features of the leading EOF mode for P1 and P2 showed a remarkable difference. The spatial structure of the leading EOF changed from a tripolar pattern for P 1 （EOF-P 1） to a dipole-like pattern for P2 （EOF-P2）. Besides, EOF-P 1 （EOF-P2） had significant spectral peaks at 4.6 yr （2.7 yr）. EOF-P2 not only had a closer association with E1 Nifio-Southern Oscillation （ENSO）, but also showed a faster response to ENSO than EOF-P1 based on their lead-lag relationships with ENSO. During the development of ENSO, the South Pacific SSTA associated with ENSO for both PI and P2 showed a significant eastward propagation. However, after the peak of ENSO, EOF-P1 showed a stronger persistence than EOF-P2, which still showed eastward propagation. The variability of the SSTA associated with the whole process of ENSO evolution during P1 and the SSTA associated with the development of ENSO during P2 support the existence of ocean-to-atmosphere forcing, but the SSTA associated with the decay of ENSO shows the phenomenon of atmosphere-to-ocean forcing.     

中国及邻区印支运动特征及其意义

通过概要论述印支运动在中国及邻区的表现特征,探讨了印支运动的主要成矿作用,指出印支运动首次使长期以来游离于全球主要大陆外的扬子、中朝、塔里木等小陆块拼合在一起,为新生代大型聚煤盆地的形成奠定了基础,也为燕山期和喜马拉雅山期二次大规模的对流地幔输入大陆事件奠定了重要基础,使之成为中国及邻区大陆上最重要的成矿时期。     

Zero-valent iron/persulfate(Fe0/PS) oxidation acetaminophen in water

Zero-valent iron (Fe⁰), as an alternative iron source, was evaluated to activate persulfate (PS) to degrade acetaminophen (APAP), a representative pharmaceutically active compound in water. Effects of key factors in the so-called Fe⁰/PS process, including Fe⁰ dosage, initial pH, temperatures and chelating agents, were studied. Under all the conditions tested, the APAP degradation followed a pseudo-first-order kinetics pattern. The degradation efficiency of APAP was highest when the Fe⁰ to PS molar ratio increased to 1:1, and the degradation rate constant and removal were 23.19 × 10^?3 min^?1 and 93.19 %, respectively. Comparing with Fe²⁺, Fe⁰ served as an alternative iron source that can gradually release Fe²⁺ into water, thereby consistently activating PS to produce sulfate radicals. The Fe⁰/PS system was effective in a broader pH range from 3 to 8.5. Heat could facilitate production of sulfate radicals and enhance the APAP degradation in the Fe⁰/PS system. High reaction temperature also improved the Fe²⁺/PS oxidation of APAP. Finally, sodium citrate (a chelating agent) at an appropriate concentration could improve the APAP degradation rate in the Fe²⁺/PS and Fe⁰/PS system. The optimal molar ratio of Fe⁰ to citrate depended on solution pH. Our results demonstrated that Fe⁰ was an alternative iron source to activate PS to degrade APAP in water.     

Coupling typhoon rainfall forecasting with overland-flow modeling for early warning of inundation

Taiwan suffers from an average of three or four typhoons annually, and the inundation caused by the heavy precipitation that is associated with typhoons frequently occurs in lowlands and floodplains. Potential inundation maps have been widely used as references to set up non-structural strategies for mitigating flood hazards. However, spatiotemporal rainfall distributions must be addressed to improve the accuracy of inundation forecasting for emergency response operations. This study presents a system for 24-h-ahead early warning of inundation, by coupling the forecasting of typhoon rainfall with the modeling of overland flow. A typhoon rainfall climatology model (TRCM) is introduced to forecast dynamically the spatiotemporal rainfall distribution based on typhoon tracks. The systematic scheme for early warning of inundation based on the spatiotemporal downscaling of rainfall and 2D overland-flow modeling yields not only the extent of inundation, but also the time to maximum inundation depth. The scheme is superior to traditional early warning method referring to the maximum extent and depth of inundation determined from conditional uniform rainfall. Analytical results show that coupling TRCM with an overland-flow model yields satisfactory inundation hydrographs for warning of the extent and peak time of inundation. This study also shows that the accuracy of forecasting spatiotemporal rainfall patterns determines the performance of inundation forecasting, which is critical to emergency response operations.     

