Simple determination of dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) using solid-phase microextraction and gas chromatography-mass spectrometry

Solid-phase microextraction (SPME) is a simple, sensitive and less destructive method for the determination of dimethylsulfide (DMS) in seawater. Combined with detection by gas chromatography-mass spectrometry (GC-MS), the method had sufficient sensitivity (minimum detectable concentration of DMS was 0.05 nM), and practical levels of reproducibility (relative standard deviation ≤7%) and linearity (r ² > 0.995) over a wide concentration range (0.5 to 910 nM). The protocol developed was applied to a Sagami Bay water sample to determine concentrations of DMS and DMSP, and in situ DMSP-lyase activity.     

Eddy Shedding from the Kuroshio Bend at Luzon Strait

TOPEX/POSEDIENT-ERS satellite altimeter data along with the mean state from the Parallel Ocean Climate Model result have been used to investigate the variation of Kuroshio intrusion and eddy shedding at Luzon Strait during 1992–2001. The Kuroshio penetrates into the South China Sea and forms a bend. The Kuroshio bend varies with time, periodically shedding anticyclonic eddies. Criteria of eddy shedding are identified: 1) When the shedding event occurs, there are usually two centers of high Sea Surface Height (SSH) together with negative geostrophic vorticity in the Kuroshio Bend (KB) area. 2) Between the two centers of high SSH there usually exists positive geostrophic vorticity. These criteria have been used to determine the eddy shedding times and locations. The most frequent eddy shedding intervals are 70, 80 and 90 days. In both the winter and summer monsoon period, the most frequent locations are 119.5°E and 120°E, which means that the seasonal variation of eddy shedding location is unclear.     

Significance of pteropods in deciphering the late Quaternary sea-level history along the southwestern Indian shelf

The paper evaluates the usefulness of pteropods in palaeobathymetric synthesis along the southwestern continental shelf of India. Core samples collected from the shelf off north Kerala (SW coast of India) were studied for faunal assemblages (pteropods and foraminifers), calcium carbonate contents and lithological characteristics. A fundamental precept for considering any organism as a bathometer is that it should be highly sensitive to changing water depths. To ascertain this, the bathymetric distribution patterns of modern pteropods as well as planktonic and benthic foraminifers were recorded in core-top samples. The results reveal that certain pteropod species (Limacina inflata, Creseis acicula, Creseis virgula, and Creseis chierchiae) are highly depth sensitive. The response of these species to depth changes was assessed in terms of the L. inflata and Creseis spp. abundance ratio. A model for the relationship between water depths and the L. inflata/Creseis spp. ratio is proposed for the southwestern shelf of India. Variations of benthic/planktonic foraminifers (BF/PF) and pteropods/planktonic foraminifers (Pt/PF) in the modern sediments were also found to be depth controlled. Two sediment cores, representing the last 36,000 and 23,000 years, were collected to investigate past sea-level changes. These cores comprised two distinct lithological units, the upper unit corresponding to the Holocene, and the lower unit to the last glacial period. The L. inflata/Creseis spp. model was successfully applied to the fossil record for reconstructing the palaeobathymetry of the shelf study locations. Down-core variations in the BF/PF and Pt/PF ratios support these inferred sea-level changes. Major periods of sea-level oscillations were also found to have a strong influence on the calcium carbonate distribution. For both core sites, the palaeobathymetric curves reflect consistency in terms of changing sea level. The results suggest that the sea level stood around 100 m below the present mean sea level during the last glacial maximum. A rapid rise in sea level was documented between 15 and 10 ka B.P. The sea-level rise has been slower since 7 ka B.P.     

Adaptive optimal control of an autonomous underwater vehicle in the dive plane using dorsal fins

In this paper, adaptive control of low speed bio-robotic autonomous underwater vehicles (BAUVs) in the dive plane using dorsal fins is considered. It is assumed that the model parameters are completely unknown and only the depth of the vehicle is measured for feedback. Two dorsal fins are mounted in the horizontal plane on either side of the BAUV. The normal force produced by the fins, when cambered, is used for the maneuvering. The BAUV model considered here is non-minimum phase. An indirect adaptive control system is designed for the depth control using the dorsal fins. The control system consists of a gradient based identifier for online parameter estimation, an observer for state estimation, and an optimal controller. Simulation results are presented which show that the adaptive control system accomplishes precise depth control of the BAUV using dorsal fins in spite of large uncertainties in the system parameters.     

