Atmospheric River Signatures in Radiosonde Profiles and Reanalyses at the Dronning Maud Land Coast,East Antarctica

Atmospheric rivers(ARs)are an important component of the hydrological cycle linking moisture sources in lower latitudes to the Antarctic surface mass balance.We investigate AR signatures in the atmospheric vertical profiles at the Dronning Maud Land coast,East Antarctica,using regular and extra radiosonde measurements conducted during the Year of Polar Prediction Special Observing Period November 2018 to February 2019.Prominent AR events affecting the locations of Neumayer and Syowa cause a strong increase in specific humidity extending through the mid-troposphere and a strong low-level jet(LLJ).At Neumayer,the peak in the moisture inversion(up to 4 g kg^?1)is observed between 800 and 900 hPa,while the LLJ(up to 32 m s^?1)is concentrated below 900 hPa.At Syowa the increase in humidity is less pronounced and peaks near the surface,while there is a substantial increase in wind speed(up to 40 m s?1)between 825 and 925 hPa.Moisture transport(MT)within the vertical profile during the ARs attains a maximum of 100 g kg?1 m s?1 at both locations,and is captured by both ERA-Interim and ERA5 reanalysis data at Neumayer,but is strongly underestimated at Syowa.Composites of the enhanced MT events during 2009?19 show that these events represent an extreme state of the lower-tropospheric profile compared to its median values with respect to temperature,humidity,wind speed and,consequently,MT.High temporal-and vertical-resolution radiosonde observations are important for understanding the contribution of these rare events to the total MT towards Antarctica and improving their representation in models.     

Computational Fluid Dynamical Modelling of Concentration Fluctuations in an Idealized Urban Area

Turbulent mixing induces variability in concentration that is important in many applications, such as reactive plumes, risk assessments or odour impact analyses (when the effects can have time scales on the order of a second). In urban canopies, the variability may be modified by the presence of buildings. Our purpose is to study concentration fluctuation variance in built-up areas using an Eulerian approach. We performed numerical simulations with the computational fluid dynamics model Mercure_Saturne, which is a three-dimensional model adapted to atmospheric flow and pollutant dispersion. We use a k − ϵ turbulence closure and predict the concentration variance with a transport equation model. The model performance is evaluated with the near-full scale experiment MUST (Mock Urban Setting Test), a field experiment conducted in Utah’s West Desert Test Center. The modelled root-mean-square of the concentration fluctuations is compared to measurements for 20 of the MUST trials. The model shows good agreement with the measurements, with the fraction of predictions within a factor of two of observations of 60.1%, with better results for horizontal lines of detectors than for the detectors on vertical masts (with fractions of predictions within a factor of two of observations of respectively 66.4% and 52.6%). The influence of different parameters on the fluctuation variance is also studied and we show the importance of taking into account the stability of the stratification when modelling the turbulent kinetic energy.     

Nickeliferous pyrite tracks pervasive hydrothermal alteration in Martian regolith breccia: A study in NWA 7533

Martian regolith breccia NWA 7533 (and the seven paired samples) is unique among Martian meteorites in showing accessory pyrite (up to 1% by weight). Pyrite is a late mineral, crystallized after the final assembly of the breccia. It is present in all of the lithologies, i.e., the fine‐grained matrix (ICM), clast‐laden impact melt rocks (CLIMR), melt spherules, microbasalts, lithic clasts, and mineral clasts, all lacking magmatic sulfides due to degassing. Pyrite crystals show combinations of cubes, truncated cubes, and octahedra. Polycrystalline clusters can reach 200 μm in maximum dimensions. Regardless of their shape, pyrite crystals display evidence of very weak shock metamorphism such as planar features, fracture networks, and disruption into subgrains. The late fracture systems acted as preferential pathways for partial replacement of pyrite by iron oxyhydroxides interpreted as resulting from hot desert terrestrial alteration. The distribution and shape of pyrite crystals argue for growth at moderate to low growth rate from just‐saturated near neutral (6 < pH<10), H₂S‐HS‐rich fluids at minimum log fO₂ of >FMQ + 2 log units. It is inferred from the maximum Ni contents (4.5 wt%) that pyrite started crystallizing at 400–500 °C, during or shortly after a short‐duration, relatively low temperature, thermal event that lithified and sintered the regolith breccias, 1.4 Ga ago as deduced from disturbance in several isotope systematics.     

