Physicochemical parameters of the melts participating in the formation of chromite ore hosted in the Klyuchevsky ultramafic massif,the Central Urals,Russia

The results of melt inclusion study are reported for chromites of the Klyuchevsky ultramafic massif, which is the most representative of all Ural ultramafic massifs localized beyond the Main Ural Fault Zone. The massif is composed of a dunite-harzburgite complex (tectonized mantle peridotite) and a dunite-wehrlite-clinopyroxenite-gabbro complex (layered portion of the ophiolitic section). The studied Kozlovsky chromite deposit is located in the southeastern part of the Klyuchevsky massif and hosted in serpentinized dunite as a series of lenticular bodies and layers up to 7–8 m thick largely composed of disseminated and locally developed massive ore. Melt inclusions have been detected in chromites of both ore types. The heated and then quenched into glass melt inclusions and host minerals were analyzed on a Camebax-Micro microprobe. The glasses of melt inclusions contain up to 1.06 wt % Na₂O + K₂O and correspond to melts of normal alkalinity. In SiO₂ content (49–56 wt %), they fit basalt and basaltic andesite. The melt inclusions are compared with those from chromites of the Nurali massif in the southern Urals and the Karashat massif in southern Tuva. The physicochemical parameters of magmatic systems related to the formation of disseminated and massive chromite ores of the Klyuchevsky massif are different. The former are characterized by a wider temperature interval (1185–1120°C) in comparison with massive chromite ore (1160–1140°C).     

Mineralogy and major-element geochemistry of the lower Permian Greta Seam,Sydney Basin,Australia

The mineralogy of the high-volatile bituminous coals and associated strata from the Greta seam, Sydney Basin, Australia, has been evaluated in this study. Although the seam is not immediately overlain by marine strata, percolation of marine water into the original peat bed is indicated by the petrological, mineralogical and geochemical characteristics, which resemble those of coals with marine roof strata. The upper and lower sections of the seam have contrasting mineralogy. Pyrite typically comprises 40 to 56 wt% of the mineral assemblage in the marine-influenced upper part of the seam section. The lower part contains much less pyrite (typically <5 wt%, organic-free basis), and also relatively abundant dawsonite (up to 14 wt%, organic-free basis). The minerals within most coal plies are largely of authigenic origin. These include pyrite, siderite, clay minerals (mainly kaolinite and Na-rich mixed-layer illite/smectite), and quartz, most of which have a relatively early, syngenetic origin. Minor Ti-bearing minerals, anatase or rutile, and phosphate minerals, fluorapatite and goyazite, were probably also formed during early diagenesis. Other minerals have features that indicate late-stage precipitation. These include abundant cleat- and fracture-filling dawsonite, which may be the result of reactions between earlier-precipitated kaolinite and Na₂CO₃- or NaHCO₃-bearing fluids. Minor albite may also be epigenetic, possibly precipitated from the same Ca–Al bearing fluids that formed the dawsonite. The most abundant detrital minerals in the Greta coals are quartz, poorly ordered kaolinite, illite and mixed-layer illite/smectite (I/S). These occur mainly in the floor, roof and other epiclastic horizons of the seam, reflecting periods of greater clastic influx into those parts of the original peat-forming environment. Detrital minerals are rare in the coals away from the epiclastic horizons, probably owing to almost complete sediment bypassing in the depositional system. Alternatively, any detrital minerals that were originally present may have been leached from the peat bed by diagenetic or post-diagenetic processes.     

Hydrosulfide/sulfide complexes of zinc to 250 °C and the thermodynamic properties of sphalerite