Geodynamics of the deep sedimentary basin of the Caspian Sea region: paragenetic correlation of seismicity and mud volcanism

In this paper we analyze seismic regime and earthquake depth distribution and correlation of seismicity and mud volcanism in the Azerbaijan and the Caspian Sea region. For the present region we have calculated accurate source locations, seismic activity, earthquake repetition and released earthquake energy parameters. It is shown that the active tectonic processes in the region are concentrated within the thick sedimentary cover that we consider as a general source of contemporary stress and a main structural element responsible for the origin of regional earthquakes. The correlation of seismicity and mud volcanism is of paragenetic character.     

Comparison of TOPEX/POSEIDON Altimeter Derived Wind Speed and Wave Parameters with Ocean Buoy Data in the North Indian Ocean

Results of comparison exercises carried out between the state-of-the-art TOPEX/POSEIDON altimeter-derived ocean surface wind speed and ocean wave parameters (significant wave height and wave period) and those measured by a set of ocean data buoys in the North Indian Ocean are presented in this article. Altimeter-derived significant wave height values exhibited rms deviation as small as ±0.3 m, and surface wind speed of ±1.6 m/s. These results are found consistent with those found for the Pacific Ocean. For estimation of ocean wave period, the spectral moments-based semiempirical approach, earlier applied on GEOSAT data, was extended to TOPEX/POSEIDON. For this purpose, distributions of first four years of TOPEX/POSEIDON altimeter data and climatology over the North Indian Ocean were analyzed and a new set of coefficients generated for estimation of wave period. It is shown that wave periods thus estimated from TOPEX/POSEIDON data (for the subsequent two years), when compared with independent data set of ocean data buoys deployed in the North Indian Ocean, exhibit improved accuracy (rms ~ ±1.4 nos) over those determined earlier with GEOSAT data.     

Some vibrational bands of theC-X system of V0 molecules in the umbral spectrum of the Sun

Vibrational transition probabilities namely Franck-Condon factors and r-centroids have been evaluated using an approximate analytical method for theC-X system of V0. Morse potential energy curves forX _{4 –} andC _{4 –} states of V0 have been constructed using the latest spectroscopic data. The value of r-centroids for the band have been found to increase linearly with the corresponding wavelength. We show results for new transition and ten new bands in the umbral spectrum of the Sun.     

Hall effects on heat and mass transfer flow with variable suction and heat generation

A study of the combined buoyancy effects of thermal and mass diffusion on MHD convection flow in the presence of Hall currents with variable suction and heat generation has been carried out. Analytical expressions for the velocity and the temperature of the fluid are given. The effects of Hall currents, parameterm, and heat source parameter on the velocity are discussed.     

Bianchi type-II,VIII, and IX in certain new theories of gravitation

Bianchi type-II, VIII, and IX models have been investigated in scalar-tensor theories developed by Saez (1985), Saez and Ballester (1985), and Lau and Prokhovnik (1986) (under the assumption of a certain relationship between the cosmological term and the scalar field ). The dynamical behaviour of these models has been studied.     

Distribution analysis of salt affected soils under canal and non-canal command area in a part of Etah district,U. P., using remote sensing technique

A World Bank-aided project on sodic land reclamation in Uttar Pradesh is being executed by U.P. Bhumi Sudhar Nigam, Lucknow, and Remote Sensing Applications Centre, U.P., Lucknow has the responsibility of sodic land mapping for the execution of land reclamation programme at the cadastral level. Sodic lands are mainly concentrated in the Gangetic alluvial plains but the problem of sodicity is particularly acute in the canal-irrigated areas. A study of the distribution pattern of sodic lands in canal and noncanal command areas in a reclamation site (covering 60 villages out of which sodic lands were mapped in 51 villages) of Etah district in Uttar Pradesh, indicates that 18.39 per cent area of the canal command villages was barren sodic which was 13.41 per cent of the total geographical area of the site (15417 ha), however, 11.69 per cent area was recorded to be barren sodic in the non-canal command villages which was only 3.16 per cent of the geographical area of the site. The results of soil chemical analysis indicate that barren sodic lands of canal command area are saline-sodic with higher concentration of soluble salts (pH₂ >8.5, EC₂ >4 dSm⁻¹), however, those of non-canal command area are sodic (pH₂ >8.5, EC₂ <4 dSm⁻¹). The post-monsoon ground level in the canal-irrigated areas was in the critical and semicritical zone (< 3.0 mbgl) whereas it was well below the semi-critical zone in the non-canal command area, which indicates that the high ground water level is a major factor to higher the area under sodicity.