Determination of Ruthenium,Palladium and Iridium in 27 In ternational Reference Silicate and I Ron-Formation Rocks,Ores and Related Materials By Isotope Dilution Inductively-Coupled Plasma Mass Spectrometry*

Ruthenium, palladium and iridium have been determined in 27 international reference rocks, ores and related materials by inductively-coupled plasma mass spectrometry using isotope dilution and sample introduction by solution nebulization and electrothermal vaporization, after chemical separation by co-precipitation with tellurium. The accuracy of the procedure is discussed by comparison of the results obtained with synthetic solutions and standard samples.     

Allowances for evolving coastal flood risk under uncertain local sea-level rise

Estimates of future flood hazards made under the assumption of stationary mean sea level are biased low due to sea-level rise (SLR). However, adjustments to flood return levels made assuming fixed increases of sea level are also inadequate when applied to sea level that is rising over time at an uncertain rate. SLR allowances—the height adjustment from historic flood levels that maintain under uncertainty the annual expected probability of flooding—are typically estimated independently of individual decision-makers’ preferences, such as time horizon, risk tolerance, and confidence in SLR projections. We provide a framework of SLR allowances that employs complete probability distributions of local SLR and a range of user-defined flood risk management preferences. Given non-stationary and uncertain sea-level rise, these metrics provide estimates of flood protection heights and offsets for different planning horizons in coastal areas. We illustrate the calculation of various allowance types for a set of long-duration tide gauges along U.S. coastlines.     

A story of “communities”: boundaries,geographical composition and social coherence in a forest conservation project,Northern Cambodia

Explicit notions of “communities”, as key actors in conservation and development projects across the Global South, are common. Narratives about “indigenous people” or “forest-dependent communities” in forest conservation programmes prevail, portraying a picture of “communities” as homogeneous and harmonious entities. In this study, we unfold “communities” as a construct with an empirical example of a community-based forest protection project, Northern Cambodia. Based on qualitative interviews, field observations and document analysis, we examine the “community” construct in terms of establishment of boundaries, geographical composition and social coherence. We not only find that the establishment of forest “community” boundaries are dominated by powerful external actors rather than the “community members” themselves, but that the spatial composition of “communities” is complex, and affects the ability of local people to benefit from the project. We also find that the studied “communities” show low levels of social coherence and mainly consist of migrant farmers, as opposed to common policy narratives. Taking these inconsistencies into account, we discuss implications of constructing “communities” for the success of forest conservation projects, and argue in favour of more discursive and political analyses to better understand, acknowledge and adapt to existing and changing conditions in present and prospective project locations.     

Mineral inclusions in diamonds from the River Ranch kimberlite, Zimbabwe

More than 99% of mineral inclusions in diamonds from the River Ranch pipe in the Late Archean Limpopo Mobile Belt (Zimbabwe), are phases of harzburgitic paragenesis, namely olivine (Fo_92–93), orthopyroxene (Mg# = 93), G10 garnets and chromites. The diamond inclusion (DI) chemistry demonstrates a limited overlap with River Ranch kimberlite macrocrysts: the DI garnets are more Ca-undersaturated, and DI spinel and garnet are more Mg-rich. Most River Ranch diamond inclusions were equilibrated at T = 1080–1320 °C, P = 47–61 kbar, and f _O2 between IW and WM buffers. The P/T profile beneath the Limpopo Mobile Belt (LMB) is consistent with a paleo-heat flow of 41–42 mW/m², similar to calculations for Roberts Victor, but hotter than for the Finsch, Kimberley, Koffiefontein and Premier Mines. This is ascribed to the younger tectonothermal age of the LMB and its proximity to Late Archean oceans. Like diamond inclusions from all other kimberlites studied, the River Ranch DI have a lithospheric affinity and therefore indicate that an ancient, chemically depleted, thick (at least 200 km) mantle root existed beneath the Limpopo Mobile Belt 530–540 Ma ago. The mantle root might have developed beneath the continental Central Zone of the LMB as early as the Archean, and could be alien to the overthrust allochthonous sheet of the Limpopo Belt. Oxygen fugacity estimates for diamond inclusions at River Ranch are similar to other diamondiferous harzburgites beneath the Kaapvaal craton, indicating that the Kaapvaal mantle as a whole was well buffered and homogeneous with respect to f _O2 at the time of peridotitic diamond crystallization. Received: 11 January 1995 / Accepted: 10 June 1997     