The solubility of synthetic ZnS_(cr) was measured at 25–250 °C and P = 150 bars as a function of pH in aqueous sulfide solutions (~ 0.015–0.15 m of total reduced sulfur). The solubility determinations were performed using a Ti flow-through hydrothermal reactor. The solubility of ZnS_(cr) was found to increase slowly with temperature over the whole pH range from 2 to ~ 10. The values of the Zn–S–HS complex stability constant, β, were determined for Zn(HS)₂⁰_(aq), Zn(HS)₃^?, Zn(HS)₄^2?, and ZnS(HS)^?. Based on the experimental values the Ryzhenko–Bryzgalin electrostatic model parameters for these stability constants were calculated, and the ZnS_(cr) solubility and the speciation of Zn in sulfide-containing hydrothermal solutions were evaluated. The most pronounced solubility increase, about 3 log units at m(S_total) = 0.1 for the temperatures from 25 to 250 °C, was found in acidic solutions (pH ~ 3 to 4) in the Zn(HS)₂⁰_(aq) predominance field. In weakly alkaline solutions, where Zn(HS)₃^? and Zn(HS)₄^2? are the dominant Zn–S–HS complexes, the ZnS_(cr) solubility increases by 1 log unit at the same conditions. It was found that ZnS(HS)^? and especially Zn(HS)₄^2? become less important in high temperature solutions. At 25 °C and m(S_total) = 0.1, these species dominate Zn speciation at pH > 7. At 100 °C and m(S_total) = 0.1, the maximum fraction of Zn(HS)₄^2? is only 20% of the total Zn concentration (i.e. at pH_t ~ 7.5), whereas at 350 °C and 3 <pH_t <10, the fraction of Zn(HS)₄^2? and ZnS(HS)^? is less than 0.05% and 2.5% respectively, of the total Zn concentration and Zn(HS)₂⁰ and Zn(HS)₃^? predominate. The measured equilibrium formation constants were combined with the literature data on the stability of Zn–Cl complexes in order to evaluate the concentration and speciation of Zn in chloride solutions. It was found that at acidic pH, and in more saline fluids having total chloride > 0.05 m, Zn–Cl complexes are responsible for hydrothermal Zn transport with no significant contribution of Zn–S–HS complexes. The hydrosulfide/sulfide complexes will play a more important role in lower salinity (< 0.05 m chloride) hydrothermal solutions which are characteristic of many epithermal ore depositing environments. The value of Δ_fG° (β-ZnS_(cr)) = ? 198.6 ± 0.2 kJ/mol at 25 °C was determined via solubility measurements of natural low-iron Santander (Spain) sphalerite.     

Turbulent flows over mountainous terrain modelled by the Reynolds equations

A numerical model based upon fundamental principles, a standard (k, ) turbulence closure and a finite element integration technique, is applied to separated flows over hills. Predictions are compared to experimental data from a wind tunnel. Although few-equation turbulence closures have been shown to have obvious deficiencies with respect to comparable flows, the model predicts remarkably accurately, without coefficient adjustments of any kind. Even the turbulent intensity is predicted quite realistically.     

Forced Waves in a Bounded Basin with One Thermocline

Within the framework of the linear theory taking into account the action of the Coriolis force, we study waves induced in a continuously stratified fluid with one thermocline by periodic variations of pressure on the free surface. The fluid fills a bounded basin of constant depth. We establish the dependences of the wave amplitudes and wave velocities on the period of disturbing pressure. The sequence of transformations of generated waves from the barotropic character of motion to baroclinic depending on changes in the period of disturbing pressure is studied in detail.     

Meso-beta scale numerical simulations of terrain drag-induced along-stream circulations. Part II: Concentration of potential vorticity within dryline bulges

