Fluorescence lifetime provides a third independent dimension of information for the resolution of totalluminescence spectra of multicomponent mixtures.The incorporation of this parameter into theexcitation-emission matrix(EEM)by the phase modulation technique results in a three-dimensionalexcitation-emission-frequency array (EEFA).Multicomponent analysis based on the three-dimensionalEEFA brings a qualitative change for the resolved spectra,i.e.individual spectra can be uniquely resolved,which is impossible with any two-dimensional analysis.In this paper we present a method for analyzingthe EEFA.We show mathematically that with the three-dimensional analysis of the EEFA individualspectra and lifetimes can be obtained.Our algorithm is developed in mathematical detail and isdemonstrated by its application to a two-component mixture. 相似文献
北碚,地处重庆主城西北部,背靠缙云山,嘉陵江环城而过,拥有宜人的自然风光和厚重的人文底蕴,历史上翁文灏、黄汲清、李春昱、侯光炯等科学巨匠都曾在此耕耘,特别是1937-1945年日本侵略中国期间,一大批东部地区科研学术机构和科学工作者内迁于此,得以延续中国科学文化的国脉和精华,北碚成为了抗日战争时大后方闪耀的科技文化中心,当时,在中国近代历史上建立最早、机构最完备、科研水平最高的中央地质调查所(The National Geological Survey of China)就是其中之一。本文追溯了中央地质调查所在抗战时期内迁北碚,在学术研究、科学救亡方面作出的巨大贡献,以供世人追忆和缅怀。 相似文献
Microbes live throughout the soil profile. Microbial communities in subsurface horizons are impacted by a saltwater–freshwater transition zone formed by seawater intrusion (SWI) in coastal regions. The main purpose of this study is to explore the changes in microbial communities within the soil profile because of SWI. The study characterizes the depth-dependent distributions of bacterial and archaeal communities through high-throughput sequencing of 16S rRNA gene amplicons by collecting surface soil and deep core samples at nine soil depths in Longkou City, China. The results showed that although microbial communities were considerably impacted by SWI in both horizontal and vertical domains, the extent of these effects was variable. The soil depth strongly influenced the microbial communities, and the microbial diversity and community structure were significantly different (p < 0.05) at various depths. Compared with SWI, soil depth was a greater influencing factor for microbial diversity and community structure. Furthermore, soil microbial community structure was closely related to the environmental conditions, among which the most significant environmental factors were soil depth, pH, organic carbon, and total nitrogen.