Numerical simulations of pollutant dispersion in an idealized urban area,for different meteorological conditions

In order to estimate the impacts of buildings on air pollution dispersion, numerical simulations are performed over an idealized urban area, modelled as regular rows of large rectangular obstacles. The simulations are evaluated with the results of the Mock Urban Setting Test (MUST), which is a near full-scale experiment conducted in Utah’s West Desert area: it consists of releases of a neutral gas in a field of regularly spaced shipping containers. The numerical simulations are performed with the model Mercure_Saturne, which is a three-dimensional computational fluid dynamics code adapted to atmospheric flow and dispersion simulations. It resolves complex geometries and uses, in this study, a k–∈ closure for the turbulence model. Sensitivity studies focus on how to prescribe the inflow conditions for turbulent kinetic energy. Furthermore, different sets of coefficients available in the literature for the k–∈ closure model are tested. Twenty MUST trials with different meteorological conditions are simulated and detailed analyses are performed for both the dynamical variables and average concentration. Our results show overall good agreement according to statistical comparison parameters, with a fraction of predictions for average concentration within a factor of two of observations of 67.1%. The set of simulations offers several inflow wind directions and allows us to emphasize the impact of elongated buildings, which create a deflection of the plume centerline relative to the upstream wind direction.     

Corals as speaking stones

Corals are animals living in shallow seas (where they may form coral reefs) or in the deep sea. Because they fossilize well, these stones inform us in detail about the geological past; not only about the history of the Earth as a whole (rotation, tectonics, sea-level changes), but also about past local environmental conditions in the sea. Joint research of marine biology and marine geology can therefore solve many questions about our changing world, and can be used to discover what factors cause deterioration of living coral reefs.     

Olivine in the Udachnaya-East Kimberlite (Yakutia, Russia): Types, Compositions and Origins

Olivine is the principal mineral of kimberlite magmas, and isthe main contributor to the ultramafic composition of kimberliterocks. Olivine is partly or completely altered in common kimberlites,and thus unavailable for studies of the origin and evolutionof kimberlite magmas. The masking effects of alteration, commonin kimberlites worldwide, are overcome in this study of theexceptionally fresh diamondiferous kimberlites of the Udachnaya-Eastpipe from the Daldyn–Alakit province, Yakutia, northernSiberia. These serpentine-free kimberlites contain large amountsof olivine (50 vol.%) in a chloride–carbonate groundmass.Olivine is represented by two populations (olivine-I and groundmassolivine-II) differing in morphology, colour and grain size,and trapped mineral and melt inclusions. The large fragmentalolivine-I is compositionally variable in terms of major (Fo_85–94)and trace element concentrations, including H₂O content (10–136ppm). Multiple sources of olivine-I, such as convecting andlithospheric mantle, are suggested. The groundmass olivine-IIis recognized by smaller grain sizes and perfect crystallographicshapes that indicate crystallization during magma ascent andemplacement. However, a simple crystallization history for olivine-IIis complicated by complex zoning in terms of Fo values and traceelement contents. The cores of olivine-II are compositionallysimilar to olivine-I, which suggests a genetic link betweenthese two types of olivine. Olivine-I and olivine-II have oxygenisotope values (+ 5·6 ± 0·1 VSMOW, 1 SD)that are indistinguishable from one another, but higher thanvalues (+ 5·18 ± 0·28) in ‘typical’mantle olivine. These elevated values probably reflect equilibriumwith the Udachnaya carbonate melt at low temperatures and ¹⁸O-enrichedmantle source. The volumetrically significant rims of olivine-IIhave constant Fo values (89·0 ± 0·2 mol%),but variable trace element compositions. The uniform Fo compositionsof the rims imply an absence of fractionation of the melt'sFe²⁺/Mg, which is possible in the carbonatite melt–olivinesystem. The kimberlite melt is argued to have originated inthe mantle as a chloride–carbonate liquid, devoid of ‘ultramafic’or ‘basaltic’ aluminosilicate components, but becameolivine-laden and olivine-saturated by scavenging olivine crystalsfrom the pathway rocks and dissolving them en route to the surface.During emplacement the kimberlite magma changed progressivelytowards an original alkali-rich chloride–carbonate meltby extensively crystallizing groundmass olivine and gravitationalseparation of solids in the pipe. KEY WORDS: kimberlite; olivine; partial melting; carbonatitic melt; oxygen isotopes; H₂O