Summary Hydrostatic and nonhydrostatic simulation models are employed to study the intensification of a terrain drag-induced dryline. The study develops a multi-stage theory for the evolution of the dryline including the concentration of potential vorticity accompanying meso-gamma scale dryline bulges.The numerical simulations indicate three fundamental stages of dryline intensification all of which are either directly or indirectly a result of the terrain-drag on the mid/upper-tropospheric jet stream by the Front Range of the Colorado Rocky Mountains. The first stage involves the downward momentum flux accompanying a large amplitude hydrostatic mountain wave which induces a downslope windstorm along the lee slopes. The surge of momentum (i.e., the dry, warm air associated with the downslope windstorm) propagates down the leeslope and modifies an existing weak dryline boundary. As the downslope windstorm initiates an undular bore along the lee slopes, the high momentum gradient which propagates downstream accompanying the bore, as well as the strong lower tropospheric sinking motions ahead of the bore, contract the scale of the surface moisture boundary between the dry air from above the leeslope and the moist air over the High Plains. This process further strengthens the dryline.The second stage involves the coupling of the terrain drag-induced along-stream ageostrophic front within the midtroposphere to the boundary layer through a thermally-indirect circulation. As the along-stream ageostrophic circulation intensifies within the middle troposphere down-stream from the mountain wave, sinking air parcels originating above 40 kPa descend to below 60 kPa over the High Plains where surface pressures are, only 85 kPa. These descending air parcels within the upstream branch of the along-stream ageostrophic thermally-indirect circulation contain high values of momentum and very low dewpoint values. As the planetary boundary layer (PBL) deepens due to surface warming during the morning hours, momentum and dry air from the midtropospheric along-stream ageostrophic front are entrained into the PBL. This process amplifies the bore-induced hydrostatic dryline bulge via low-level ageostrophic confluence.Finally, regions of low Richardson number (arising from strong vertical shears) within the amplifying midtropospheric along-stream ageostrophic thermally-indirect circulation become preferred regions for the development of non-hydrostatic evanescent internal gravity waves. These waves are embedded within the hydrostatic along-stream front above the low-level dryline and are accomapanied by very significant values of vertical momentum flux which act to focus the meso-gamma scale structure of the dryline into smaller scale bulges where low-level winds and vorticities are very high. This meso-gamma scale process follows the hydrostatic tilting and vortex tube stretching which creates meso-beta scale maxima of mid-lower tropospheric vorticity. The turbulent momentum fluxes accompanying wavebreaking within the nonhydrostatic dryline bulge create very large (i.e., stratospheric values of) potential vorticity near 70 kPa due to the nonconservation of potential vorticity on isentropic surfaces.With 30 Figures     

LA-ICP-MS heavy metal analyses of fish scales from sediments of the Oxbow Lake Certak of the Morava River (Czech Republic)

Heavy metal concentrations were studied in the scales of recent and subrecent (2–25 years old) fish buried in the oxbow lake sediments of the Morava River. The samples were taken from two cores up to 4-m deep and analysed using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and an electron microprobe analysis (EMPA). The results were compared with heavy metal concentrations of bulk samples of the embedding sediment. The study has revealed substantial differences in heavy metal contents existing between the recent and subrecent fish scales documenting an extreme rapidity of the diagenesis/fossilization processes. The most apparent features of the early fossilization include the quick loss of the mucous envelope, collagen and magnesium and an enormous increase in the heavy metal concentrations in particular iron, which is connected with a colour change. The variations in heavy metal contents in fish scales within a sample are attributed to variations in heavy metal content in the environment and variable amounts of organic matter in the embedding sediment. In contrast to the contamination of the embedding sediment, no general increase in heavy metal concentrations in fish scales was observed down to the cores. It is inferred that the rapid sorption stabilizes the biologic hydroxyapatite of the fish scales, which thus rapidly attain a thermodynamic equilibrium with the embedding water-saturated sediment. The results show that the processes of sorption, fossilization and stabilization of hydroxyapatite can act very quickly over a time scale of several years and represent thus a great advantage in the preservation of the original signals of the ancient environments.     

Petrography, Mineralogy, and Metamorphic Evolution of an Eclogite from the Island of Margarita, Venezuela

The petrography and mineralogy of a coarse-grained eclogitelens from the La Rinconada Group of northeastern Margarita Island,Venezuela, reflect the metamorphic evolution of the rock. Omphacite+ garnet + paragonite + barroisite + epidote + rutile/ilmenite+ quartz + pyrite + apatite represents the stable assemblagemarking the culmination of a single metamorphic episode. Electronmicroprobe analyses of the major minerals indicate an affinitywith Smulikowski's low-temperature ‘ophiolitic’type. Schreinemakers relationships among the mineral phasesallow the observed complex reaction relations to be explainedas late-stage depressurization effects. The crystallizationof eclogite instead of amphibole gneiss, as in the chemicallyidentical country rock, must be related to a lower _H2O in theaqueous fluid phase attending metamorphism. It is inferred frommineralogical stability data that the ‘culmination assemblage’was stable at approximately 450–525 °C and 11.5–13.5kb load pressure, and that depressurization to less than 5 kboccurred at slightly increasing metamorphic temperatures.