Risk assessment of earth dam overtopping and its application research

The problem of dam safety is one of the most important research topics of water conservancy projects, and many researchers pay much attention to study the risk of earth dam overtopping. This paper synthesizes in the definition of risk the probabilities of dam failure and the corresponding losses, including the probability estimation, losses evaluation and criteria exploring risk approaches. Then, a comprehensive risk assessment system of dam flood overtopping is established, which is widely applicable. Gate failure, randomness of flood, initial water level and time-varying effects are incorporated in the failure probability model. Many complex factors are simplified in losses estimation. In addition, thresholds of various types of losses are proposed and are adapted to the national conditions. The methodology is applied to the Lianghekou hydropower station in China to illustrate the assessment process of flood overtopping risk and to evaluate its safe loophole with a view to the failure of spillway gates. Monte Carlo simulation and JC method programs are adopted to solve the model based on MATLAB tools and DELPHI. The results show that the losses pose significant impact on the risk assessment and should be considered in the assessment of risk. Probability calculation and loss estimation could be well combined with standards, providing a basis for risk management and decision-making.     

基于PLSR的典型沼泽湿地植物叶片性状与光谱模型构建——以三江国家级自然保护区为例

通过植物光学特性测量叶片性状是一种非破坏性的、长期的湿地动态监测方法。选择三江国家级自然保护区多种典型湿地植物为研究对象,探究植物性状与叶片光谱之间的联系。研究表明：叶片氮含量与光谱的模型构建效果最好,模型R²为0.61,均方根误差（RMSE）为2.3862;叶片含水量、叶片磷、可溶性糖、纤维素和木质素含量之和的模型一般,R²在0.38~0.55范围内,RMSE在0.0004~10.7019范围内;淀粉含量拟合效果较差, R²为0.29,RMSE为0.0106。光谱预测重要性的结果表明,可见光与近红外边缘范围内的光谱信息对于叶片含水量、叶片氮含量、叶片磷含量、单位叶面积质量、纤维素和木质素之和、可溶性糖和淀粉的预测具有最高的重要性。     

Gentrifying rural community development: A case study of Bama Panyang River Basin in Guangxi,China

Journal of Geographical Sciences - Rural gentrification is deeply characterized by institutional context and spatiotemporal heterogeneity. Based on a diachronic field investigation, this paper...     

Effects of meteorological and hydrogeological factors on gross recharge percentage at unconfined sandy aquifers with an equatorial climate

A thorough understanding of rainfall recharge processes and their controlling factors is essential for management of groundwater systems. This study investigates the effects of various meteorological and hydrogeological factors on the gross recharge percentages, the rainfall–recharge relationships and the recharge threshold values for unconfined sandy aquifers under an equatorial climate. Among the meteorological factors investigated, rainfall intensity was found to have the most significant impact on the gross recharge rate. The effects of potential evaporation rate, relative humidity and air temperature on the gross recharge percentage were significant when the vadose zone thickness is larger than 2·5 m. The recharge threshold values were found to depend strongly on the vadose zone thickness. The rainfall–recharge relationships could generally be well defined by a normal–log relationship. The rainfall–recharge relationships derived here are applicable to yield estimates of gross recharge percentages for unconfined sandy aquifers under an equatorial climate, using rainfall intensity and vadose zone thickness as input variables. In this study, a theory was developed and validated to provide physical explanations for the observations, based on the residence time of the percolated rainwater within the vadose zone. Among the soil hydraulic parameters tested, porosity and saturated hydraulic conductivity were found to have the most pronounced effects on the gross recharge percentage. Utilizing the sensitivity results and the theory derived, an approach was developed for extending the application of the derived rainfall–recharge relationships to other sand textures. The approach was found to be capable of producing rough and fast estimations of gross recharge percentage for other sand textures. Copyright © 2007 John Wiley & Sons, Ltd.